The DOI matches its Crossref record; 14 of the 14 references it cites were found in a registry or an index.
Electrochemical Activation of CO2 through Atomic Ordering Transformations of AuCu Nanoparticles
Open accessAbstract
Precise control of elemental configurations within multimetallic nanoparticles (NPs) could enable access to functional nanomaterials with significant performance benefits. This can be achieved down to the atomic level by the disorder-to-order transformation of individual NPs. Here, by systematically controlling the ordering degree, we show that the atomic ordering transformation, applied to AuCu NPs, activates them to perform as selective electrocatalysts for CO 2 reduction. In contrast to the disordered alloy NP, which is catalytically active for hydrogen evolution, ordered AuCu NPs selectively converted CO 2 to CO at faradaic efficiency reaching 80%. CO formation could be achieved with a reduction in overpotential of ∼200 mV, and catalytic turnover was enhanced by 3.2-fold. In comparison to those obtained with a pure gold catalyst, mass activities could be improved as well. Atomic-level structural investigations revealed three atomic gold layers over the intermetallic core to be sufficient for enhanced catalytic behavior, which is further supported by DFT analysis.
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Self-citationComputational high-throughput screening of electrocatalytic materials for hydrogen evolution
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Self-citationHow copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels
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Self-citationEnhanced electrocatalytic CO2 reduction via field-induced reagent concentration
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Activity Descriptors for CO 2 Electroreduction to Methane on Transition-Metal Catalysts
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Self-citationElectrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces
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Self-citationActive and Selective Conversion of CO 2 to CO on Ultrathin Au Nanowires
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Cited by
Progress and perspectives of electrochemical CO2 reduction on copper in aqueous electrolyte
Nitopi, S., Bertheussen, E., Scott, S. B., Liu, X., Engstfeld, A. K., Horch, S., Seger, B., Stephens, I. E. L., Chan, K., Hahn, C., et al. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00705 · Cited by 5,223
Self-citationCO 2 electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface
Dinh, C.-T., Burdyny, T., Kibria, M. G., Seifitokaldani, A., Gabardo, C. M., García de Arquer, F. P., Kiani, A., Edwards, J. P., De Luna, P., Bushuyev, O. S., et al. (2018) · Science · doi:10.1126/science.aas9100 · Cited by 2,515
Designing materials for electrochemical carbon dioxide recycling
Ross, M. B., De Luna, P., Li, Y., Dinh, C.-T., Kim, D., Yang, P., & Sargent, E. H. (2019) · Nature Catalysis · doi:10.1038/s41929-019-0306-7 · Cited by 1,302
Self-citationElectrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
High-entropy materials for catalysis: A new frontier
Sun, Y., & Dai, S. (2021) · Science Advances · doi:10.1126/sciadv.abg1600 · Cited by 942
Metadata
- Authors
- Kim, D., Xie, C., Becknell, N., Yu, Y., Karamad, M., Chan, K., Crumlin, E. J., Nørskov, J. K., & Yang, P.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-06-07
- Volume
- 139
- Issue
- 24
- Pages
- 8329-8336
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2619141030
- Cited by
- 680
- References
- 14
- FWCI
- 18.50
- Type
- journal article
- Language
- en
- Open access
- green
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- Kim, D., Xie, C., Becknell, N., Yu, Y., Karamad, M., Chan, K., Crumlin, E. J., Nørskov, J. K., & Yang, P. (2017). Electrochemical Activation of CO2 through Atomic Ordering Transformations of AuCu Nanoparticles. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.7b03516
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