The DOI matches its Crossref record; 32 of the 32 references it cites were found in a registry or an index.
Controlled Intercalation and Chemical Exfoliation of Layered Metal–Organic Frameworks Using a Chemically Labile Intercalating Agent
Abstract
Creating ordered two-dimensional (2D) metal-organic framework (MOF) nanosheets has attracted extensive interest. However, it still remains a great challenge to synthesize ultrathin 2D MOF nanosheets with controlled thickness in high yields. In this work, we demonstrate a novel intercalation and chemical exfoliation approach to obtain MOF nanosheets from intrinsically layered MOF crystals. This approach involves two steps: first, layered porphyrinic MOF crystals are intercalated with 4,4'-dipyridyl disulfide through coordination bonding with the metal nodes; subsequently, selective cleavage of the disulfide bond induces exfoliation of the intercalated MOF crystals, leading to individual freestanding MOF nanosheets. This chemical exfoliation process can proceed efficiently at room temperature to produce ultrathin (∼1 nm) 2D MOF nanosheets in ∼57% overall yield. The obtained ultrathin nanosheets exhibit efficient and far superior heterogeneous photocatalysis performance compared with the corresponding bulk MOF.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Novoselov, K. S., Fal′ko, V. I., Colombo, L., Gellert, P. R., Schwab, M. G., & Kim, K. (2012) · Nature · doi:10.1038/nature11458 · Cited by 9,251
Chemical methods for the production of graphenes
Park, S., & Ruoff, R. S. (2009) · Nature Nanotechnology · doi:10.1038/nnano.2009.58 · Cited by 6,663
Photosensitized singlet oxygen and its applications
DeRosa, M. (2002) · Coordination Chemistry Reviews · doi:10.1016/s0010-8545(02)00034-6 · Cited by 2,931
Ultrathin metal–organic framework nanosheets for electrocatalytic oxygen evolution
Zhao, S., Wang, Y., Dong, J., He, C.-T., Yin, H., An, P., Zhao, K., Zhang, X., Gao, C., Zhang, L., et al. (2016) · Nature Energy · doi:10.1038/nenergy.2016.184 · Cited by 2,602
Self-citationYang, S., Gong, Y., Zhang, J., Zhan, L., Ma, L., Fang, Z., Vajtai, R., Wang, X., & Ajayan, P. M. (2013) · Advanced Materials · doi:10.1002/adma.201204453 · Cited by 2,515
Ultrathin Two-Dimensional Nanomaterials
Zhang, H. (2015) · ACS Nano · doi:10.1021/acsnano.5b05040 · Cited by 2,167
Metal–organic framework nanosheets in polymer composite materials for gas separation
Rodenas, T., Luz, I., Prieto, G., Seoane, B., Miro, H., Corma, A., Kapteijn, F., Llabrés i Xamena, F. X., & Gascon, J. (2015) · Nature Materials · doi:10.1038/nmat4113 · Cited by 2,136
Metal dichalcogenide nanosheets: preparation, properties and applications
Huang, X., Zeng, Z., & Zhang, H. (2013) · Chemical Society Reviews · doi:10.1039/c2cs35387c · Cited by 2,030
Metal-organic framework nanosheets as building blocks for molecular sieving membranes
Peng, Y., Li, Y., Ban, Y., Jin, H., Jiao, W., Liu, X., & Yang, W. (2014) · Science · doi:10.1126/science.1254227 · Cited by 1,731
Lv, R., Robinson, J. A., Schaak, R. E., Sun, D., Sun, Y., Mallouk, T. E., & Terrones, M. (2015) · Accounts of Chemical Research · doi:10.1021/ar5002846 · Cited by 1,380
Cited by
Xu, G.-R., An, Z.-H., Xu, K., Liu, Q., Das, R., & Zhao, H.-L. (2021) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2020.213554 · Cited by 379
FeS2/CoS2 Interface Nanosheets as Efficient Bifunctional Electrocatalyst for Overall Water Splitting
Li, Y., Yin, J., An, L., Lu, M., Sun, K., Zhao, Y., Gao, D., Cheng, F., & Xi, P. (2018) · Small · doi:10.1002/smll.201801070 · Cited by 365
Huang, J., Li, Y., Huang, R., He, C., Gong, L., Hu, Q., Wang, L., Xu, Y., Tian, X., Liu, S., et al. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201801029 · Cited by 341
Metadata
- Authors
- Ding, Y., Chen, Y.-P., Zhang, X., Chen, L., Dong, Z., Jiang, H.-L., Xu, H., & Zhou, H.-C.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-06-30
- Volume
- 139
- Issue
- 27
- Pages
- 9136-9139
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2733683283
- Cited by
- 470
- References
- 32
- FWCI
- 17.25
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Controlled Intercalation and Chemical Exfoliation of Layered Metal–Organic Frameworks Using a Chemically Labile Intercalating Agent. https://app.cochat.ai/papers/10.1021/jacs.7b04829
- The paper
- Ding, Y., Chen, Y.-P., Zhang, X., Chen, L., Dong, Z., Jiang, H.-L., Xu, H., & Zhou, H.-C. (2017). Controlled Intercalation and Chemical Exfoliation of Layered Metal–Organic Frameworks Using a Chemically Labile Intercalating Agent. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.7b04829
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
