The DOI matches its Crossref record; 27 of the 27 references it cites were found in a registry or an index.
Designing Air-Stable O3-Type Cathode Materials by Combined Structure Modulation for Na-Ion Batteries
Open accessAbstract
As promising high-capacity cathode materials for Na-ion batteries, O3-type Na-based metal oxides always suffer from their poor air stability originating from the spontaneous extraction of Na and oxidation of transition metals when exposed to air. Herein, a combined structure modulation is proposed to tackle concurrently the two handicaps via reducing Na layers spacing and simultaneously increasing valence state of transition metals. Guided by density functional theory calculations, we demonstrate such a modulation can be subtly realized through cosubstitution of one kind of heteroatom with comparable electronegativity and another one with substantially different Fermi level, by adjusting the structure of NaNi 0.5 Mn 0.5 O 2 via Cu/Ti codoping. The as-obtained NaNi 0.45 Cu 0.05 Mn 0.4 Ti 0.1 O 2 exhibits an increase of 20 times in stable air-exposure period and 9 times in capacity retention after 500 cycles, and even retains its structure and capacity after being soaked in water. Such a simple and effective structure modulation reveals a new avenue for high-performance O3-type cathodes and pushes the large-scale industrialization of Na-ion batteries a decisive step forward.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
A phosphorene–graphene hybrid material as a high-capacity anode for sodium-ion batteries
Sun, J., Lee, H.-W., Pasta, M., Yuan, H., Zheng, G., Sun, Y., Li, Y., & Cui, Y. (2015) · Nature Nanotechnology · doi:10.1038/nnano.2015.194 · Cited by 1,480
Recent Advances and Prospects of Cathode Materials for Sodium‐Ion Batteries
Xiang, X., Zhang, K., & Chen, J. (2015) · Advanced Materials · doi:10.1002/adma.201501527 · Cited by 1,160
Removal of Interstitial H2O in Hexacyanometallates for a Superior Cathode of a Sodium-Ion Battery
Song, J., Wang, L., Lu, Y., Liu, J., Guo, B., Xiao, P., Lee, J.-J., Yang, X.-Q., Henkelman, G., & Goodenough, J. B. (2015) · Journal of the American Chemical Society · doi:10.1021/ja512383b · Cited by 966
Self-citationKomaba, S., Yabuuchi, N., Nakayama, T., Ogata, A., Ishikawa, T., & Nakai, I. (2012) · Inorganic Chemistry · doi:10.1021/ic300357d · Cited by 822
Prototype Sodium‐Ion Batteries Using an Air‐Stable and Co/Ni‐Free O3‐Layered Metal Oxide Cathode
Mu, L., Xu, S., Li, Y., Hu, Y., Li, H., Chen, L., & Huang, X. (2015) · Advanced Materials · doi:10.1002/adma.201502449 · Cited by 704
Electrospun Sb/C Fibers for a Stable and Fast Sodium-Ion Battery Anode
Zhu, Y., Han, X., Xu, Y., Liu, Y., Zheng, S., Xu, K., Hu, L., & Wang, C. (2013) · ACS Nano · doi:10.1021/nn4025674 · Cited by 639
Wang, Y., Xiao, R., Hu, Y.-S., Avdeev, M., & Chen, L. (2015) · Nature Communications · doi:10.1038/ncomms7954 · Cited by 592
Sathiya, M., Hemalatha, K., Ramesha, K., Tarascon, J.-M., & Prakash, A. S. (2012) · Chemistry of Materials · doi:10.1021/cm300466b · Cited by 564
Ma, C., Alvarado, J., Xu, J. L., Clément, R. J., Kodur, M., Tong, W., Grey, C. P., & Meng, Y. S. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b00164 · Cited by 513
Enabling Sodium Batteries Using Lithium‐Substituted Sodium Layered Transition Metal Oxide Cathodes
Kim, D., Kang, S., Slater, M., Rood, S., Vaughey, J. T., Karan, N., Balasubramanian, M., & Johnson, C. S. (2011) · Advanced Energy Materials · doi:10.1002/aenm.201000061 · Cited by 446
Li, Y., Yang, Z., Xu, S., Mu, L., Gu, L., Hu, Y., Li, H., & Chen, L. (2015) · Advanced Science · doi:10.1002/advs.201500031 · Cited by 423
Self-citationYuan, D., Wang, Y. X., Cao, Y., Ai, X. P., & Yang, H. X. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b00594 · Cited by 330
Oh, S.-M., Myung, S.-T., Yoon, C. S., Lu, J., Hassoun, J., Scrosati, B., Amine, K., & Sun, Y.-K. (2014) · Nano Letters · doi:10.1021/nl500077v · Cited by 314
A Honeycomb‐Layered Na3Ni2SbO6: A High‐Rate and Cycle‐Stable Cathode for Sodium‐Ion Batteries
Yuan, D., Liang, X., Wu, L., Cao, Y., Ai, X., Feng, J., & Yang, H. (2014) · Advanced Materials · doi:10.1002/adma.201401946 · Cited by 295
Wang, P.-F., You, Y., Yin, Y.-X., & Guo, Y.-G. (2016) · Journal of Materials Chemistry A · doi:10.1039/c6ta07589d · Cited by 262
Self-citationThe Interplay of Al and Mg Speciation in Advanced Mg Battery Electrolyte Solutions
See, K. A., Chapman, K. W., Zhu, L., Wiaderek, K. M., Borkiewicz, O. J., Barile, C. J., Chupas, P. J., & Gewirth, A. A. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b10987 · Cited by 238
High Capacity O3-Type Na[Li0.05(Ni0.25Fe0.25Mn0.5)0.95]O2 Cathode for Sodium Ion Batteries
Oh, S.-M., Myung, S.-T., Hwang, J.-Y., Scrosati, B., Amine, K., & Sun, Y.-K. (2014) · Chemistry of Materials · doi:10.1021/cm502481b · Cited by 237
Han, M. H., Gonzalo, E., Sharma, N., López del Amo, J. M., Armand, M., Avdeev, M., Saiz Garitaonandia, J. J., & Rojo, T. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b03276 · Cited by 234
High Power–High Energy Sodium Battery Based on Threefold Interpenetrating Network
Zhu, C., Kopold, P., van Aken, P. A., Maier, J., & Yu, Y. (2016) · Advanced Materials · doi:10.1002/adma.201505943 · Cited by 231
Keller, M., Buchholz, D., & Passerini, S. (2015) · Advanced Energy Materials · doi:10.1002/aenm.201501555 · Cited by 227
Dong, Y., Li, S., Zhao, K., Han, C., Chen, W., Wang, B., Wang, L., Xu, B., Wei, Q., Zhang, L., et al. (2015) · Energy & Environmental Science · doi:10.1039/c5ee00036j · Cited by 173
Electrochemical properties of NaNi1/3Co1/3Fe1/3O2 as a cathode material for Na-ion batteries
Vassilaras, P., Toumar, A. J., & Ceder, G. (2014) · Electrochemistry Communications · doi:10.1016/j.elecom.2013.11.015 · Cited by 170
Stratford, J. M., Mayo, M., Allan, P. K., Pecher, O., Borkiewicz, O. J., Wiaderek, K. M., Chapman, K. W., Pickard, C. J., Morris, A. J., & Grey, C. P. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b01398 · Cited by 167
Thorne, J. S., Dunlap, R. A., & Obrovac, M. N. (2012) · Journal of The Electrochemical Society · doi:10.1149/2.058302jes · Cited by 139
Atomic Force Microscopy Studies on Molybdenum Disulfide Flakes as Sodium-Ion Anodes
Lacey, S. D., Wan, J., Cresce, A. V. W., Russell, S. M., Dai, J., Bao, W., Xu, K., & Hu, L. (2014) · Nano Letters · doi:10.1021/nl503871s · Cited by 125
Emerging Prototype Sodium‐Ion Full Cells with Nanostructured Electrode Materials
Ren, W., Zhu, Z., An, Q., & Mai, L. (2017) · Small · doi:10.1002/smll.201604181 · Cited by 121
Cabana, J., Chernova, N. A., Xiao, J., Roppolo, M., Aldi, K. A., Whittingham, M. S., & Grey, C. P. (2013) · Inorganic Chemistry · doi:10.1021/ic400579w · Cited by 82
Cited by
Tian, Y., Zeng, G., Rutt, A., Shi, T., Kim, H., Wang, J., Koettgen, J., Sun, Y., Ouyang, B., Chen, T., et al. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00767 · Cited by 1,614
Rational design of layered oxide materials for sodium-ion batteries
Zhao, C., Wang, Q., Yao, Z., Wang, J., Sánchez-Lengeling, B., Ding, F., Qi, X., Lu, Y., Bai, X., Li, B., et al. (2020) · Science · doi:10.1126/science.aay9972 · Cited by 1,540
Bresser, D., Buchholz, D., Moretti, A., Varzi, A., & Passerini, S. (2018) · Energy & Environmental Science · doi:10.1039/c8ee00640g · Cited by 640
Recent Progress of Layered Transition Metal Oxide Cathodes for Sodium‐Ion Batteries
Liu, Q., Hu, Z., Chen, M., Zou, C., Jin, H., Wang, S., Chou, S., & Dou, S. (2019) · Small · doi:10.1002/smll.201805381 · Cited by 447
Chen, M., Liu, Q., Wang, S., Wang, E., Guo, X., & Chou, S. (2019) · Advanced Energy Materials · doi:10.1002/aenm.201803609 · Cited by 341
Metadata
- Authors
- Yao, H.-R., Wang, P.-F., Gong, Y., Zhang, J., Yu, X., Gu, L., OuYang, C., Yin, Y.-X., Hu, E., Yang, X.-Q., Stavitski, E., Guo, Y.-G., & Wan, L.-J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-06-16
- Volume
- 139
- Issue
- 25
- Pages
- 8440-8443
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2623414978
- Cited by
- 466
- References
- 27
- FWCI
- 16.78
- Type
- journal article
- Language
- en
- Open access
- green
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
