The DOI matches its Crossref record; 36 of the 36 references it cites were found in a registry or an index.
Visible-Light-Driven Valorization of Biomass Intermediates Integrated with H2 Production Catalyzed by Ultrathin Ni/CdS Nanosheets
Abstract
Photocatalytic upgrading of crucial biomass-derived intermediate chemicals (i.e., furfural alcohol, 5-hydroxymethylfurfural (HMF)) to value-added products (aldehydes and acids) was carried out on ultrathin CdS nanosheets (thickness ∼1 nm) decorated with nickel (Ni/CdS). More importantly, simultaneous H 2 production was realized upon visible light irradiation under ambient conditions utilizing these biomass intermediates as proton sources. The remarkable difference in the rates of transformation of furfural alcohol and HMF to their corresponding aldehydes in neutral water was observed and investigated. Aided by theoretical computation, it was rationalized that the slightly stronger binding affinity of the aldehyde group in HMF to Ni/CdS resulted in the lower transformation of HMF to 2,5-diformylfuran compared to that of furfural alcohol to furfural. Nevertheless, photocatalytic oxidation of furfural alcohol and HMF under alkaline conditions led to complete transformation to the respective carboxylates with concomitant production of H 2 .
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Kresse, G., & Furthmüller, J. (1996) · Computational Materials Science · doi:10.1016/0927-0256(96)00008-0 · Cited by 75,638
Kresse, G., & Hafner, J. (1994) · Physical Review B · doi:10.1103/physrevb.49.14251 · Cited by 23,019
Semiconductor-based Photocatalytic Hydrogen Generation
Chen, X., Shen, S., Guo, L., & Mao, S. S. (2010) · Chemical Reviews · doi:10.1021/cr1001645 · Cited by 7,876
Chemical Routes for the Transformation of Biomass into Chemicals
Corma, A., Iborra, S., & Velty, A. (2007) · Chemical Reviews · doi:10.1021/cr050989d · Cited by 5,970
Heyd, J., Scuseria, G. E., & Ernzerhof, M. (2006) · The Journal of Chemical Physics · doi:10.1063/1.2204597 · Cited by 5,288
Conversion of Biomass into Chemicals over Metal Catalysts
Besson, M., Gallezot, P., & Pinel, C. (2014) · Chemical Reviews · doi:10.1021/cr4002269 · Cited by 1,780
Rosatella, A. A., Simeonov, S. P., Frade, R. F. M., & Afonso, C. A. M. (2011) · Green Chemistry · doi:10.1039/c0gc00401d · Cited by 1,652
Catalysis Research of Relevance to Carbon Management: Progress, Challenges, and Opportunities
Arakawa, H., Aresta, M., Armor, J. N., Barteau, M. A., Beckman, E. J., Bell, A. T., Bercaw, J. E., Creutz, C., Dinjus, E., Dixon, D. A., et al. (2001) · Chemical Reviews · doi:10.1021/cr000018s · Cited by 1,411
Yan, H., Yang, J., Ma, G., Wu, G., Zong, X., Lei, Z., Shi, J., & Li, C. (2009) · Journal of Catalysis · doi:10.1016/j.jcat.2009.06.024 · Cited by 1,119
You, B., Liu, X., Jiang, N., & Sun, Y. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b07127 · Cited by 1,001
Self-citation
Cited by
Bifunctional Electrocatalysts for Overall and Hybrid Water Splitting
Quan, L., Jiang, H., Mei, G., Sun, Y., & You, B. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00332 · Cited by 874
Self-citationYang, Y., & Mu, T. (2021) · Green Chemistry · doi:10.1039/d1gc00914a · Cited by 539
Cadmium sulfide-based nanomaterials for photocatalytic hydrogen production
Yuan, Y.-J., Chen, D., Yu, Z.-T., & Zou, Z.-G. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta00671g · Cited by 523
Kampouri, S., & Stylianou, K. C. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b00332 · Cited by 298
Photocatalytic conversion of lignocellulosic biomass to valuable products
Liu, X., Duan, X., Wei, W., Wang, S., & Ni, B.-J. (2019) · Green Chemistry · doi:10.1039/c9gc01728c · Cited by 268
Metadata
- Authors
- Han, G., Jin, Y.-H., Burgess, R. A., Dickenson, N. E., Cao, X.-M., & Sun, Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-10-25
- Volume
- 139
- Issue
- 44
- Pages
- 15584-15587
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2763056250
- Cited by
- 533
- References
- 36
- FWCI
- 18.16
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Visible-Light-Driven Valorization of Biomass Intermediates Integrated with H2 Production Catalyzed by Ultrathin Ni/CdS Nanosheets. https://app.cochat.ai/papers/10.1021/jacs.7b08657
- The paper
- Han, G., Jin, Y.-H., Burgess, R. A., Dickenson, N. E., Cao, X.-M., & Sun, Y. (2017). Visible-Light-Driven Valorization of Biomass Intermediates Integrated with H2 Production Catalyzed by Ultrathin Ni/CdS Nanosheets. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.7b08657
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
