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Visible-Light-Driven Valorization of Biomass Intermediates Integrated with H2 Production Catalyzed by Ultrathin Ni/CdS Nanosheets
Abstract
Photocatalytic upgrading of crucial biomass-derived intermediate chemicals (i.e., furfural alcohol, 5-hydroxymethylfurfural (HMF)) to value-added products (aldehydes and acids) was carried out on ultrathin CdS nanosheets (thickness ∼1 nm) decorated with nickel (Ni/CdS). More importantly, simultaneous H 2 production was realized upon visible light irradiation under ambient conditions utilizing these biomass intermediates as proton sources. The remarkable difference in the rates of transformation of furfural alcohol and HMF to their corresponding aldehydes in neutral water was observed and investigated. Aided by theoretical computation, it was rationalized that the slightly stronger binding affinity of the aldehyde group in HMF to Ni/CdS resulted in the lower transformation of HMF to 2,5-diformylfuran compared to that of furfural alcohol to furfural. Nevertheless, photocatalytic oxidation of furfural alcohol and HMF under alkaline conditions led to complete transformation to the respective carboxylates with concomitant production of H 2 .
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Cites
Kresse, G., & Furthmüller, J. (1996) · Computational Materials Science · doi:10.1016/0927-0256(96)00008-0 · Cited by 75,638
Kresse, G., & Hafner, J. (1994) · Physical Review B · doi:10.1103/physrevb.49.14251 · Cited by 23,019
Semiconductor-based Photocatalytic Hydrogen Generation
Chen, X., Shen, S., Guo, L., & Mao, S. S. (2010) · Chemical Reviews · doi:10.1021/cr1001645 · Cited by 7,876
Chemical Routes for the Transformation of Biomass into Chemicals
Corma, A., Iborra, S., & Velty, A. (2007) · Chemical Reviews · doi:10.1021/cr050989d · Cited by 5,970
Heyd, J., Scuseria, G. E., & Ernzerhof, M. (2006) · The Journal of Chemical Physics · doi:10.1063/1.2204597 · Cited by 5,288
Conversion of Biomass into Chemicals over Metal Catalysts
Besson, M., Gallezot, P., & Pinel, C. (2014) · Chemical Reviews · doi:10.1021/cr4002269 · Cited by 1,780
Rosatella, A. A., Simeonov, S. P., Frade, R. F. M., & Afonso, C. A. M. (2011) · Green Chemistry · doi:10.1039/c0gc00401d · Cited by 1,652
Catalysis Research of Relevance to Carbon Management: Progress, Challenges, and Opportunities
Arakawa, H., Aresta, M., Armor, J. N., Barteau, M. A., Beckman, E. J., Bell, A. T., Bercaw, J. E., Creutz, C., Dinjus, E., Dixon, D. A., et al. (2001) · Chemical Reviews · doi:10.1021/cr000018s · Cited by 1,411
Yan, H., Yang, J., Ma, G., Wu, G., Zong, X., Lei, Z., Shi, J., & Li, C. (2009) · Journal of Catalysis · doi:10.1016/j.jcat.2009.06.024 · Cited by 1,119
You, B., Liu, X., Jiang, N., & Sun, Y. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b07127 · Cited by 1,001
Self-citationYou, B., Jiang, N., Sheng, M., Bhushan, M. W., & Sun, Y. (2016) · ACS Catalysis · doi:10.1021/acscatal.5b02193 · Cited by 818
Self-citationRecent progress towards the electrosynthesis of ammonia from sustainable resources
Shipman, M. A., & Symes, M. D. (2017) · Catalysis Today · doi:10.1016/j.cattod.2016.05.008 · Cited by 762
Chen, J., Wu, X., Yin, L., Li, B., Hong, X., Fan, Z., Chen, B., Xue, C., & Zhang, H. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201410172 · Cited by 669
Thoi, V. S., Sun, Y., Long, J. R., & Chang, C. J. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35272a · Cited by 668
Self-citationColmenares, J. C., & Luque, R. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60262a · Cited by 645
You, B., Jiang, N., Liu, X., & Sun, Y. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201603798 · Cited by 615
Self-citationWang, T., Nolte, M. W., & Shanks, B. H. (2014) · Green Chem. · doi:10.1039/c3gc41365a · Cited by 596
Exploring the limits: A low-pressure, low-temperature Haber–Bosch process
Vojvodic, A., Medford, A. J., Studt, F., Abild-Pedersen, F., Khan, T. S., Bligaard, T., & Nørskov, J. K. (2014) · Chemical Physics Letters · doi:10.1016/j.cplett.2014.03.003 · Cited by 526
You, B., Liu, X., Liu, X., & Sun, Y. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b00876 · Cited by 392
Self-citationJiang, N., You, B., Boonstra, R., Terrero Rodriguez, I. M., & Sun, Y. (2016) · ACS Energy Letters · doi:10.1021/acsenergylett.6b00214 · Cited by 387
Self-citationSetzler, B. P., Zhuang, Z., Wittkopf, J. A., & Yan, Y. (2016) · Nature Nanotechnology · doi:10.1038/nnano.2016.265 · Cited by 384
Chai, Z., Zeng, T.-T., Li, Q., Lu, L.-Q., Xiao, W.-J., & Xu, D. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b06860 · Cited by 373
Xu, Y., Zhao, W., Xu, R., Shi, Y., & Zhang, B. (2013) · Chemical Communications · doi:10.1039/c3cc46342g · Cited by 337
Vuyyuru, K. R., & Strasser, P. (2012) · Catalysis Today · doi:10.1016/j.cattod.2012.05.008 · Cited by 337
Hierarchically Porous Nickel Sulfide Multifunctional Superstructures
You, B., & Sun, Y. (2016) · Advanced Energy Materials · doi:10.1002/aenm.201502333 · Cited by 302
Self-citationYan, Y., Crisp, R. W., Gu, J., Chernomordik, B. D., Pach, G. F., Marshall, A. R., Turner, J. A., & Beard, M. C. (2017) · Nature Energy · doi:10.1038/nenergy.2017.52 · Cited by 213
Catalytic Conversion of Biomass: Challenges and Issues
Gallezot, P. (2008) · ChemSusChem · doi:10.1002/cssc.200800091 · Cited by 205
Photodeposition of Pt on Colloidal CdS and CdSe/CdS Semiconductor Nanostructures
Dukovic, G., Merkle, M. G., Nelson, J. H., Hughes, S. M., & Alivisatos, A. P. (2008) · Advanced Materials · doi:10.1002/adma.200800384 · Cited by 195
Sun, Y., Sun, J., Long, J. R., Yang, P., & Chang, C. J. (2013) · Chem. Sci. · doi:10.1039/c2sc21163g · Cited by 187
Self-citationTang, M. L., Grauer, D. C., Lassalle‐Kaiser, B., Yachandra, V. K., Amirav, L., Long, J. R., Yano, J., & Alivisatos, A. P. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201104412 · Cited by 176
Filiciotto, L., Balu, A. M., Van der Waal, J. C., & Luque, R. (2018) · Catalysis Today · doi:10.1016/j.cattod.2017.03.008 · Cited by 168
De, S., Dutta, S., & Saha, B. (2016) · Catalysis Science & Technology · doi:10.1039/c6cy01370h · Cited by 152
Fang, R., Luque, R., & Li, Y. (2016) · Green Chemistry · doi:10.1039/c6gc02018f · Cited by 106
Nanostructured Electrocatalysts for PEM Fuel Cells and Redox Flow Batteries: A Selected Review
Shao, Y., Cheng, Y., Duan, W., Wang, W., Lin, Y., Wang, Y., & Li, B. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b01737 · Cited by 87
Yin, S., Han, J., Zou, Y., Zhou, T., & Xu, R. Q. (2016) · Nanoscale · doi:10.1039/c6nr00989a · Cited by 83
Green Photo-active Nanomaterials
(2015) · RSC green chemistry series · doi:10.1039/9781782622642 · Cited by 25
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Self-citationYang, Y., & Mu, T. (2021) · Green Chemistry · doi:10.1039/d1gc00914a · Cited by 539
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Metadata
- Authors
- Han, G., Jin, Y.-H., Burgess, R. A., Dickenson, N. E., Cao, X.-M., & Sun, Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-10-25
- Volume
- 139
- Issue
- 44
- Pages
- 15584-15587
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2763056250
- Cited by
- 533
- References
- 36
- FWCI
- 18.16
- Type
- journal article
- Language
- en
- Open access
- closed
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