Regioregular Bis-Pyridal[2,1,3]thiadiazole-Based Semiconducting Polymer for High-Performance Ambipolar Transistors
Abstract
We report a regioregular bis-pyridal[2,1,3]-thiadiazole (BPT) acceptor strategy to construct the first ambipolar pyridal[2,1,3]thiadiazole-based semiconducting polymer (PBPTV). The use of BPT unit enables PBPTV to achieve high electron affinity, low LUMO level, and extended π-conjugation. All these factors provide PBPTV with encouraging hole and electron mobilities up to 6.87 and 8.49 cm 2 V –1 s –1, respectively. Our work demonstrates that the BPT unit is a promising building block for designing high-performance electron-transporting semiconductors in organic electronics.
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Upon aggregate formation, PBPTV chains adopt a geometry with tilted or twisted close contact similar to a herringbone-like structure.
“Upon aggregate formation, the PBPTV chains adopt a geometry with tilted or twisted close contact similar to a herringbone-like structure.185”
From The Pursuit of Shortwave Infrared-Emitting Nanoparticles with Bright Fluorescence through Molecular Design and Excited-State Engineering of Molecular Aggregates (2022) · cites this paper as [185]
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Self-citation
- Authors
- Zhu, C., Zhao, Z., Chen, H., Zheng, L., Li, X., Chen, J., Sun, Y., Liu, F., Guo, Y., & Liu, Y.
- Affiliations
- Xiangtan University (CN)
- Chinese Academy of Sciences (CN)
- Beihang University (CN)
- Shanghai Jiao Tong University (CN)
- Corresponding author
- Chen, Huajie
- Guo, Yunlong
- Liu, Yunqi
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-11-22
- Volume
- 139
- Issue
- 49
- Pages
- 17735-17738
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2770729493
- Cited by
- 126
- References
- 30
- Citations by year
- 2026: 2 · 2025: 7 · 2024: 8 · 2023: 14 · 2022: 18 · 2021: 11 · 2020: 18 · 2019: 29 · 2018: 19
- FWCI
- 7.50
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of the American Chemical Society (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Hunan Provincial Science and Technology Department (2017RS3048)
- Education Department of Hunan Province (17B253)
- National Natural Science Foundation of China (51233006, 51403177)
- Chinese Academy of Sciences (XDB12030100, XDPB06)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Electronics and Photovoltaics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Light-Emitting Diodes Research
- Physical Sciences › Materials Science › Polymers and Plastics › Conducting polymers and applications
- Keywords
- regioregular polymers, semiconducting polymers, ambipolar transistors, electron transport materials, hole mobility, electron mobility, LUMO energy, π-conjugation, organic field-effect transistors
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