The DOI matches its Crossref record; 30 of the 30 references it cites were found in a registry or an index.
Fast, Ambient Temperature and Pressure Ionothermal Synthesis of Three-Dimensional Covalent Organic Frameworks
Abstract
Covalent organic frameworks (COFs) are an emerging class of porous crystalline polymers with wide range of potential applications. However, the availability of three-dimensional (3D) COFs is still limited, and their synthesis is confined to the high-temperature solvothermal method. Here, we report for the first time a general and simple strategy to produce a series of 3D ionic liquid (IL)-containing COFs (3D-IL-COFs) by using IL as a green solvent. The syntheses are carried out at ambient temperature and pressure accompanied by a high reaction speed (e.g., only three mins for 3D-IL-COF-1), and the IL can be reused without activity loss. Furthermore, the 3D-IL-COFs show impressive performance in the separation of CO 2 /N 2 and CO 2 /CH 4 . This research thus presents a potential pathway to green large-scale industrial production of COFs.
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Cites
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Porous, Covalent Triazine‐Based Frameworks Prepared by Ionothermal Synthesis
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Designed Synthesis of 3D Covalent Organic Frameworks
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Cited by
Single-crystal x-ray diffraction structures of covalent organic frameworks
Ma, T., Kapustin, E. A., Yin, S. X., Liang, L., Zhou, Z., Niu, J., Li, L.-H., Wang, Y., Su, J., Li, J., et al. (2018) · Science · doi:10.1126/science.aat7679 · Cited by 1,381
Opportunities of Covalent Organic Frameworks for Advanced Applications
Song, Y., Sun, Q., Aguila, B., & Ma, S. (2019) · Advanced Science · doi:10.1002/advs.201801410 · Cited by 586
Chiral covalent organic frameworks: design, synthesis and property
Han, X., Yuan, C., Hou, B., Liu, L., Li, H., Liu, Y., & Cui, Y. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00009d · Cited by 478
Self-citation
Metadata
- Authors
- Guan, X., Ma, Y., Li, H., Yusran, Y., Xue, M., Fang, Q., Yan, Y., Valtchev, V., & Qiu, S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-03-19
- Volume
- 140
- Issue
- 13
- Pages
- 4494-4498
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2790700013
- Cited by
- 438
- References
- 30
- FWCI
- 13.55
- Type
- journal article
- Language
- en
- Open access
- closed
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- Guan, X., Ma, Y., Li, H., Yusran, Y., Xue, M., Fang, Q., Yan, Y., Valtchev, V., & Qiu, S. (2018). Fast, Ambient Temperature and Pressure Ionothermal Synthesis of Three-Dimensional Covalent Organic Frameworks. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.8b01320
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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