The DOI matches its Crossref record; 30 of the 30 references it cites were found in a registry or an index.
Fast, Ambient Temperature and Pressure Ionothermal Synthesis of Three-Dimensional Covalent Organic Frameworks
Abstract
Covalent organic frameworks (COFs) are an emerging class of porous crystalline polymers with wide range of potential applications. However, the availability of three-dimensional (3D) COFs is still limited, and their synthesis is confined to the high-temperature solvothermal method. Here, we report for the first time a general and simple strategy to produce a series of 3D ionic liquid (IL)-containing COFs (3D-IL-COFs) by using IL as a green solvent. The syntheses are carried out at ambient temperature and pressure accompanied by a high reaction speed (e.g., only three mins for 3D-IL-COF-1), and the IL can be reused without activity loss. Furthermore, the 3D-IL-COFs show impressive performance in the separation of CO 2 /N 2 and CO 2 /CH 4 . This research thus presents a potential pathway to green large-scale industrial production of COFs.
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Cites
Room-Temperature Ionic Liquids: Solvents for Synthesis and Catalysis. 2
Hallett, J. P., & Welton, T. (2011) · Chemical Reviews · doi:10.1021/cr1003248 · Cited by 12,578
Porous, Crystalline, Covalent Organic Frameworks
Côté, A. P., Benin, A. I., Ockwig, N. W., O'Keeffe, M., Matzger, A. J., & Yaghi, O. M. (2005) · Science · doi:10.1126/science.1120411 · Cited by 8,357
Introduction to Metal–Organic Frameworks
Zhou, H.-C., Long, J. R., & Yaghi, O. M. (2012) · Chemical Reviews · doi:10.1021/cr300014x · Cited by 7,720
The atom, the molecule, and the covalent organic framework
Diercks, C. S., & Yaghi, O. M. (2017) · Science · doi:10.1126/science.aal1585 · Cited by 3,482
Porous, Covalent Triazine‐Based Frameworks Prepared by Ionothermal Synthesis
Kuhn, P., Antonietti, M., & Thomas, A. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200705710 · Cited by 2,634
Furukawa, H., & Yaghi, O. M. (2009) · Journal of the American Chemical Society · doi:10.1021/ja9015765 · Cited by 2,608
Designed Synthesis of 3D Covalent Organic Frameworks
El-Kaderi, H. M., Hunt, J. R., Mendoza-Cortés, J. L., Côté, A. P., Taylor, R. E., O'Keeffe, M., & Yaghi, O. M. (2007) · Science · doi:10.1126/science.1139915 · Cited by 2,575
Ding, S.-Y., Gao, J., Wang, Q., Zhang, Y., Song, W.-G., Su, C.-Y., & Wang, W. (2011) · Journal of the American Chemical Society · doi:10.1021/ja206846p · Cited by 2,443
Direct Capture of CO2 from Ambient Air
Sanz-Pérez, E. S., Murdock, C. R., Didas, S. A., & Jones, C. W. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00173 · Cited by 2,406
Kandambeth, S., Mallick, A., Lukose, B., Mane, M. V., Heine, T., & Banerjee, R. (2012) · Journal of the American Chemical Society · doi:10.1021/ja308278w · Cited by 2,156
Covalent organic frameworks: a materials platform for structural and functional designs
Huang, N., Wang, P., & Jiang, D. (2016) · Nature Reviews Materials · doi:10.1038/natrevmats.2016.68 · Cited by 2,017
A Crystalline Imine-Linked 3-D Porous Covalent Organic Framework
Uribe-Romo, F. J., Hunt, J. R., Furukawa, H., Klöck, C., O’Keeffe, M., & Yaghi, O. M. (2009) · Journal of the American Chemical Society · doi:10.1021/ja8096256 · Cited by 1,715
Metal–organic framework membranes: from synthesis to separation application
Qiu, S., Xue, M., & Zhu, G. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00159a · Cited by 1,630
Self-citationTwo-dimensional sp 2 carbon–conjugated covalent organic frameworks
Jin, E., Asada, M., Xu, Q., Dalapati, S., Addicoat, M. A., Brady, M. A., Xu, H., Nakamura, T., Heine, T., Chen, Q., et al. (2017) · Science · doi:10.1126/science.aan0202 · Cited by 1,334
3D Porous Crystalline Polyimide Covalent Organic Frameworks for Drug Delivery
Fang, Q., Wang, J., Gu, S., Kaspar, R. B., Zhuang, Z., Zheng, J., Guo, H., Qiu, S., & Yan, Y. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b04147 · Cited by 1,065
Self-citationPostsynthetically Modified Covalent Organic Frameworks for Efficient and Effective Mercury Removal
Sun, Q., Aguila, B., Perman, J., Earl, L. D., Abney, C. W., Cheng, Y., Wei, H., Nguyen, N., Wojtas, L., & Ma, S. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b12885 · Cited by 1,056
Wang, S., Wang, Q., Shao, P., Han, Y., Gao, X., Ma, L., Yuan, S., Ma, X., Zhou, J., Feng, X., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b02648 · Cited by 1,030
Rationally synthesized two-dimensional polymers
Colson, J. W., & Dichtel, W. R. (2013) · Nature Chemistry · doi:10.1038/nchem.1628 · Cited by 1,016
Exceptional ammonia uptake by a covalent organic framework
Doonan, C. J., Tranchemontagne, D. J., Glover, T. G., Hunt, J. R., & Yaghi, O. M. (2010) · Nature Chemistry · doi:10.1038/nchem.548 · Cited by 999
Ionothermal Synthesis of Zeolites, Metal–Organic Frameworks, and Inorganic–Organic Hybrids
Parnham, E. R., & Morris, R. E. (2007) · Accounts of Chemical Research · doi:10.1021/ar700025k · Cited by 885
A Belt‐Shaped, Blue Luminescent, and Semiconducting Covalent Organic Framework
Wan, S., Guo, J., Kim, J., Ihee, H., & Jiang, D. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200803826 · Cited by 880
A Pyrene-Based, Fluorescent Three-Dimensional Covalent Organic Framework
Lin, G., Ding, H., Yuan, D., Wang, B., & Wang, C. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b00652 · Cited by 797
Designed synthesis of large-pore crystalline polyimide covalent organic frameworks
Fang, Q., Zhuang, Z., Gu, S., Kaspar, R. B., Zheng, J., Wang, J., Qiu, S., & Yan, Y. (2014) · Nature Communications · doi:10.1038/ncomms5503 · Cited by 753
Self-citationIonic Covalent Organic Frameworks with Spiroborate Linkage
Du, Y., Yang, H., Whiteley, J. M., Wan, S., Jin, Y., Lee, S., & Zhang, W. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201509014 · Cited by 674
Han, X., Xia, Q., Huang, J., Liu, Y., Tan, C., & Cui, Y. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b04008 · Cited by 500
Tailored crystalline microporous materials by post-synthesis modification
Valtchev, V., Majano, G., Mintova, S., & Pérez-Ramírez, J. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35196j · Cited by 478
Self-citationCalik, M., Auras, F., Salonen, L. M., Bader, K., Grill, I., Handloser, M., Medina, D. D., Dogru, M., Löbermann, F., Trauner, D., et al. (2014) · Journal of the American Chemical Society · doi:10.1021/ja509551m · Cited by 452
(1803) · Philosophical Transactions of the Royal Society of London · doi:10.1098/rstl.1803.0004 · Cited by 445
Constructing monocrystalline covalent organic networks by polymerization
Beaudoin, D., Maris, T., & Wuest, J. D. (2013) · Nature Chemistry · doi:10.1038/nchem.1730 · Cited by 435
Li, Z., Li, H., Guan, X., Tang, J., Yusran, Y., Li, Z., Xue, M., Fang, Q., Yan, Y., Valtchev, V., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b11283 · Cited by 269
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Single-crystal x-ray diffraction structures of covalent organic frameworks
Ma, T., Kapustin, E. A., Yin, S. X., Liang, L., Zhou, Z., Niu, J., Li, L.-H., Wang, Y., Su, J., Li, J., et al. (2018) · Science · doi:10.1126/science.aat7679 · Cited by 1,381
Opportunities of Covalent Organic Frameworks for Advanced Applications
Song, Y., Sun, Q., Aguila, B., & Ma, S. (2019) · Advanced Science · doi:10.1002/advs.201801410 · Cited by 586
Chiral covalent organic frameworks: design, synthesis and property
Han, X., Yuan, C., Hou, B., Liu, L., Li, H., Liu, Y., & Cui, Y. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00009d · Cited by 478
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Metadata
- Authors
- Guan, X., Ma, Y., Li, H., Yusran, Y., Xue, M., Fang, Q., Yan, Y., Valtchev, V., & Qiu, S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-03-19
- Volume
- 140
- Issue
- 13
- Pages
- 4494-4498
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2790700013
- Cited by
- 438
- References
- 30
- FWCI
- 13.55
- Type
- journal article
- Language
- en
- Open access
- closed
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