Unveiling the active sites of graphene-catalyzed peroxymonosulfate activation
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Defective sites and distorted carbon species that maintain intact sp2-hybridization and confine π-electrons and spins in a localized area can demonstrate high catalytic potential.
“Theoretical modelling by density functional theory (DFT) further illustrates that defective sites (edge sites, vacancy defects, and voids, etc.) and distorted carbon species that maintain intact sp 2 -hybridization and confine π-electrons and spins in localized area can demonstrate high catalytic potential.57”
From Sustainable remediation with an electroactive biochar system: mechanisms and perspectives (2020) · cites this paper as [57]
PMS molecule can be cleaved into SO4•- over ketonic C=O group.
“Theoretically, the PMS molecule (HO-OSO3 -) was able to be cleaved into SO4 •-over ketonic C=O group.57”
From Sustainable remediation with an electroactive biochar system: mechanisms and perspectives (2020) · cites this paper as [57]
Calcinating temperature was adopted to readily regulate degrees of defects within carbon lattice.
“Calcinating temperature was adopted to readily regulate degrees of defects within carbon lattice.57”
From Sustainable remediation with an electroactive biochar system: mechanisms and perspectives (2020) · cites this paper as [57]
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Self-citation
- Authors
- Duan, X., Sun, H., Ao, Z., Zhou, L., Wang, G., & Wang, S.
- Affiliations
- Curtin University (AU)
- Edith Cowan University (AU)
- University of Technology Sydney (AU)
- Corresponding author
- Sun, Hongqi
- Ao, Zhimin
- Wang, Shaobin
- Venue
- Carbon
- Publisher
- Elsevier BV
- Published
- 2016-10
- Volume
- 107
- Pages
- 371-378
- ISSN
- 0008-6223 (ISSN-L)
- OpenAlex
- W2408898971
- Cited by
- 498
- References
- 43
- Citations by year
- 2026: 32 · 2025: 60 · 2024: 62 · 2023: 61 · 2022: 82 · 2021: 69 · 2020: 53 · 2019: 39 · 2018: 20 · 2017: 17 · 2016: 2
- FWCI
- 15.41
- Type
- journal article
- Language
- en
- Open access
- green
- ro.ecu.edu.au
- Locations
- Carbon (publishedVersion)
- Australasian Journal of Paramedicine (submittedVersion)
- Adelaide Research & Scholarship (AR&S) (University of Adelaide) (submittedVersion)
- eSpace (Curtin University) (submittedVersion)
- Funders
- Australian Research Council (ARC DP130101319, DP150103026)
- National Computational Infrastructure
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Advanced oxidation water treatment
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Advanced Photocatalysis Techniques
- Physical Sciences › Materials Science › Materials Chemistry › Graphene research and applications
- Keywords
- peroxymonosulfate activation, reduced graphene oxide, active site, oxygen vacancies, catalytic oxidation, oxygen-containing functional groups, adsorption energy
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