The DOI matches its Crossref record; 11 of the 11 references it cites were found in a registry or an index.
Electrochemical Fragmentation of Cu2O Nanoparticles Enhancing Selective C–C Coupling from CO2 Reduction Reaction
Abstract
In this study, we demonstrate that the initial morphology of nanoparticles can be transformed into small fragmented nanoparticles, which were densely contacted to each other, during electrochemical CO 2 reduction reaction (CO 2 RR). Cu-based nanoparticles were directly grown on a carbon support by using cysteamine immobilization agent, and the synthesized nanoparticle catalyst showed increasing activity during initial CO 2 RR, doubling Faradaic efficiency of C 2 H 4 production from 27% to 57.3%. The increased C 2 H 4 production activity was related to the morphological transformation over reaction time. Twenty nm cubic Cu 2 O crystalline particles gradually experienced in situ electrochemical fragmentation into 2–4 nm small particles under the negative potential, and the fragmentation was found to be initiated from the surface of the nanocrystal. Compared to Cu@CuO nanoparticle/C or bulk Cu foil, the fragmented Cu-based NP/C catalyst achieved enhanced C 2+ production selectivity, accounting 87% of the total CO 2 RR products, and suppressed H 2 production. In-situ X-ray absorption near edge structure studies showed metallic Cu 0 state was observed under CO 2 RR, but the fragmented nanoparticles were more readily reoxidized at open circuit potential inside of the electrolyte, allowing labile Cu states. The unique morphology, small nanoparticles stacked upon on another, is proposed to promote C–C coupling reaction selectivity from CO 2 RR by suppressing HER.
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Cites
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Highly selective plasma-activated copper catalysts for carbon dioxide reduction to ethylene
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Grain-Boundary-Dependent CO 2 Electroreduction Activity
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Probing the Active Surface Sites for CO Reduction on Oxide-Derived Copper Electrocatalysts
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Enhanced Electrochemical Methanation of Carbon Dioxide with a Dispersible Nanoscale Copper Catalyst
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Subsurface Oxygen in Oxide-Derived Copper Electrocatalysts for Carbon Dioxide Reduction
Eilert, A., Cavalca, F., Roberts, F. S., Osterwalder, J., Liu, C., Favaro, M., Crumlin, E. J., Ogasawara, H., Friebel, D., Pettersson, L. G. M., et al. (2017) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b02273 · Cited by 443
Investigating the Role of Copper Oxide in Electrochemical CO 2 Reduction in Real Time
Mandal, L., Yang, K. R., Motapothula, M. R., Ren, D., Lobaccaro, P., Patra, A., Sherburne, M., Batista, V. S., Yeo, B. S., Ager, J. W., et al. (2018) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b15418 · Cited by 269
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Stability and Effects of Subsurface Oxygen in Oxide-Derived Cu Catalyst for CO 2 Reduction
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Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
Highly active and stable stepped Cu surface for enhanced electrochemical CO2 reduction to C2H4
Choi, C., Kwon, S., Cheng, T., Xu, M., Tieu, P., Lee, C., Cai, J., Lee, H. M., Pan, X., Duan, X., et al. (2020) · Nature Catalysis · doi:10.1038/s41929-020-00504-x · Cited by 592
Self-citationElectrochemical CO2 reduction (CO2RR) to multi-carbon products over copper-based catalysts
Woldu, A. R., Huang, Z., Zhao, P., Hu, L., & Astruc, D. (2022) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2021.214340 · Cited by 578
Boosting electrocatalytic CO2–to–ethanol production via asymmetric C–C coupling
Wang, P., Yang, H., Tang, C., Wu, Y., Zheng, Y., Cheng, T., Davey, K., Huang, X., & Qiao, S.-Z. (2022) · Nature Communications · doi:10.1038/s41467-022-31427-9 · Cited by 574
Stabilizing Cu2+ Ions by Solid Solutions to Promote CO2 Electroreduction to Methane
Zhou, X., Shan, J., Chen, L., Xia, B. Y., Ling, T., Duan, J., Jiao, Y., Zheng, Y., & Qiao, S.-Z. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.1c12212 · Cited by 518
Metadata
- Authors
- Jung, H., Lee, S. Y., Lee, C. W., Cho, M. K., Won, D. H., Kim, C., Oh, H.-S., Min, B. K., & Hwang, Y. J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-01-31
- Volume
- 141
- Issue
- 11
- Pages
- 4624-4633
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2912281710
- Cited by
- 611
- References
- 11
- FWCI
- 14.64
- Type
- journal article
- Language
- en
- Open access
- closed
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