The DOI matches its Crossref record; 34 of the 34 references it cites were found in a registry or an index.
Enhanced Superoxide Generation on Defective Surfaces for Selective Photooxidation
Abstract
Photocatalytic selective oxidation reactions hold great promise for the design of high-value-added organic intermediates, but many of these reactions suffer from low conversion efficiency and selectivity due to uncontrollable oxidation processes. In view of using photogenerated reactive oxygen species as the key oxidant in a selective oxidation reaction, we propose that a highly selective oxidation reaction can be achieved by modulating the corresponding photocatalytic molecular oxygen (O 2 ) activation processes. Using cubic indium sulfide (β-In 2 S 3 ) nanosheets as a model system, we show that the charge carriers involved in O 2 activation can be optimized with the introduction of surface S vacancies. Benefiting from the enhanced charge separation and transfer processes, the In 2 S 3 nanosheets with S vacancies could simultaneously activate O 2 into superoxide radicals via electron transfer under visible-light irradiation to display outstanding activity for the selective oxidation of alcohols to aldehydes with high conversion and selectivity. This study offers a new strategy to optimize photocatalytic selective oxidation reactions.
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Cites
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Self-citationVisible light photocatalysis as a greener approach to photochemical synthesis
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Cited by
Surface Modification of 2D Photocatalysts for Solar Energy Conversion
Feng, C., Wu, Z., Huang, K., Ye, J., & Zhang, H. (2022) · Advanced Materials · doi:10.1002/adma.202200180 · Cited by 456
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Highly active deficient ternary sulfide photoanode for photoelectrochemical water splitting
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Metadata
- Authors
- Sun, X., Luo, X., Zhang, X., Xie, J., Jin, S., Wang, H., Zheng, X., Wu, X., & Xie, Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-02-20
- Volume
- 141
- Issue
- 9
- Pages
- 3797-3801
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2916591823
- Cited by
- 396
- References
- 34
- FWCI
- 9.69
- Type
- journal article
- Language
- en
- Open access
- closed
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- Sun, X., Luo, X., Zhang, X., Xie, J., Jin, S., Wang, H., Zheng, X., Wu, X., & Xie, Y. (2019). Enhanced Superoxide Generation on Defective Surfaces for Selective Photooxidation. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.8b13051
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