The DOI matches its Crossref record; 35 of the 35 references it cites were found in a registry or an index.
Unifying the Hydrogen Evolution and Oxidation Reactions Kinetics in Base by Identifying the Catalytic Roles of Hydroxyl-Water-Cation Adducts
Open accessAbstract
Despite the fundamental and practical significance of the hydrogen evolution and oxidation reactions (HER/HOR), their kinetics in base remain unclear. Herein, we show that the alkaline HER/HOR kinetics can be unified by the catalytic roles of the adsorbed hydroxyl (OH ad )-water-alkali metal cation (AM + ) adducts, on the basis of the observations that enriching the OH ad abundance via surface Ni benefits the HER/HOR; increasing the AM + concentration only promotes the HER, while varying the identity of AM + affects both HER/HOR. The presence of OH ad -(H 2 O) x -AM + in the double-layer region facilitates the OH ad removal into the bulk, forming OH – -(H 2 O) x -AM + as per the hard–soft acid–base theory, thereby selectively promoting the HER. It can be detrimental to the HOR as per the bifunctional mechanism, as the AM + destabilizes the OH ad, which is further supported by the CO oxidation results. This new notion may be important for alkaline electrochemistry.
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Cites
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode
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Chatenet, M., Pollet, B. G., Dekel, D. R., Dionigi, F., Deseure, J., Millet, P., Braatz, R. D., Bazant, M. Z., Eikerling, M., Staffell, I., et al. (2022) · Chemical Society Reviews · doi:10.1039/d0cs01079k · Cited by 2,025
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Zhu, Z., Jiang, T., Ali, M., Meng, Y., Jin, Y., Cui, Y., & Chen, W. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00289 · Cited by 1,769
The hydrogen evolution reaction: from material to interfacial descriptors
Dubouis, N., & Grimaud, A. (2019) · Chemical Science · doi:10.1039/c9sc03831k · Cited by 962
Li, P., Jiang, Y., Hu, Y., Men, Y., Liu, Y., Cai, W., & Chen, S. (2022) · Nature Catalysis · doi:10.1038/s41929-022-00846-8 · Cited by 852
The role of adsorbed hydroxide in hydrogen evolution reaction kinetics on modified platinum
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Metadata
- Authors
- Liu, E., Li, J., Jiao, L., Doan, H. T. T., Liu, Z., Zhao, Z., Huang, Y., Abraham, K. M., Mukerjee, S., & Jia, Q.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-01-23
- Volume
- 141
- Issue
- 7
- Pages
- 3232-3239
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2914655032
- Cited by
- 382
- References
- 35
- FWCI
- 8.40
- Type
- journal article
- Language
- en
- Open access
- green
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- Liu, E., Li, J., Jiao, L., Doan, H. T. T., Liu, Z., Zhao, Z., Huang, Y., Abraham, K. M., Mukerjee, S., & Jia, Q. (2019). Unifying the Hydrogen Evolution and Oxidation Reactions Kinetics in Base by Identifying the Catalytic Roles of Hydroxyl-Water-Cation Adducts. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.8b13228
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