The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Cobalt-Modulated Molybdenum–Dinitrogen Interaction in MoS2 for Catalyzing Ammonia Synthesis
Open accessAbstract
Dinitrogen conversion to ammonia via electrochemical reduction with over 10% Faradaic efficiency is demonstrated in this work. Co-doped MoS 2- x polycrystalline nanosheets with S vacancies as the catalysts are loaded onto carbon cloth by hydrothermal growth from Mo, Co, and S precursors. A sulfur vacancy on the MoS 2- x basal plane mimicking the natural Mo-nitrogenase active site is modified by Co doping and exhibits superior dinitrogen-to-ammonia conversion activity. Density-functional simulation reveals that the free energy barrier, which can be compensated by applied overpotential, is reduced from 1.62 to 0.59 eV after Co doping. Meanwhile, dinitrogen tends to be chemically adsorbed to defective MoS 2- x, which effectively activates the dinitrogen molecule for the dissociation of the N≡N triple bond. This process is further accelerated by Co doping, resulting from the modulation of Mo–N bonding configuration.
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Cites
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode
Nørskov, J. K., Rossmeisl, J., Logadottir, A., Lindqvist, L., Kitchin, J. R., Bligaard, T., & Jónsson, H. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp047349j · Cited by 13,153
Identification of Active Edge Sites for Electrochemical H 2 Evolution from MoS 2 Nanocatalysts
Jaramillo, T. F., Jørgensen, K. P., Bonde, J., Nielsen, J. H., Horch, S., & Chorkendorff, I. (2007) · Science · doi:10.1126/science.1141483 · Cited by 6,100
Structure–function relationships of alternative nitrogenases
Eady, R. R. (1996) · Chemical Reviews · doi:10.1021/cr950057h · Cited by 877
Cited by
Ammonia and Nitric Acid Demands for Fertilizer Use in 2050
Lim, J., Fernández, C. A., Lee, S. W., & Hatzell, M. C. (2021) · ACS Energy Letters · doi:10.1021/acsenergylett.1c01614 · Cited by 523
Comprehensive Understanding of the Thriving Ambient Electrochemical Nitrogen Reduction Reaction
Zhao, X., Hu, G., Chen, G., Zhang, H., Zhang, S., & Wang, H. (2021) · Advanced Materials · doi:10.1002/adma.202007650 · Cited by 503
Roadmap and Direction toward High-Performance MoS 2 Hydrogen Evolution Catalysts
Cao, Y. (2021) · ACS Nano · doi:10.1021/acsnano.1c01879 · Cited by 405
Bo, Y., Wang, H., Lin, Y., Yang, T., Ye, R., Li, Y., Hu, C., Du, P., Hu, Y., Liu, Z., et al. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202104001 · Cited by 355
Self-citationLiu, W., Luo, C., Zhang, S., Zhang, B., Ma, J., Wang, X., Liu, W., Li, Z., Yang, Q.-H., & Lv, W. (2021) · ACS Nano · doi:10.1021/acsnano.1c00896 · Cited by 269
Metadata
- Authors
- Zhang, J., Tian, X., Liu, M., Guo, H., Zhou, J., Fang, Q., Liu, Z., Wu, Q., & Lou, J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-11-08
- Volume
- 141
- Issue
- 49
- Pages
- 19269-19275
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2983000192
- Cited by
- 248
- References
- 3
- FWCI
- 7.38
- Type
- journal article
- Language
- en
- Open access
- green
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- Zhang, J., Tian, X., Liu, M., Guo, H., Zhou, J., Fang, Q., Liu, Z., Wu, Q., & Lou, J. (2019). Cobalt-Modulated Molybdenum–Dinitrogen Interaction in MoS2 for Catalyzing Ammonia Synthesis. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.9b02501
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