The DOI matches its Crossref record; 22 of the 22 references it cites were found in a registry or an index.
Tunable Redox Chemistry and Stability of Radical Intermediates in 2D Covalent Organic Frameworks for High Performance Sodium Ion Batteries
Abstract
Radicals are inevitable intermediates during the charging and discharging of organic redox electrodes. The increase of the reactivity of the radical intermediates is desirable to maximize the capacity and enhance the rate capability but is detrimental to cycling stability. Therefore, it is a great challenge to controllably balance the redox reactivity and stability of radical intermediates to optimize the electrochemical properties with a good combination of high specific capacity, excellent rate capability, and long-term cycle life. Herein, we reported the redox and tunable stability of radical intermediates in covalent organic frameworks (COFs) considered as high capacity and stable anode for sodium-ion batteries. The comprehensive characterizations combined with theoretical simulation confirmed that the redox of C-O· and α-C radical intermediates play an important role in the sodiation/desodiation process. Specifically, the stacking behavior could be feasibly tuned by the thickness of 2D COFs, essentially determining the redox reactivity and stability of the α-C radical intermediates and their contributive capacity. The modulation of reversible redox chemistry and stabilization mechanism of radical intermediates in COFs offers a novel entry to design novel high performance organic electrode materials for energy storage and conversion.
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Cites
β-Ketoenamine-Linked Covalent Organic Frameworks Capable of Pseudocapacitive Energy Storage
DeBlase, C. R., Silberstein, K. E., Truong, T.-T., Abruña, H. D., & Dichtel, W. R. (2013) · Journal of the American Chemical Society · doi:10.1021/ja409421d · Cited by 1,249
Wang, S., Wang, Q., Shao, P., Han, Y., Gao, X., Ma, L., Yuan, S., Ma, X., Zhou, J., Feng, X., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b02648 · Cited by 1,030
Peng, C., Ning, G.-H., Su, J., Zhong, G., Tang, W., Tian, B., Su, C., Yu, D., Zu, L., Yang, J., et al. (2017) · Nature Energy · doi:10.1038/nenergy.2017.74 · Cited by 713
Boosting lithium storage in covalent organic framework via activation of 14-electron redox chemistry
Lei, Z., Yang, Q., Xu, Y. W., Guo, S., Sun, W., Liu, H., Lv, L., Zhang, Y., & Wang, Y. (2018) · Nature Communications · doi:10.1038/s41467-018-02889-7 · Cited by 692
Li, Y., Lu, Y., Zhao, C., Hu, Y.-S., Titirici, M.-M., Li, H., Huang, X., & Chen, L. (2017) · Energy Storage Materials · doi:10.1016/j.ensm.2017.01.002 · Cited by 642
Self-citationMorita, Y., Nishida, S., Murata, T., Moriguchi, M., Ueda, A., Satoh, M., Arifuku, K., Sato, K., & Takui, T. (2011) · Nature Materials · doi:10.1038/nmat3142 · Cited by 568
Advanced Organic Electrode Materials for Rechargeable Sodium‐Ion Batteries
Zhao, Q., Lu, Y., & Chen, J. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201601792 · Cited by 551
Self-citationRoutes to High Energy Cathodes of Sodium‐Ion Batteries
Fang, C., Huang, Y., Zhang, W., Han, J., Deng, Z., Cao, Y., & Yang, H. (2015) · Advanced Energy Materials · doi:10.1002/aenm.201501727 · Cited by 531
He, J., Wang, N., Cui, Z., Du, H., Fu, L., Huang, C., Yang, Z., Shen, X., Yi, Y., Tu, Z., et al. (2017) · Nature Communications · doi:10.1038/s41467-017-01202-2 · Cited by 479
Self-citationXu, F., Xu, H., Chen, X., Wu, D., Wu, Y., Liu, H., Gu, C., Fu, R., & Jiang, D. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201501706 · Cited by 449
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Covalent Organic Framework Photocatalysts: Structures and Applications
Wang, H., Wang, H., Wang, Z., Tang, L., Zeng, G., Xu, P., Chen, M., Xiong, T., Zhou, C., Li, X., et al. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00278j · Cited by 1,301
Self-citationLiu, R., Tan, K. T., Gong, Y., Chen, Y., Li, Z., Xie, S., He, T., Lu, Z., Yang, H., & Jiang, D. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00620c · Cited by 1,083
Self-citationOpportunities and Challenges for Organic Electrodes in Electrochemical Energy Storage
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Sun, T., Xie, J., Guo, W., Li, D., & Zhang, Q. (2020) · Advanced Energy Materials · doi:10.1002/aenm.201904199 · Cited by 622
Design Strategies to Enable the Efficient Use of Sodium Metal Anodes in High‐Energy Batteries
Sun, B., Xiong, P., Maitra, U., Langsdorf, D., Yan, K., Wang, C., Janek, J., Schröder, D., & Wang, G. (2020) · Advanced Materials · doi:10.1002/adma.201903891 · Cited by 355
Zinc ion interactions in a two-dimensional covalent organic framework based aqueous zinc ion battery
Khayum M, A., Ghosh, M., Vijayakumar, V., Halder, A., Nurhuda, M., Kumar, S., Addicoat, M., Kurungot, S., & Banerjee, R. (2019) · Chemical Science · doi:10.1039/c9sc03052b · Cited by 322
An Ultrafast, Energy‐Efficient Electrochromic and Thermochromic Device for Smart Windows
Deng, B., Zhu, Y., Wang, X., Zhu, J., Liu, M., Liu, M., He, Y., Zhu, C., Zhang, C., & Meng, H. (2023) · Advanced Materials · doi:10.1002/adma.202302685 · Cited by 259
Self-citationLiu, S., Wang, M., He, Y., Cheng, Q., Qian, T., & Yan, C. (2023) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2022.214882 · Cited by 236
Metadata
- Authors
- Gu, S., Wu, S., Cao, L., Li, M., Qin, N., Zhu, J., Wang, Z., Li, Y., Li, Z., Chen, J., & Lu, Z.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-05-23
- Volume
- 141
- Issue
- 24
- Pages
- 9623-9628
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2945117870
- Cited by
- 396
- References
- 22
- FWCI
- 17.36
- Type
- journal article
- Language
- en
- Open access
- closed
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