The DOI matches its Crossref record; 48 of the 48 references it cites were found in a registry or an index.
Scalable Production of Efficient Single-Atom Copper Decorated Carbon Membranes for CO2 Electroreduction to Methanol
Abstract
Electrocatalytic reduction reaction of CO 2 (CO 2 RR) is an effective way to mitigate energy and environmental issues. However, very limited catalysts are capable of converting CO 2 resources into high-value products such as hydrocarbons or alcohols. Herein, we first propose a facile strategy for the large-scale synthesis of isolated Cu decorated through-hole carbon nanofibers (CuSAs/TCNFs). This CuSAs/TCNFs membrane has excellent mechanical properties and can be directly used as cathode for CO 2 RR, which could generate nearly pure methanol with 44% Faradaic efficiency in liquid phase. The self-supporting and through-hole structure of CuSAs/TCNFs greatly reduces the embedded metal atoms and produces abundant efficient Cu single atoms, which could actually participate in CO 2 RR, eventually causing −93 mA cm –2 partial current density for C1 products and more than 50 h stability in aqueous solution. According to DFT calculations, Cu single atoms possess a relatively higher binding energy for *CO intermediate. Therefore, *CO could be further reduced to products like methanol, instead of being easily released from the catalyst surface as CO product. This report may benefit the design of efficient and high-yield single-atom catalysts for other electrocatalytic reactions.
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Cites
How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels
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Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction
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Self-citationEnhanced electrocatalytic CO2 reduction via field-induced reagent concentration
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Activity Descriptors for CO 2 Electroreduction to Methane on Transition-Metal Catalysts
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Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces
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Self-citationDopant-induced electron localization drives CO2 reduction to C2 hydrocarbons
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Cited by
Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
Recent Advances in MOF‐Derived Single Atom Catalysts for Electrochemical Applications
Song, Z., Zhang, L., Doyle‐Davis, K., Fu, X., Luo, J., & Sun, X. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202001561 · Cited by 412
Fundamentals and challenges of ultrathin 2D photocatalysts in boosting CO2 photoreduction
Jiao, X., Zheng, K., Liang, L., Li, X., Sun, Y., & Xie, Y. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00332h · Cited by 394
Hu, Q., Han, Z., Wang, X., Li, G., Wang, Z., Huang, X., Yang, H., Ren, X., Zhang, Q., Liu, J., et al. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202009277 · Cited by 241
Self-citationCheng, Z., Wang, X., Yang, H., Yu, X., Lin, Q., Hu, Q., & He, C. (2021) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2020.04.018 · Cited by 33
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Metadata
- Authors
- Yang, H., Wu, Y., Li, G., Lin, Q., Hu, Q., Zhang, Q., Liu, J., & He, C.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-07-26
- Volume
- 141
- Issue
- 32
- Pages
- 12717-12723
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2964641221
- Cited by
- 788
- References
- 48
- FWCI
- 19.17
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yang, H., Wu, Y., Li, G., Lin, Q., Hu, Q., Zhang, Q., Liu, J., & He, C. (2019). Scalable Production of Efficient Single-Atom Copper Decorated Carbon Membranes for CO2 Electroreduction to Methanol. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.9b04907
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