The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Ensemble Effect in Bimetallic Electrocatalysts for CO2 Reduction
Abstract
Alloying is an important strategy for the design of catalytic materials beyond pure metals. The conventional alloy catalysts however lack precise control over the local atomic structures of active sites. Here we report on an investigation of the active-site ensemble effect in bimetallic Pd–Au electrocatalysts for CO 2 reduction. A series of Pd@Au electrocatalysts are synthesized by decorating Au nanoparticles with Pd of controlled doses, giving rise to bimetallic surfaces containing Pd ensembles of various sizes. Their catalytic activity for electroreduction of CO 2 to CO exhibits a nonlinear behavior in dependence of the Pd content, which is attributed to the variation of Pd ensemble size and the corresponding tuning of adsorption properties. Density functional theory calculations reveal that the Pd@Au electrocatalysts with atomically dispersed Pd sites possess lower energy barriers for activation of CO 2 than pure Au and are also less poisoned by strongly binding *CO intermediates than pure Pd, with an intermediate ensemble size of active sites, such as Pd dimers, giving rise to the balance between these two rate-limiting factors and achieving the highest activity for CO 2 reduction.
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Cites
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO 2 Fixation
Appel, A. M., Bercaw, J. E., Bocarsly, A. B., Dobbek, H., DuBois, D. L., Dupuis, M., Ferry, J. G., Fujita, E., Hille, R., Kenis, P. J. A., et al. (2013) · Chemical Reviews · doi:10.1021/cr300463y · Cited by 2,193
Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
Li, C. W., Ciston, J., & Kanan, M. W. (2014) · Nature · doi:10.1038/nature13249 · Cited by 1,728
Self-citationActivity Descriptors for CO 2 Electroreduction to Methane on Transition-Metal Catalysts
Peterson, A. A., & Nørskov, J. K. (2012) · The Journal of Physical Chemistry Letters · doi:10.1021/jz201461p · Cited by 1,667
Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces
Kuhl, K. P., Hatsukade, T., Cave, E. R., Abram, D. N., Kibsgaard, J., & Jaramillo, T. F. (2014) · Journal of the American Chemical Society · doi:10.1021/ja505791r · Cited by 1,649
General Techno-Economic Analysis of CO 2 Electrolysis Systems
Jouny, M., Luc, W., & Jiao, F. (2018) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.7b03514 · Cited by 1,628
What Should We Make with CO2 and How Can We Make It?
Bushuyev, O. S., De Luna, P., Dinh, C. T., Tao, L., Saur, G., van de Lagemaat, J., Kelley, S. O., & Sargent, E. H. (2018) · Joule · doi:10.1016/j.joule.2017.09.003 · Cited by 1,593
Intermetallic Alloys as CO Electroreduction Catalysts—Role of Isolated Active Sites
Karamad, M., Tripkovic, V., & Rossmeisl, J. (2014) · ACS Catalysis · doi:10.1021/cs500328c · Cited by 125
Importance of electronic ligand effects in metal alloy catalysts
Burch, R. (1982) · Accounts of Chemical Research · doi:10.1021/ar00073a004 · Cited by 104
Cited by
Gu, J., Liu, S., Ni, W., Ren, W., Haussener, S., & Hu, X. (2022) · Nature Catalysis · doi:10.1038/s41929-022-00761-y · Cited by 846
Liu, L., & Corma, A. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00733 · Cited by 689
Single‐atom catalysis for carbon neutrality
Wang, L., Wang, D., & Li, Y. (2022) · Carbon Energy · doi:10.1002/cey2.194 · Cited by 293
Recent Progress on Rational Design of Bimetallic Pd Based Catalysts and Their Advanced Catalysis
Fan, J., Du, H., Zhao, Y., Wang, Q., Liu, Y., Li, D., & Feng, J. (2020) · ACS Catalysis · doi:10.1021/acscatal.0c03280 · Cited by 265
Ternary Sn‐Ti‐O Electrocatalyst Boosts the Stability and Energy Efficiency of CO2 Reduction
Wen, G., Ren, B., Park, M. G., Yang, J., Dou, H., Zhang, Z., Deng, Y., Bai, Z., Yang, L., Gostick, J., et al. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202004149 · Cited by 97
Metadata
- Authors
- Wang, Y., Cao, L., Libretto, N. J., Li, X., Li, C., Wan, Y., He, C., Lee, J., Gregg, J., Zong, H., Su, D., Miller, J. T., Mueller, T., & Wang, C.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-09-11
- Volume
- 141
- Issue
- 42
- Pages
- 16635-16642
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2973160985
- Cited by
- 345
- References
- 8
- FWCI
- 7.94
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, Y., Cao, L., Libretto, N. J., Li, X., Li, C., Wan, Y., He, C., Lee, J., Gregg, J., Zong, H., Su, D., Miller, J. T., Mueller, T., & Wang, C. (2019). Ensemble Effect in Bimetallic Electrocatalysts for CO2 Reduction. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.9b05766
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