The DOI matches its Crossref record; 23 of the 23 references it cites were found in a registry or an index.
Metal–Organic Framework Coating Enhances the Performance of Cu2O in Photoelectrochemical CO2 Reduction
Abstract
Photoelectrochemical (PEC) reduction of CO 2 into chemical fuels and chemical building blocks is a promising strategy for addressing the energy and environmental challenges, which relies on the development of p-type photocathodes. Cu 2 O is such a p-type semiconductor for photocathodes but commonly suffers from detrimental photocorrosion and chemical changes. In this communication, we develop a facile procedure for coating a metal–organic framework (MOF) on the surface of a Cu 2 O photocathode, which can both prevent photocorrosion and offer active sites for CO 2 reduction. As evidenced by ultrafast spectroscopy, the formed interface can effectively promote charge separation and transfer. As a result, both the activity and durability of Cu 2 O are dramatically enhanced for PEC CO 2 reduction. This work provides fresh insights into the design of advanced hybrid photoelectrodes and highlights the important role of interfacial charge dynamics in PEC CO 2 conversion.
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Self-citation
Metadata
- Authors
- Deng, X., Li, R., Wu, S., Wang, L., Hu, J., Ma, J., Jiang, W., Zhang, N., Zheng, X., Gao, C., Wang, L., Zhang, Q., Zhu, J., & Xiong, Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-06-14
- Volume
- 141
- Issue
- 27
- Pages
- 10924-10929
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2951075750
- Cited by
- 322
- References
- 23
- FWCI
- 7.83
- Type
- journal article
- Language
- en
- Open access
- closed
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