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Cited by 239

The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.

Constructing High-Loading Single-Atom/Cluster Catalysts via an Electrochemical Potential Window Strategy

Liu, Jin-Cheng, Xiao, Hai, Li, Jun·2020·Journal of the American Chemical Society

Abstract

Single-atom catalysts (SACs) and single-cluster catalysts (SCCs) are the new frontier of heterogeneous catalysis, which exhibit high activity, selectivity, stability, and atomic efficiency as well as precise tunability. However, the lack of efficient methods for producing high-loading and high-purity SACs and SCCs hinders their industrial applications. In this work, we propose a general and efficient strategy for the production of high-loading and high-purity SACs and SCCs anchored on suitable substrates. Our strategy relies on the existence of an electrochemical potential window (EcPW) we predict within which any aggregate forms of the target metal on the substrate are leached away by electrochemical oxidation, while the strongly bound single atoms or single clusters remain at the substrate. We demonstrate the applicability of this strategy with modeling the production of Pt, Pd, and Ni SACs anchored on N-doped graphene and Fe 2 O 3 as well as Pt 3 and Ni 3 SCCs anchored on graphdiyne.

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Metadata

Authors
Liu, J.-C., Xiao, H., & Li, J.
Venue
Journal of the American Chemical Society
Published
2020-01-29
Volume
142
Issue
7
Pages
3375-3383
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W3004328904
Cited by
239
References
8
FWCI
12.96
Type
journal article
Language
en
Open access
closed

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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