The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Cascade Reactions in Nanozymes: Spatially Separated Active Sites inside Ag-Core–Porous-Cu-Shell Nanoparticles for Multistep Carbon Dioxide Reduction to Higher Organic Molecules
Open accessAbstract
Abstract Enzymes can perform complex multistep cascade reactions by linking multiple distinct catalytic sites via substrate channeling. We mimic this feature in a generalized approach with an electrocatalytic nanoparticle for the carbon dioxide reduction reaction comprising a Ag core surrounded by a porous Cu shell, providing different active sites in nanoconfined volumes. The architecture of the nanozyme provides the basis for a cascade reaction, which promotes C–C coupling reactions. The first step occurs on the Ag core, and the subsequent steps on the porous copper shell, where a sufficiently high CO concentration due to the nanoconfinement facilitates C–C bond formation. The architecture yields the formation of n-propanol and propionaldehyde at potentials as low as −0.6 V vs RHE.
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Cites
Li, C. W., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3010978 · Cited by 2,000
Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
Li, C. W., Ciston, J., & Kanan, M. W. (2014) · Nature · doi:10.1038/nature13249 · Cited by 1,728
Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces
Kuhl, K. P., Hatsukade, T., Cave, E. R., Abram, D. N., Kibsgaard, J., & Jaramillo, T. F. (2014) · Journal of the American Chemical Society · doi:10.1021/ja505791r · Cited by 1,649
Hori, Y., Kikuchi, K., & Suzuki, S. (1985) · Chemistry Letters · doi:10.1246/cl.1985.1695 · Cited by 1,401
Ma, M., Trześniewski, B. J., Xie, J., & Smith, W. A. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201604654 · Cited by 530
Importance of Ag–Cu Biphasic Boundaries for Selective Electrochemical Reduction of CO2to Ethanol
Lee, S., Park, G., & Lee, J. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b02822 · Cited by 391
Investigating the Role of Copper Oxide in Electrochemical CO 2 Reduction in Real Time
Mandal, L., Yang, K. R., Motapothula, M. R., Ren, D., Lobaccaro, P., Patra, A., Sherburne, M., Batista, V. S., Yeo, B. S., Ager, J. W., et al. (2018) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b15418 · Cited by 269
Tailoring gas-phase CO 2 electroreduction selectivity to hydrocarbons at Cu nanoparticles
Merino-Garcia, I., Albo, J., & Irabien, A. (2018) · Nanotechnology · doi:10.1088/1361-6528/aa994e · Cited by 129
Cited by
Xiao, C., & Zhang, J. (2021) · ACS Nano · doi:10.1021/acsnano.0c10697 · Cited by 371
Metal–Organic‐Framework‐Engineered Enzyme‐Mimetic Catalysts
Ma, L., Jiang, F., Fan, X., Wang, L., He, C., Zhou, M., Li, S., Luo, H., Cheng, C., & Qiu, L. (2020) · Advanced Materials · doi:10.1002/adma.202003065 · Cited by 298
Liu, C., Wu, Y., Sun, K., Fang, J., Huang, A., Pan, Y., Cheong, W.-C., Zhuang, Z., Zhuang, Z., Yuan, Q., et al. (2021) · Chem · doi:10.1016/j.chempr.2021.02.001 · Cited by 253
Metadata
- Authors
- O’Mara, P. B., Wilde, P., Benedetti, T. M., Andronescu, C., Cheong, S., Gooding, J. J., Tilley, R. D., & Schuhmann, W.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-08-25
- Volume
- 141
- Issue
- 36
- Pages
- 14093-14097
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2969350875
- Cited by
- 219
- References
- 8
- FWCI
- 4.95
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- O’Mara, P. B., Wilde, P., Benedetti, T. M., Andronescu, C., Cheong, S., Gooding, J. J., Tilley, R. D., & Schuhmann, W. (2019). Cascade Reactions in Nanozymes: Spatially Separated Active Sites inside Ag-Core–Porous-Cu-Shell Nanoparticles for Multistep Carbon Dioxide Reduction to Higher Organic Molecules. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.9b07310
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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