Production of CO and CH4 in electrochemical reduction of CO2 at metal electrodes in aqueous hydrogencarbonate solution
Abstract
Abstract The total analysis of gaseous and soluble products was carried out in the electrochemical reduction of CO2 (current density 5 mA cm−2) on various electrode metals. HCOO− was predominantly produced at Cd, In, Sn, and Pb cathodes. Ag and Au principally gave CO. CH4 was formed in an appreciable amount at Cu cathode.
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Since pioneering works by Hori et al., massive efforts have been devoted to boost catalytic performance of electrochemical CO2RR, especially within the past decade.
“Since the pioneering works by Hori et al.,313,314 massive efforts have been devoted to boost the catalytic performance of electrochemical CO2RR, especially within the past decade.315, 316, 317, 318, 319, 320, 321”
From Technologies and perspectives for achieving carbon neutrality (2021) · cites this paper as [314]
Cites
Halmann, M. M. (1978) · Nature · doi:10.1038/275115a0 · Cited by 1,006 · see citing works
Electrocatalytic reduction of carbon dioxide by using macrocycles of nickel and cobalt
Fisher, B. J., & Eisenberg, R. (1980) · Journal of the American Chemical Society · doi:10.1021/ja00544a035 · Cited by 560 · see citing works
Catalytic reduction of carbon dioxide at carbon electrodes modified with cobalt phthalocyanine
Lieber, C. M., & Lewis, N. S. (1984) · Journal of the American Chemical Society · doi:10.1021/ja00329a082 · Cited by 316 · see citing works
Electrochemical Reduction of Carbon Dioxide to Methane, Methanol, and CO on Ru Electrodes
Frese, K. W., & Leach, S. C. (1985) · Journal of The Electrochemical Society · doi:10.1149/1.2113780 · Cited by 155 · see citing works
Reduction of Carbon Dioxide on Mercury Cathodes
Teeter, T. E., & Rysselberghe, P. V. (1954) · The Journal of Chemical Physics · doi:10.1063/1.1740178 · Cited by 138 · see citing works
Canfield, D., & Frese, K. W. (1983) · Journal of The Electrochemical Society · doi:10.1149/1.2120090 · Cited by 128 · see citing works
Electrochemistry of carbon dioxide in dimethyl sulfoxide at gold and mercury electrodes
Haynes, L. V., & Sawyer, D. T. (1967) · Analytical Chemistry · doi:10.1021/ac60247a013 · Cited by 115 · see citing works
Electroreduction of carbon dioxide catalyzed by iron-sulfur cluster compounds [Fe4S4(SR)4]2-
Tezuka, M., Yajima, T., Tsuchiya, A., Matsumoto, Y., Uchida, Y., & Hidai, M. (1982) · Journal of the American Chemical Society · doi:10.1021/ja00388a085 · Cited by 100 · see citing works
Zum Mechanismus der elektrochemischen Dimerisierung von CO 2 zu Oxalsäure
Kaiser, U., & Heitz, E. (1973) · Berichte der Bunsengesellschaft für physikalische Chemie · doi:10.1002/bbpc.19730771018 · Cited by 94 · see citing works
The reduction of carbon dioxide at illuminated p-type semiconductor electrodes in nonaqueous media
Taniguchi, I., Aurian‐Blajeni, B., & Bockris, J. O. (1984) · Electrochimica Acta · doi:10.1016/0013-4686(84)87137-6 · Cited by 79 · see citing works
Reduction of CO 2 on n ‐ GaAs Electrodes and Selective Methanol Synthesis
Frese, K. W., & Canfield, D. (1984) · Journal of The Electrochemical Society · doi:10.1149/1.2115351 · Cited by 77 · see citing works
Ito, K., Ikeda, S., Iida, T., & NOMURA, A. (1982) · Denki Kagaku oyobi Kogyo Butsuri Kagaku · doi:10.5796/kogyobutsurikagaku.50.463 · Cited by 54 · see citing works
Taniguchi, Y., Hiroshi Yoneyama, C., & Tamura, H. (1982) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.55.2034 · Cited by 45 · see citing works
Ito, K., Ikeda, S., Yoshida, M., et al. (1984) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.57.583 · Cited by 36 · see citing works
On the electrolytic reduction of carbon dioxide at TiO2 and TiO2-Ru Cathodes
Monnier, A., Augustyński, J., & Stalder, C. J. (1980) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(80)80420-7 · Cited by 32 · see citing works
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Progress and perspectives of electrochemical CO2 reduction on copper in aqueous electrolyte
Nitopi, S., Bertheussen, E., Scott, S. B., Liu, X., Engstfeld, A. K., Horch, S., Seger, B., Stephens, I. E. L., Chan, K., Hahn, C., et al. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00705 · Cited by 5,223 · see citing works
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
Kuhl, K. P., Cave, E. R., Abram, D. N., & Jaramillo, T. F. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21234j · Cited by 3,160 · see citing works
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
Qiao, J., Liu, Y., Hong, F., & Zhang, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60323g · Cited by 2,990 · see citing works
Li, C. W., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3010978 · Cited by 2,000 · see citing works
Activity Descriptors for CO <sub>2</sub> Electroreduction to Methane on Transition-Metal Catalysts
Peterson, A. A., & Nørskov, J. K. (2012) · The Journal of Physical Chemistry Letters · doi:10.1021/jz201461p · Cited by 1,667 · see citing works
Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces
Kuhl, K. P., Hatsukade, T., Cave, E. R., Abram, D. N., Kibsgaard, J., & Jaramillo, T. F. (2014) · Journal of the American Chemical Society · doi:10.1021/ja505791r · Cited by 1,649 · see citing works
Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide
Zhu, D. D., Liu, J. L., & Qiao, S. Z. (2016) · Advanced Materials · doi:10.1002/adma.201504766 · Cited by 1,594 · see citing works
Technologies and perspectives for achieving carbon neutrality
Wang, F., Harindintwali, J. D., Yuan, Z., Wang, M., Wang, F., Li, S., Yin, Z., Huang, L., Fu, Y., Li, L., et al. (2021) · The Innovation · doi:10.1016/j.xinn.2021.100180 · Cited by 1,330 · see citing works
Electrocatalysis for CO <sub>2</sub> conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295 · see citing works
Highly selective plasma-activated copper catalysts for carbon dioxide reduction to ethylene
Mistry, H., Varela, A. S., Bonifacio, C. S., Zegkinoglou, I., Sinev, I., Choi, Y.-W., Kisslinger, K., Stach, E. A., Yang, J. C., Strasser, P., et al. (2016) · Nature Communications · doi:10.1038/ncomms12123 · Cited by 1,214 · see citing works
Calle‐Vallejo, F., & Koper, M. T. M. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201301470 · Cited by 941 · see citing works
Goodpaster, J. D., Bell, A. T., & Head-Gordon, M. (2016) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b00358 · Cited by 702 · see citing works
Mistry, H., Reske, R., Zeng, Z., Zhao, Z.-J., Greeley, J., Strasser, P., & Cuenya, B. R. (2014) · Journal of the American Chemical Society · doi:10.1021/ja508879j · Cited by 690 · see citing works
Theoretical Insights into Heterogeneous (Photo)electrochemical CO<sub>2</sub>Reduction
Xu, S., & Carter, E. A. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00481 · Cited by 652 · see citing works
Gupta, N., Gattrell, M., & MacDougall, B. (2006) · Journal of Applied Electrochemistry · doi:10.1007/s10800-005-9058-y · Cited by 558 · see citing works
Enhanced Electrochemical Methanation of Carbon Dioxide with a Dispersible Nanoscale Copper Catalyst
Manthiram, K., Beberwyck, B. J., & Alivisatos, A. P. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5065284 · Cited by 546 · see citing works
Active Sites of Au and Ag Nanoparticle Catalysts for CO2 Electroreduction to CO
Back, S., Yeom, M. S., & Jung, Y. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00462 · Cited by 545 · see citing works
Kas, R., Kortlever, R., Yılmaz, H., Koper, M. T. M., & Mul, G. (2015) · ChemElectroChem · doi:10.1002/celc.201402373 · Cited by 464 · see citing works
Lim, R. J., Xie, M., Sk, M. A., Lee, J.-M., Fisher, A., Wang, X., & Lim, K. H. (2014) · Catalysis Today · doi:10.1016/j.cattod.2013.11.037 · Cited by 460 · see citing works
Xiao, H., Cheng, T., & Goddard, W. A. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b06846 · Cited by 458 · see citing works
Cheng, T., Xiao, H., & Goddard, W. A. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b08534 · Cited by 453 · see citing works
Highly Dense Cu Nanowires for Low-Overpotential CO <sub>2</sub> Reduction
Raciti, D., Livi, K. J., & Wang, C. (2015) · Nano Letters · doi:10.1021/acs.nanolett.5b03298 · Cited by 395 · see citing works
Torelli, D. A., Francis, S. A., Crompton, J. C., Javier, A., Thompson, J. R., Brunschwig, B. S., Soriaga, M. P., & Lewis, N. S. (2016) · ACS Catalysis · doi:10.1021/acscatal.5b02888 · Cited by 306 · see citing works
Li, Y., Su, H., Chan, S. H., & Sun, Q. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b01165 · Cited by 265 · see citing works
Jeanty, P., Scherer, C., Magori, E., Wiesner-Fleischer, K., Hinrichsen, O., & Fleischer, M. (2018) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2018.01.011 · Cited by 224 · see citing works
Larrazábal, G. O., Martín, A. J., & Pérez-Ramírez, J. (2017) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.7b01380 · Cited by 176 · see citing works
Intermetallic Alloys as CO Electroreduction Catalysts—Role of Isolated Active Sites
Karamad, M., Tripkovic, V., & Rossmeisl, J. (2014) · ACS Catalysis · doi:10.1021/cs500328c · Cited by 125 · see citing works
Wen, G., Ren, B., Park, M. G., Yang, J., Dou, H., Zhang, Z., Deng, Y., Bai, Z., Yang, L., Gostick, J., et al. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202004149 · Cited by 97 · see citing works
Dewulf, D. W., & Bard, A. J. (1988) · Catalysis Letters · doi:10.1007/bf00765357 · Cited by 91 · see citing works
Carbon dioxide reduction at low temperature on various metal electrodes
Azuma, M., Hashimoto, K., Hiramoto, M., Watanabe, M., & Sakata, T. (1989) · Journal of Electroanalytical Chemistry and Interfacial Electrochemistry · doi:10.1016/0022-0728(89)87158-x · Cited by 89 · see citing works
Effect of pressure on the electrochemical reduction of CO2 on Group VIII metal electrodes
Nakagawa, S., Kudo, A., Azuma, M., & Sakata, T. (1991) · Journal of Electroanalytical Chemistry and Interfacial Electrochemistry · doi:10.1016/0022-0728(91)85080-9 · Cited by 86 · see citing works
Komatsu, S., Tanaka, M., Okumura, A., & Kungi, A. (1995) · Electrochimica Acta · doi:10.1016/0013-4686(94)00325-u · Cited by 83 · see citing works
Electrochemical CO2 reduction on a glassy carbon electrode under high pressure
Hara, K., Kudo, A., & Sakata, T. (1997) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(96)01028-5 · Cited by 73 · see citing works
De Jesús-Cardona, H., del Moral, C., & Cabrera, C. R. (2001) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(01)00598-8 · Cited by 54 · see citing works
Influence of Electrolytes and Membranes on Cell Operation for Syn-Gas Production
Dufek, E. J., Lister, T. E., & McIlwain, M. E. (2012) · Electrochemical and Solid-State Letters · doi:10.1149/2.010204esl · Cited by 45 · see citing works
Maliutina, K. M., Omoriyekomwan, J. E., He, C., Fan, L., & Folli, A. (2023) · Frontiers in Environmental Engineering · doi:10.3389/fenve.2023.1228992 · Cited by 35 · see citing works
- Authors
- Hori, Y., Kikuchi, K., & Suzuki, S.
- Affiliations
- Chiba University (JP)
- ORCID
- Suzuki, Shin
- Venue
- Chemistry Letters
- Publisher
- Oxford University Press (OUP)
- Published
- 1985-11
- Volume
- 14
- Issue
- 11
- Pages
- 1695-1698
- ISSN
- 0366-7022 (ISSN-L)
- 1348-0715
- OpenAlex
- W2063031338
- Cited by
- 1,401
- References
- 15
- Citations by year
- 2026: 66 · 2025: 117 · 2024: 112 · 2023: 113 · 2022: 119 · 2021: 130 · 2020: 121 · 2019: 107 · 2018: 88 · 2017: 77 · 2016: 70 · 2015: 40 · 2014: 39 · 2013: 24 · 2012: 19
- FWCI
- 0.62
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemistry Letters (publishedVersion)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Keywords
- electrochemical CO2 reduction, carbon monoxide production, methane production, formate production, metal electrodes, electrode materials, silver electrodes, gold electrode, copper electrode, cadmium electrode, indium electrode, TiN electrodes, lead electrode
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