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Phosphonium-Based Ionic Liquids Analogues and Their Physical Properties
Abstract
New ionic liquids analogues, that is, deep eutectic solvents (DESs), have been successfully synthesized. These DESs have been synthesized by the reaction of phosphonium-based salts with different hydrogen bond donors. Many of these DESs have melting temperatures lower than 100 °C. Preliminary laboratory results showed that these DESs can be used in different applications, for example, electrochemical processes, separation of sugars, and so forth. Melting temperature, density, viscosity, pH, conductivity, and dissolved oxygen content of the novel phosphonium-based DESs were measured as a function of temperature. It was found that the type of the salt and hydrogen bond donor and the mole ratio of both compounds have a paramount effect on the studied properties.
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Abbott, A. P., Capper, G., Davies, D. L., Rasheed, R. K., & Tambyrajah, V. (2003) · Chemical Communications · doi:10.1039/b210714g · Cited by 5,738
Abbott, A. P., Boothby, D., Capper, G., Davies, D. L., & Rasheed, R. K. (2004) · Journal of the American Chemical Society · doi:10.1021/ja048266j · Cited by 4,340
Cited by
Deep Eutectic Solvents (DESs) and Their Applications
Smith, E. L., Abbott, A. P., & Ryder, K. S. (2014) · Chemical Reviews · doi:10.1021/cr300162p · Cited by 7,378
Deep eutectic solvents: syntheses, properties and applications
Zhang, Q., De Oliveira Vigier, K., Royer, S., & Jérôme, F. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35178a · Cited by 4,899
Low-transition-temperature mixtures (LTTMs): A new generation of designer solvents
Francisco, M., van den Bruinhorst, A., & Kroon, M. C. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201207548 · Cited by 1,378
Deep Eutectic Solvents: Physicochemical Properties and Gas Separation Applications
García, G., Aparicio, S., Ullah, R., & Atilhan, M. (2015) · Energy & Fuels · doi:10.1021/ef5028873 · Cited by 1,112
Basics and properties of deep eutectic solvents: a review
El Achkar, T., Greige-Gerges, H., & Fourmentin, S. (2021) · Environmental Chemistry Letters · doi:10.1007/s10311-021-01225-8 · Cited by 1,106
Metadata
- Authors
- Kareem, M. A., Mjalli, F. S., Hashim, M. A., & AlNashef, I. M.
- Venue
- Journal of Chemical & Engineering Data
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-09-08
- Volume
- 55
- Issue
- 11
- Pages
- 4632-4637
- ISSN
- 0021-9568 (ISSN-L)
- 1520-5134
- OpenAlex
- W2316371242
- Cited by
- 426
- References
- 2
- FWCI
- 4.92
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kareem, M. A., Mjalli, F. S., Hashim, M. A., & AlNashef, I. M. (2010). Phosphonium-Based Ionic Liquids Analogues and Their Physical Properties. Journal of Chemical & Engineering Data. https://doi.org/10.1021/je100104v
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