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Viscosities of Acetate or Chloride-Based Ionic Liquids and Some of Their Mixtures with Water or Other Common Solvents

Fendt, Sebastian, Padmanabhan, Sasisanker, Blanch, Harvey W., Prausnitz, John M.·2011·Journal of Chemical & Engineering Data

Abstract

For the temperature range (80 to 120) °C, viscosity data are reported for imidazolium-based ionic liquids 1-octyl-3-methylimidazolium chloride [Omim][Cl], 1-hexyl-3-methylimidazolium chloride [Hmim][Cl], 1-butyl-3-methylimidazolium chloride [Bmim][Cl], 1-ethyl-3-methylimidazolium chloride [Emim][Cl], 1-ethyl-3-methylimidazolium acetate [Emim][Ac], 1-butyl-3-methylimidazolium acetate [Bmim][Ac], and 1-butyl-3-methylimidazolium dicyanamide [Bmim] [N(CN) 2 ]. Acetate-based ionic liquids have considerably lower viscosities than the corresponding chloride-based ILs. At 25 °C, viscosity data are reported for binary mixtures of [Bmim][Ac] with diluents water, acetonitrile, dimethylformamide (DMF), and ethylene glycol. Even a small concentration of diluent very much reduces the viscosity of an ionic liquid.

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Metadata

Authors
Fendt, S., Padmanabhan, S., Blanch, H. W., & Prausnitz, J. M.
Venue
Journal of Chemical & Engineering Data
Published
2010-12-17
Volume
56
Issue
1
Pages
31-34
ISSN
  • 0021-9568 (ISSN-L)
  • 1520-5134
OpenAlex
W2316301857
Cited by
240
References
4
FWCI
4.25
Type
journal article
Language
en
Open access
closed

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Fendt, S., Padmanabhan, S., Blanch, H. W., & Prausnitz, J. M. (2011). Viscosities of Acetate or Chloride-Based Ionic Liquids and Some of Their Mixtures with Water or Other Common Solvents. Journal of Chemical & Engineering Data. https://doi.org/10.1021/je1007235

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