The DOI matches its Crossref record; 12 of the 12 references it cites were found in a registry or an index.
Ionic Liquids — Promising but Challenging Solvents for Homogeneous Derivatization of Cellulose
Open accessAbstract
In the past decade, ionic liquids (ILs) have received enormous interest as solvents for cellulose. They have been studied intensively for fractionation and biorefining of lignocellulosic biomass, for dissolution of the polysaccharide, for preparation of cellulosic fibers, and in particular as reaction media for the homogeneous preparation of highly engineered polysaccharide derivatives. ILs show great potential for application on a commercial scale regarding recyclability, high dissolution power, and their broad structural diversity. However, a critical analysis reveals that these promising features are combined with serious drawbacks that need to be addressed in order to utilize ILs for the efficient synthesis of cellulose derivatives. This review presents a comprehensive overview about chemical modification of cellulose in ILs. Difficulties encountered thereby are discussed critically and current as well as future developments in this field of polysaccharide research are outlined.
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Cites
Influence of chloride, water, and organic solvents on the physical properties of ionic liquids
Seddon, K. R., Stark, A., & Torres, M.-J. (2000) · Pure and Applied Chemistry · doi:10.1351/pac200072122275 · Cited by 2,293
Ionic Liquids and Their Interaction with Cellulose
Pinkert, A., Marsh, K. N., Pang, S., & Staiger, M. P. (2009) · Chemical Reviews · doi:10.1021/cr9001947 · Cited by 1,508
Ionic liquid processing of cellulose
Wang, H., Gurau, G., & Rogers, R. D. (2012) · Chemical Society Reviews · doi:10.1039/c2cs15311d · Cited by 1,369
Cellulose dissolution with polar ionic liquids under mild conditions: required factors for anions
Fukaya, Y., Hayashi, K., Wada, M., & Ohno, H. (2008) · Green Chem. · doi:10.1039/b713289a · Cited by 775
Xu, A., Wang, J., & Wang, H. (2010) · Green Chem. · doi:10.1039/b916882f · Cited by 439
The effect of the ionic liquid anion in the pretreatment of pine wood chips
Brandt, A., Hallett, J. P., Leak, D. J., Murphy, R. J., & Welton, T. (2010) · Green Chemistry · doi:10.1039/b918787a · Cited by 333
Assessing the greenness of some typical laboratory ionic liquid preparations
Deetlefs, M., & Seddon, K. R. (2010) · Green Chem. · doi:10.1039/b915049h · Cited by 280
Rheological Properties of Cellulose/Ionic Liquid Solutions: From Dilute to Concentrated States
Gericke, M., Schlufter, K., Liebert, T., Heinze, T., & Budtova, T. (2009) · Biomacromolecules · doi:10.1021/bm801430x · Cited by 276
Self-citationViscosity of Cellulose−Imidazolium-Based Ionic Liquid Solutions
Sescousse, R., Le, K. A., Ries, M. E., & Budtova, T. (2010) · The Journal of Physical Chemistry B · doi:10.1021/jp1024203 · Cited by 178
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Cited by
Sen, S., Martin, J. D., & Argyropoulos, D. S. (2013) · ACS Sustainable Chemistry & Engineering · doi:10.1021/sc400085a · Cited by 302
Pretreatment of biomass using ionic liquids: Research updates
Zhang, Q., Hu, J., & Lee, D.-J. (2017) · Renewable Energy · doi:10.1016/j.renene.2017.03.093 · Cited by 163
Zhao, Y., Wang, P., Zheng, W., Yu, G., Li, Z., She, Y., & Lee, M. (2019) · Industrial Crops and Products · doi:10.1016/j.indcrop.2019.111660 · Cited by 105
Metadata
- Authors
- Gericke, M., Fardim, P., & Heinze, T.
- Venue
- Molecules
- Publisher
- MDPI AG
- Published
- 2012-06-15
- Volume
- 17
- Issue
- 6
- Pages
- 7458-7502
- ISSN
- 1420-3049 (ISSN-L)
- OpenAlex
- W2148593591
- Cited by
- 358
- References
- 12
- FWCI
- 12.43
- Type
- journal article
- Language
- en
- Open access
- gold
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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