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Cited by 233

The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.

Quantitative Determination of PAHs in Biochar: A Prerequisite To Ensure Its Quality and Safe Application

Hilber, Isabel, Blum, Franziska, Leifeld, Jens, Schmidt, Hans-Peter, Bucheli, Thomas D.·2012·Journal of Agricultural and Food Chemistry

Abstract

Biochar is increasingly promoted as a beneficial soil conditioner. However, it may contain residues of polycyclic aromatic hydrocarbons (PAHs) as a result of its production by pyrolysis. To date, analytical methods to analyze PAHs in biochar quantitatively are hardly available. This study presents an optimized and validated procedure to quantify the 16 U.S. EPA PAHs in biochar. PAHs were best extracted with Soxhlet for 36 h using 100% toluene. Average absolute recoveries of isotope labeled internal standards used for each analyte from three different biochars ranged from 42% to 72%, and relative recoveries were between 71% and 105%. The limits of detection were biochar-dependent, but on average a factor of >50 lower than quantified PAH concentrations (9-355 mg kg(dry weight)(-1)). The established method prepares the ground for a harmonized protocol for PAH analysis of biochars, a necessity for biochar quality control, registration, and legislation.

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Metadata

Authors
Hilber, I., Blum, F., Leifeld, J., Schmidt, H.-P., & Bucheli, T. D.
Venue
Journal of Agricultural and Food Chemistry
Published
2012-03-20
Volume
60
Issue
12
Pages
3042-3050
ISSN
  • 0021-8561 (ISSN-L)
  • 1520-5118
OpenAlex
W2316551964
Cited by
233
References
1
FWCI
11.80
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Quantitative Determination of PAHs in Biochar: A Prerequisite To Ensure Its Quality and Safe Application. https://app.cochat.ai/papers/10.1021/jf205278v
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Hilber, I., Blum, F., Leifeld, J., Schmidt, H.-P., & Bucheli, T. D. (2012). Quantitative Determination of PAHs in Biochar: A Prerequisite To Ensure Its Quality and Safe Application. Journal of Agricultural and Food Chemistry. https://doi.org/10.1021/jf205278v

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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.