The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Quantitative Determination of PAHs in Biochar: A Prerequisite To Ensure Its Quality and Safe Application
Abstract
Biochar is increasingly promoted as a beneficial soil conditioner. However, it may contain residues of polycyclic aromatic hydrocarbons (PAHs) as a result of its production by pyrolysis. To date, analytical methods to analyze PAHs in biochar quantitatively are hardly available. This study presents an optimized and validated procedure to quantify the 16 U.S. EPA PAHs in biochar. PAHs were best extracted with Soxhlet for 36 h using 100% toluene. Average absolute recoveries of isotope labeled internal standards used for each analyte from three different biochars ranged from 42% to 72%, and relative recoveries were between 71% and 105%. The limits of detection were biochar-dependent, but on average a factor of >50 lower than quantified PAH concentrations (9-355 mg kg(dry weight)(-1)). The established method prepares the ground for a harmonized protocol for PAH analysis of biochars, a necessity for biochar quality control, registration, and legislation.
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Citations
Cites
Characterisation and evaluation of biochars for their application as a soil amendment
Singh, B., Singh, B. P., & Cowie, A. L. (2010) · Soil Research · doi:10.1071/sr10058 · Cited by 991
Cited by
Biochar's role in mitigating soil nitrous oxide emissions: A review and meta-analysis
Cayuela, M. L., van Zwieten, L., Singh, B. P., Jeffery, S., Roig, A., & Sánchez-Monedero, M. A. (2014) · Agriculture, Ecosystems & Environment · doi:10.1016/j.agee.2013.10.009 · Cited by 1,053
Recent advances in utilization of biochar
Qian, K., Kumar, A., Zhang, H., Bellmer, D., & Huhnke, R. (2015) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2014.10.074 · Cited by 915
Kuppusamy, S., Thavamani, P., Megharaj, M., Venkateswarlu, K., & Naidu, R. (2016) · Environment International · doi:10.1016/j.envint.2015.10.018 · Cited by 383
Haider, G., Steffens, D., Moser, G., Müller, C., & Kammann, C. I. (2017) · Agriculture, Ecosystems & Environment · doi:10.1016/j.agee.2016.12.019 · Cited by 334
A critical review of the possible adverse effects of biochar in the soil environment
Brtnicky, M., Datta, R., Holatko, J., Bielska, L., Gusiatin, Z. M., Kucerik, J., Hammerschmiedt, T., Danish, S., Radziemska, M., Mravcova, L., et al. (2021) · Science of The Total Environment · doi:10.1016/j.scitotenv.2021.148756 · Cited by 331
Metadata
- Authors
- Hilber, I., Blum, F., Leifeld, J., Schmidt, H.-P., & Bucheli, T. D.
- Venue
- Journal of Agricultural and Food Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-03-20
- Volume
- 60
- Issue
- 12
- Pages
- 3042-3050
- ISSN
- 0021-8561 (ISSN-L)
- 1520-5118
- OpenAlex
- W2316551964
- Cited by
- 233
- References
- 1
- FWCI
- 11.80
- Type
- journal article
- Language
- en
- Open access
- closed
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- Hilber, I., Blum, F., Leifeld, J., Schmidt, H.-P., & Bucheli, T. D. (2012). Quantitative Determination of PAHs in Biochar: A Prerequisite To Ensure Its Quality and Safe Application. Journal of Agricultural and Food Chemistry. https://doi.org/10.1021/jf205278v
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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