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The Reaction of 1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU) with Carbon Dioxide
Abstract
Amidines have been reported to react with CO(2) to form a stable and isolable zwitterionic adduct but previous studies were performed in the presence of at least some water. However, spectroscopy of the reaction between DBU and CO(2) detects the rapid formation of the bicarbonate salt of DBU when wet DBU is exposed to CO(2) and does not indicate that an isolable zwitterionic adduct between DBU and CO(2) forms either in the presence or the absence of water.
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Citations
Cited by
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Bui, M., Adjiman, C. S., Bardow, A., Anthony, E. J., Boston, A., Brown, S., Fennell, P. S., Fuss, S., Galindo, A., Hackett, L. A., et al. (2018) · Energy & Environmental Science · doi:10.1039/c7ee02342a · Cited by 4,374
Carbon capture and storage update
Boot-Handford, M. E., Abanades, J. C., Anthony, E. J., Blunt, M. J., Brandani, S., Mac Dowell, N., Fernández, J. R., Ferrari, M.-C., Gross, R., Hallett, J. P., et al. (2014) · Energy Environ. Sci. · doi:10.1039/c3ee42350f · Cited by 2,386
Organocatalysis: Opportunities and Challenges for Polymer Synthesis
Kiesewetter, M. K., Shin, E. J., Hedrick, J. L., & Waymouth, R. M. (2010) · Macromolecules · doi:10.1021/ma9025948 · Cited by 907
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Fiorani, G., Guo, W., & Kleij, A. W. (2015) · Green Chemistry · doi:10.1039/c4gc01959h · Cited by 658
Alves, M., Grignard, B., Mereau, R., Jerome, C., Tassaing, T., & Detrembleur, C. (2017) · Catalysis Science & Technology · doi:10.1039/c7cy00438a · Cited by 531
Metadata
- Authors
- Heldebrant, D. J., Jessop, P. G., Thomas, C. A., Eckert, C. A., & Liotta, C. L.
- Venue
- The Journal of Organic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-05-26
- Volume
- 70
- Issue
- 13
- Pages
- 5335-5338
- ISSN
- 0022-3263 (ISSN-L)
- 1520-6904
- OpenAlex
- W2003240023
- Cited by
- 350
- References
- 0
- FWCI
- 8.50
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: The Reaction of 1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU) with Carbon Dioxide. https://app.cochat.ai/papers/10.1021/jo0503759
- The paper
- Heldebrant, D. J., Jessop, P. G., Thomas, C. A., Eckert, C. A., & Liotta, C. L. (2005). The Reaction of 1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU) with Carbon Dioxide. The Journal of Organic Chemistry. https://doi.org/10.1021/jo0503759
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
