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Switchable-Polarity Solvents Prepared with a Single Liquid Component
Abstract
Known liquids that can reversibly switch their polarity at atmospheric pressure are all prepared as mixtures of two liquid components; we now report a series of switchable-polarity solvents that consist, in their low-polarity form, of only a single liquid component, a secondary amine. These solvents operate in a polarity range that is significantly lower than those of previously reported switchable solvents. Application to the separation and purification of a polymer and recovery of a catalyst is described.
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Cited by
Green and sustainable solvents in chemical processes
Clarke, C. J., Tu, W.-C., Levers, O., Bröhl, A., & Hallett, J. P. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00571 · Cited by 2,071
Ionic liquids and catalysis: Recent progress from knowledge to applications
Olivier-Bourbigou, H., Magna, L., & Morvan, D. (2010) · Applied Catalysis A: General · doi:10.1016/j.apcata.2009.10.008 · Cited by 1,639
Carbon dioxide utilization with C–N bond formation: carbon dioxide capture and subsequent conversion
Yang, Z.-Z., He, L.-N., Gao, J., Liu, A.-H., & Yu, B. (2012) · Energy & Environmental Science · doi:10.1039/c2ee02774g · Cited by 520
Gregory, G. L., Ulmann, M., & Buchard, A. (2015) · RSC Advances · doi:10.1039/c5ra07290e · Cited by 87
Switchable hydrophilicity solvents in analytical chemistry. Five years of achievements
Bazel, Y., Rečlo, M., & Chubirka, Y. (2020) · Microchemical Journal · doi:10.1016/j.microc.2020.105115 · Cited by 72
Metadata
- Authors
- Phan, L., Andreatta, J. R., Horvey, L. K., Edie, C. F., Luco, A.-L., Mirchandani, A., Darensbourg, D. J., & Jessop, P. G.
- Venue
- The Journal of Organic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-12-08
- Volume
- 73
- Issue
- 1
- Pages
- 127-132
- ISSN
- 0022-3263 (ISSN-L)
- 1520-6904
- OpenAlex
- W2034678673
- Cited by
- 184
- References
- 0
- FWCI
- 4.05
- Type
- journal article
- Language
- en
- Open access
- closed
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