Synthesis of 6-membered cyclic carbonates from 1,3-diols and low CO 2 pressure: a novel mild strategy to replace phosgene reagents
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Low pressure CO 2 is used for the synthesis of cyclic carbonates from 1,3-diols in a novel mild alternative to phosgene derivatives.
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The coupling of diols with CO2 occurred at 25 °C and ambient pressure, affording cyclic carbonates in 40-70% yields.
“The coupling of diols with CO2 occurred at 25 °C and ambient pressure, affording cyclic carbonates in 40-70% yields.”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [202]
Buchard reported an efficient two-step procedure using DBU as the base in the first step to activate the hydroxyl group toward carbonylation and NH3/TsCl in the second step to facilitate the cyclization.
“Recently, Buchard reported an efficient two-step procedure using DBU as the base in the first step to activate the hydroxyl group toward carbonylation and NH3/TsCl in the second step to facilitate the cyclization.202”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [202]
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Cites
Shaikh, A.-A. G., & Sivaram, S. (1996) · Chemical Reviews · doi:10.1021/cr950067i · Cited by 1,381 · see citing works
Polymer Science: A Comprehensive Reference
(2012) · Elsevier eBooks · doi:10.1016/c2009-1-28406-1 · Cited by 1,124 · see citing works
The synthesis of organic carbonates from carbon dioxide
Sakakura, T., & Kohno, K. (2009) · Chemical Communications · doi:10.1039/b819997c · Cited by 1,067 · see citing works
Recent Advances in the Catalytic Preparation of Cyclic Organic Carbonates
Martín, C., Fiorani, G., & Kleij, A. W. (2015) · ACS Catalysis · doi:10.1021/cs5018997 · Cited by 1,037 · see citing works
Reversible nonpolar-to-polar solvent
Jessop, P. G., Heldebrant, D. J., Li, X., Eckert, C. A., & Liotta, C. L. (2005) · Nature · doi:10.1038/4361102a · Cited by 973 · see citing works
Catalysts for CO <sub>2</sub> /epoxide copolymerisation
Kember, M. R., Buchard, A., & Williams, C. K. (2011) · Chem. Commun. · doi:10.1039/c0cc02207a · Cited by 797 · see citing works
Self-citationAliphatic cyclic carbonates and spiroorthocarbonates as monomers
Rokicki, G. (2000) · Progress in Polymer Science · doi:10.1016/s0079-6700(00)00006-x · Cited by 499 · see citing works
New Methods of Preparative Organic Chmistry IV. Syntheses Using Heterocyclic Amides (Azolides)
Staab, H. A. (1962) · Angewandte Chemie International Edition in English · doi:10.1002/anie.196203511 · Cited by 488 · see citing works
Oxetanes as Versatile Elements in Drug Discovery and Synthesis
Burkhard, J. A., Wuitschik, G., Rogers‐Evans, M., Müller, K., & Carreira, E. M. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.200907155 · Cited by 447 · see citing works
Construction of functional aliphatic polycarbonates for biomedical applications
Feng, J., Zhuo, R., & Zhang, X. (2011) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2011.07.008 · Cited by 358 · see citing works
Tempelaar, S., Mespouille, L., Coulembier, O., Dubois, P., & Dove, A. P. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35268k · Cited by 345 · see citing works
Synthetic Biodegradable Polymers
Rieger, B., Zevaco, T. A., Dinjus, E., Reichardt, R., Coates, G. W., & Künkel, A. (2012) · Advances in polymer science · doi:10.1007/978-3-642-27154-0 · Cited by 269 · see citing works
Honda, M., Tamura, M., Nakao, K., Suzuki, K., Nakagawa, Y., & Tomishige, K. (2014) · ACS Catalysis · doi:10.1021/cs500301d · Cited by 216 · see citing works
Dimethyl carbonate for environmentally benign reactions
Ono, Y. (1997) · Catalysis Today · doi:10.1016/s0920-5861(96)00130-7 · Cited by 214 · see citing works
Sanders, D. P., Fukushima, K., Coady, D. J., Nelson, A., Fujiwara, M., Yasumoto, M., & Hedrick, J. L. (2010) · Journal of the American Chemical Society · doi:10.1021/ja105332k · Cited by 213 · see citing works
Basel, Y., & Häßner, A. (2000) · The Journal of Organic Chemistry · doi:10.1021/jo000257f · Cited by 205 · see citing works
Tamura, M., Honda, M., Nakagawa, Y., & Tomishige, K. (2013) · Journal of Chemical Technology & Biotechnology · doi:10.1002/jctb.4209 · Cited by 187 · see citing works
Switchable-Polarity Solvents Prepared with a Single Liquid Component
Phan, L., Andreatta, J. R., Horvey, L. K., Edie, C. F., Luco, A.-L., Mirchandani, A. A., Darensbourg, D. J., & Jessop, P. G. (2007) · The Journal of Organic Chemistry · doi:10.1021/jo7017697 · Cited by 184 · see citing works
Koning, C. E., Wildeson, J. R., Parton, R. F., Plum, B., Steeman, P. A. M., & Darensbourg, D. J. (2001) · Polymer · doi:10.1016/s0032-3861(00)00709-6 · Cited by 180 · see citing works
Park, J. H., Jeon, J. Y., Lee, J. J., Jang, Y., Varghese, J. K., & Lee, B. Y. (2013) · Macromolecules · doi:10.1021/ma400360w · Cited by 158 · see citing works
Synthesis of cyclic carbonates from urea and diols over metal oxides
Li, Q., Zhang, W., Zhao, N., Wei, W., & Sun, Y. (2006) · Catalysis Today · doi:10.1016/j.cattod.2006.02.033 · Cited by 157 · see citing works
Xu, M., Chen, Y., Qian, L., Wang, J., & Tang, S. (2014) · Journal of Applied Polymer Science · doi:10.1002/app.41006 · Cited by 149 · see citing works
Zhu, W., Huang, X., Li, C., Xiao, Y., Zhang, D., & Guan, G. (2011) · Polymer International · doi:10.1002/pi.3043 · Cited by 142 · see citing works
Polycarbonates Derived from Glucose via an Organocatalytic Approach
Mikami, K., Lonnecker, A. T., Gustafson, T. P., Zinnel, N. F., Pai, P., Russell, D. H., & Wooley, K. L. (2013) · Journal of the American Chemical Society · doi:10.1021/ja402319m · Cited by 132 · see citing works
Tominaga, Y., Shimomura, T., & Nakamura, M. (2010) · Polymer · doi:10.1016/j.polymer.2010.07.037 · Cited by 110 · see citing works
Enantiopure Isotactic PCHC Synthesized by Ring-Opening Polymerization of Cyclohexene Carbonate
Guerin, W., Diallo, A. K., Kirillov, E., Hélou, M., Slawinski, M., Brusson, J., Carpentier, J., & Guillaume, S. M. (2014) · Macromolecules · doi:10.1021/ma5009397 · Cited by 105 · see citing works
Guillaume, S. M., & Carpentier, J.-F. (2012) · Catalysis Science & Technology · doi:10.1039/c2cy00507g · Cited by 102 · see citing works
Improving the regeneration of CO2-binding organic liquids with a polarity change
Mathias, P. M., Afshar, K., Zheng, F., Bearden, M. D., Freeman, C. J., Andrea, T., Koech, P., Kutnyakov, I. V., Zwoster, A. J., Smith, A. R., et al. (2013) · Energy & Environmental Science · doi:10.1039/c3ee41016a · Cited by 96 · see citing works
Synthesis of cyclic carbonates with carbon dioxide and cesium carbonate
Reithofer, M. R., Sum, Y. N., & Zhang, Y. (2013) · Green Chemistry · doi:10.1039/c3gc40790j · Cited by 95 · see citing works
Yasuda, H., Aludin, M. S., Kitamura, N., Tanabe, M., & Sirahama, H. (1999) · Macromolecules · doi:10.1021/ma981904w · Cited by 90 · see citing works
Metal‐Free Synthesis of Cyclic and Acyclic Carbonates from CO2 and Alcohols
Lim, Y. N., Lee, C., & Jang, H. (2014) · European Journal of Organic Chemistry · doi:10.1002/ejoc.201400031 · Cited by 84 · see citing works
Some Anticonvulsant Agents Derived from 1,3-Propanediols
Ludwig, B. J., & Piech, E. C. (1951) · Journal of the American Chemical Society · doi:10.1021/ja01156a086 · Cited by 72 · see citing works
Li, Q., Zhao, N., Wei, W., & Sun, Y. (2007) · Journal of Molecular Catalysis A Chemical · doi:10.1016/j.molcata.2007.01.018 · Cited by 69 · see citing works
Brunelle, D. J., & Korn, M. R. (2005) · ACS symposium series · doi:10.1021/bk-2005-0898 · Cited by 66 · see citing works
Gabriele, B., Mancuso, R., Salerno, G., Veltri, L., Costa, M., & Dibenedetto, A. (2011) · ChemSusChem · doi:10.1002/cssc.201100250 · Cited by 63 · see citing works
Azechi, M., Matsumoto, K., & Endo, T. (2013) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.26538 · Cited by 56 · see citing works
Synthesis and polymerization of alkyl halide-functional cyclic carbonates
Mindemark, J., & Bowden, T. M. (2011) · Polymer · doi:10.1016/j.polymer.2011.10.027 · Cited by 52 · see citing works
Palladium‐Catalyzed Carbonylation of Diols to Cyclic Carbonates
Pearson, D., Conley, N. R., & Waymouth, R. M. (2011) · Advanced Synthesis & Catalysis · doi:10.1002/adsc.201100240 · Cited by 46 · see citing works
Solution‐Processed Nanostructured Benzoporphyrin with Polycarbonate Binder for Photovoltaics
Ku, S., Liman, C. D., Cochran, J. E., Toney, M. F., Chabinyc, M. L., & Hawker, C. J. (2011) · Advanced Materials · doi:10.1002/adma.201100028 · Cited by 39 · see citing works
Diallo, A. K., Kirillov, E., Slawinski, M., Brusson, J., Guillaume, S. M., & Carpentier, J. (2015) · Polymer Chemistry · doi:10.1039/c4py01713g · Cited by 30 · see citing works
A high yielding, one-pot synthesis of dialkyl carbonates from alcohols using Mitsunobu’s reagent
Chaturvedi, D., Mishra, N., & Mishra, V. (2007) · Tetrahedron Letters · doi:10.1016/j.tetlet.2007.05.103 · Cited by 30 · see citing works
Sanders, D. P., Coady, D. J., Yasumoto, M., Fujiwara, M., Sardón, H., & Hedrick, J. L. (2013) · Polymer Chemistry · doi:10.1039/c3py01128c · Cited by 27 · see citing works
Ethylene carbonate/cyclic ester random copolymers synthesized by ring-opening polymerization
Guerin, W., Hélou, M., Slawinski, M., Brusson, J., Carpentier, J., & Guillaume, S. M. (2015) · Polymer Chemistry · doi:10.1039/c4py01660b · Cited by 24 · see citing works
Polycarbonates as temporary adhesives
Fritz, N., Dao, H., Allen, S. A. B., & Kohl, P. A. (2012) · International Journal of Adhesion and Adhesives · doi:10.1016/j.ijadhadh.2012.04.001 · Cited by 20 · see citing works
Kobayashi, K., Kanmuri, S., Kimura, Y., & Masutani, K. (2014) · Polymer International · doi:10.1002/pi.4839 · Cited by 20 · see citing works
Matsukizono, H., & Endo, T. (2015) · Journal of Applied Polymer Science · doi:10.1002/app.41956 · Cited by 19 · see citing works
A New Route to Carbonate Monomers for Synthesis of Polycarbonates
Rokicki, G., Pawlicki, J., & Kuran, W. (1982) · Polymer Journal · doi:10.1295/polymj.14.839 · Cited by 16 · see citing works
Flagged first, then by citations
Research works printed but not linked: 42
- J. Xu, E. Feng and J. Song, J. Appl. Polym. Sci., 2014, 131, 39822-39838;
- J. Feng, R.-X. Zhuo and X.-Z. Zhang, Prog. Polym. Sci., 2012, 37, 211-236.
- K. Kobayashi, S. Kanmuri, Y. Kimura and K. Masutani, Polym. Int., 2015, 64, 641-646;
- C. Koning, J. Wildeson, R. Parton, B. Plum, P. Steeman and D. J. Darensbourg, Polymer, 2001, 42, 3995-4004.
- S.-Y. Ku, C. D. Liman, J. E. Cochran, M. F. Toney, M. L. Chabinyc and C. J. Hawker, Adv. Mater., 2011, 23, 2289-2293.
- Y. Tominaga, T. Shimomura and M. Nakamura, Polymer, 2010, 51, 4295-4298.
- N. Fritz, H. Dao, S. A. B. Allen and P. A. Kohl, Int. J. Adhes. Adhes., 2012, 38, 45-49.
- M. R. Kember, A. Buchard and C. K. Williams, Chem. Commun., 2011, 47, 141-163.
- J. H. Park, J. Y. Jeon, J. J. Lee, Y. Jang, J. K. Varghese and B. Y. Lee, Macromolecules, 2013, 46, 3301-3308;
- W. Zhu, X. Huang, C. Li, Y. Xiao, D. Zhang and G. Guan, Polym. Int., 2011, 60, 1060-1067;
- G. Rokicki, J. Pawlicki and W. Kuran, Polym. J., 1982, 14, 839-845; (
- Y. Ono, Catal. Today, 1997, 35, 15-25;
- G. Rokicki, Prog. Polym. Sci., 2000, 25, 259-342.
- S. M. Guillaume and J.-F. Carpentier, Catal. Sci. Technol., 2012, 2, 898-906.
- S. Tempelaar, L. Mespouille, O. Coulembier, P. Dubois and A. P. Dove, Chem. Soc. Rev., 2013, 42, 1312-1336;
- M. Azechi, K. Matsumoto and T. Endo, J. Polym. Sci., Part A: Polym. Chem., 2013, 51, 1651-1655;
- W. Guerin, A. K. Diallo, E. Kirilov, M. Helou, M. Slawinski, J.-M. Brusson, J.-F. Carpentier and S. M. Guillaume, Macromolecules, 2014, 47, 4230-4235;
- W. Guerin, M. Helou, M. Slawinski, J.-M. Brusson, J.-F. Carpentier and S. M. Guillaume, Polym. Chem., 2015, 6, 1972-1985;
- A. K. Diallo, E. Kirillov, M. Slawinski, J.-M. Brusson, S. M. Guillaume and J.-F. Carpentier, Polym. Chem., 2015, 6, 1961-1971.
- A.-A. G. Shaikh and S. Sivaram, Chem. Rev., 1996, 96, 951- 976.
- H. A. Staab, Angew. Chem., Int. Ed. Engl., 1962, 1, 351-367.
- Y. Basel and A. Hassner, J. Org. Chem., 2000, 65, 6368-6380.
- J. Mindemark and T. Bowden, Polymer, 2011, 52, 5716-5722.
- D. P. Sanders, K. Fukushima, D. J. Coady, A. Nelson, M. Fujiwara, M. Yasumoto and J. L. Hedrick, J. Am. Chem. Soc., 2010, 132, 14724-14726;
- D. P. Sanders, D. J. Coady, M. Yasumoto, M. Fujiwara, H. Sardon and J. L. Hedrick, Polym. Chem., 2014, 5, 327-329;
- K. Mikami, A. T. Lonnecker, T. P. Gustafson, N. F. Zinnel, P. J. Pai, D. H. Russell and K. L. Wooley, J. Am. Chem. Soc., 2013, 135, 6826-6829;
- B. Gabriele, R. Mancuso, G. Salerno, L. Veltri, M. Costa and A. Dibenedetto, ChemSusChem, 2011, 4, 1778-1786;
- D. M. Pearson, N. R. Conley and R. M. Waymouth, Adv. Synth. Catal., 2011, 353, 3007-3013.
- C. Martín, G. Fiorani and A. W. Kleij, ACS Catal., 2015, 5, 1353-1370.
- J. A. Burkhard, G. Wuitschik, M. Rogers-Evans, K. Müller and E. M. Carreira, Angew. Chem., Int. Ed., 2010, 49, 9052-9067.
- Q. Li, W. Zhang, N. Zhao, W. Wei and Y. Sun, Catal. Today, 2006, 115, 111-116;
- Q. Li, N. Zhao, W. Wei and Y. Sun, J. Mol. Catal. A: Chem., 2007, 270, 44-49.
- D. Chaturvedi, N. Mishra and V. Mishra, Tetrahedron Lett., 2007, 48, 5043-5045;
- M. Tamura, M. Honda, Y. Nakagawa and K. Tomishige, J. Chem. Technol. Biotechnol., 2014, 89, 19-33.
- M. Honda, M. Tamura, K. Nakao, K. Suzuki, Y. Nakagawa and K. Tomishige, ACS Catal., 2014, 4, 1893-1896.
- Y. N. Lim, C. Lee and H.-Y. Jang, Eur. J. Org. Chem., 2014, 9, 1823-1826.
- M. R. Reithofer, Y. N. Sum and Y. Zhang, Green Chem., 2013, 15, 2086-2090.
- P. G. Jessop, D. J. Heldebrant, X. Li, C. A. Eckert and C. L. Liotta, Nature, 2005, 436, 1102.
- P. M. Mathias, K. Afshar, F. Zheng, M. D. Bearden, C. J. Freeman, T. Andrea, P. K. Koech, I. Kutnyakov, A. Zwoster, A. R. Smith, P. G. Jessop, O. G. Nik and D. J. Heldebrant, Energy Environ. Sci., 2013, 6, 2233-2242;
- L. Phan, J. R. Andreatta, L. K. Horvey, C. F. Edie, A.-L. Luco, A. Mirchandani, D. J. Darensbourg and P. G. Jessop, J. Org. Chem., 2008, 73, 127-132.
- H. Yasuda, M.-S. Aludin, N. Kitamura, M. Tanabe and H. Sirahama, Macromolecules, 1999, 32, 6047-6057.
- B. J. Ludwig and E. C. Piech, J. Am. Chem. Soc., 1951, 73, 5779-5781.
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Update and Challenges in Carbon Dioxide‐Based Polycarbonate Synthesis
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Self-citationPolymers from Sugars and CO2: Synthesis and Polymerization of a d -Mannose-Based Cyclic Carbonate
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Self-citationSynthesis of cyclic carbonates from diols and CO 2 catalyzed by carbenes
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Zhang, Q., Yuan, H., Lin, X.-T., Fukaya, N., Fujitani, T., Sato, K., & Choi, J. (2020) · Green Chemistry · doi:10.1039/d0gc01402h · Cited by 81 · see citing works
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Hosseinian, A., Farshbaf, S., Mohammadi, R., Monfared, A., & Vessally, E. (2018) · RSC Advances · doi:10.1039/c8ra01280f · Cited by 47 · see citing works
López‐Vidal, E. M., Gregory, G. L., Kociok-Köhn, G. I., & Buchard, A. (2018) · Polymer Chemistry · doi:10.1039/c8py00119g · Cited by 45 · see citing works
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Tan, E., Hedrick, J. L., Arrechea, P. L., Erdmann, T., Kiyek, V., Lottier, S., Yang, Y. Y., & Park, N. H. (2021) · Macromolecules · doi:10.1021/acs.macromol.0c02880 · Cited by 37 · see citing works
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Qiao, C., Shi, W., Brandolese, A., Benet‐Buchholz, J., Escudero‐Adán, E. C., & Kleij, A. W. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202205053 · Cited by 29 · see citing works
Maeda, C., Inoue, H., Ichiki, A., Okihara, T., & Ema, T. (2022) · ACS Catalysis · doi:10.1021/acscatal.2c03583 · Cited by 27 · see citing works
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Charlesworth, T., Yiamsawat, K., Gao, H., Rees, G. J., Williams, C. K., Bruce, P. G., Pasta, M., & Gregory, G. L. (2024) · Angewandte Chemie International Edition · doi:10.1002/anie.202408246 · Cited by 22 · see citing works
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Singer, F. N., Deacy, A. C., McGuire, T. M., Williams, C. K., & Buchard, A. (2022) · Angewandte Chemie · doi:10.1002/ange.202201785 · Cited by 21 · see citing works
Self-citationBrège, A., Méreau, R., McGehee, K., Grignard, B., Detrembleur, C., Jérôme, C., & Tassaing, T. (2020) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2020.01.003 · Cited by 21 · see citing works
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DeRosa, C. A., Luke, A. M., Anderson, K., Reineke, T. M., Tolman, W. B., Bates, F. S., & Hillmyer, M. A. (2021) · Macromolecules · doi:10.1021/acs.macromol.1c00828 · Cited by 21 · see citing works
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Lanzi, M., & Kleij, A. W. (2023) · Chinese Journal of Chemistry · doi:10.1002/cjoc.202300502 · Cited by 20 · see citing works
Step-Growth Polyesters with Biobased (R)-1,3-Butanediol
DeRosa, C. A., Kua, X. Q., Bates, F. S., & Hillmyer, M. A. (2020) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.0c03009 · Cited by 20 · see citing works
Recent Advances in RO(CO)P of Bio-Based Monomers
Santoro, O., Izzo, L., & Monica, F. D. (2022) · Sustainable Chemistry · doi:10.3390/suschem3020017 · Cited by 20 · see citing works
CO2 and Lignin‐Based Sustainable Polymers with Closed‐Loop Chemical Recycling
Ghorai, A., & Chung, H. (2024) · Advanced Functional Materials · doi:10.1002/adfm.202403035 · Cited by 19 · see citing works
Fluoride-promoted carbonylation polymerization: a facile step-growth technique to polycarbonates
Olsson, J. V., Hult, D., García‐Gallego, S., & Malkoch, M. (2017) · Chemical Science · doi:10.1039/c6sc05582f · Cited by 16 · see citing works
Gao, X., Deng, Y., Lu, C., Zhang, L., Wang, X., & Yu, B. (2018) · Catalysts · doi:10.3390/catal8070271 · Cited by 16 · see citing works
Helbling, P., Hermant, F., Petit, M., Vidil, T., & Cramail, H. (2023) · Macromolecular Chemistry and Physics · doi:10.1002/macp.202300300 · Cited by 13 · see citing works
Tamura, M., Matsuda, K., Nakagawa, Y., & Tomishige, K. (2018) · Chemical Communications · doi:10.1039/c8cc08405j · Cited by 15 · see citing works
Tufano, F., Santulli, F., Liguori, C., Santoriello, G., Ritacco, I., Caporaso, L., Grisi, F., Mazzeo, M., & Lamberti, M. (2024) · Catalysis Science & Technology · doi:10.1039/d4cy01353k · Cited by 11 · see citing works
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Monica, F. D., Brandolese, A., Carmine, G. D., Selva, M., Fiorani, G., & Izzo, L. (2025) · ChemSusChem · doi:10.1002/cssc.202500030 · Cited by 11 · see citing works
Qaroush, A. K., Eftaiha, A. F., Smadi, A. H., Assaf, K. I., Al-Qaisi, F. M., & Alsoubani, F. A. (2022) · ACS Omega · doi:10.1021/acsomega.2c01774 · Cited by 11 · see citing works
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Maquilón, C., Monica, F. D., Limburg, B., & Kleij, A. W. (2021) · Advanced Synthesis & Catalysis · doi:10.1002/adsc.202100654 · Cited by 10 · see citing works
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Li, J., Zhao, Q., Liu, P., Zhang, D., Song, Q., & Zhang, K. (2018) · Greenhouse Gases Science and Technology · doi:10.1002/ghg.1807 · Cited by 10 · see citing works
Goodrich, P. A., Gunaratne, H. Q. N., Jin, L., Lei, Y., & Seddon, K. R. (2018) · Australian Journal of Chemistry · doi:10.1071/ch17530 · Cited by 10 · see citing works
Qiao, C., Villar‐Yanez, A., Sprachmann, J., Limburg, B., Bó, C., & Kleij, A. W. (2020) · Angewandte Chemie · doi:10.1002/ange.202007350 · Cited by 10 · see citing works
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Gregory, G. L., Sulley, G. S., Kimpel, J., Szewczyk‐Łagodzińska, M., Häfele, L., Carrodeguas, L. P., & Williams, C. K. (2022) · Angewandte Chemie · doi:10.1002/ange.202210748 · Cited by 9 · see citing works
Self-citationTufano, F., Napolitano, C., Mazzeo, M., Grisi, F., & Lamberti, M. (2024) · Biomacromolecules · doi:10.1021/acs.biomac.4c00532 · Cited by 9 · see citing works
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Schuler, M., & Tatibouët, A. (2018) · doi:10.1002/9783527697014.ch11 · Cited by 9 · see citing works
Baek, S., Lee, J., Kim, H., Cha, I., & Song, C. (2021) · Polymers · doi:10.3390/polym13244381 · Cited by 7 · see citing works
Mu, Q., Lv, J.-Y., Chen, M., Bai, X., Chen, J., Xia, C., & Xu, L. (2017) · RSC Advances · doi:10.1039/c7ra06727e · Cited by 7 · see citing works
Hirano, N., Yoshida, H., Ando, T., & Ajiro, H. (2024) · Journal of Polymer Science · doi:10.1002/pol.20240347 · Cited by 6 · see citing works
Hwang, J., Song, Y., Hwang, H., Kim, S., Kim, H., Bong, K. W., Jeon, H., Park, C. H., Na, J., & Seo, J. Y. (2025) · Chemical Engineering Journal · doi:10.1016/j.cej.2025.163848 · Cited by 5 · see citing works
Sharifian, S., Iranmanesh, Z., KOLUR, N. A., Vahidi, E., & Harasek, M. (2026) · Journal of Environmental Management · doi:10.1016/j.jenvman.2026.128785 · Cited by 5 · see citing works
Efficient synthesis of 6-membered cyclic monothiocarbonates from halohydrin and carbonyl sulfide
Li, Y., Li, J., Zhang, Y., Fang, Z., & Zhang, C. (2023) · Chemical Communications · doi:10.1039/d3cc01541f · Cited by 5 · see citing works
Synthesis of sustainable sulfur‐containing polycarbonates from xylose and carbonyl sulfide
Chen, Q., Chen, W., & Zhou, H. (2023) · Journal of Polymer Science · doi:10.1002/pol.20230163 · Cited by 5 · see citing works
Lee, S., Lee, H., Chung, S. H., Lee, J. S., & Lim, S. Y. (2023) · ACS Omega · doi:10.1021/acsomega.3c05023 · Cited by 5 · see citing works
Fukushima, K. (2018) · Royal Society of Chemistry eBooks · doi:10.1039/9781788015738-00274 · Cited by 5 · see citing works
Zarras, P., Goodman, P. A., Baca, A. J., Baca, J. E., & Vang, S. (2016) · doi:10.1002/9781119185055.ch14 · Cited by 5 · see citing works
New Sustainable Chemicals and Materials Derived from CO 2and Bio‐based Resources
Paninho, A. B., Zakrzewska, M. E., Correa, L. R. C., daSilva, F. G., Branco, L. C., & Nunes, A. V. M. (2024) · doi:10.1002/9781119870647.ch4 · Cited by 4 · see citing works
Recyclable, Biobased Polycarbonates and Polyesters by Naphthoxy‐Imine Zinc and Magnesium Complexes
Tufano, F., Galotto, M. V., D'Elia, A., Santulli, F., Mazzeo, M., & Lamberti, M. (2025) · Chemistry - A European Journal · doi:10.1002/chem.202501271 · Cited by 3 · see citing works
Catalytic synthesis of bio-sourced organic carbonates and sustainable hybrid materials from CO2
de la Cruz‐Martínez, F., Castro‐Osma, J. A., & Lara‐Sánchez, A. (2022) · Advances in catalysis · doi:10.1016/bs.acat.2022.07.003 · Cited by 3 · see citing works
Functional polymers from CO2 as feedstock
Yeung, C. W. S., Seah, G. E. K. K., Tan, A. Y. X., Tee, S. Y., Lim, J. Y. C., & Goh, S. S. (2023) · Elsevier eBooks · doi:10.1016/b978-0-323-91198-6.00005-x · Cited by 4 · see citing works
Clickable and Degradable Polycarbonate Vehicles for mRNA Delivery
LaSalle, C. J., Morrissey, D. V., & Reineke, T. M. (2025) · Bioconjugate Chemistry · doi:10.1021/acs.bioconjchem.5c00073 · Cited by 3 · see citing works
A Novel Catalytic Route to Polymerizable Bicyclic Cyclic Carbonate Monomers from Carbon Dioxide
Qiao, C., Shi, W., Brandolese, A., Benet‐Buchholz, J., Escudero‐Adán, E. C., & Kleij, A. W. (2022) · Angewandte Chemie · doi:10.1002/ange.202205053 · Cited by 3 · see citing works
Grondin, J., Aupetit, C., Vincent, J., & Tassaing, T. (2023) · Catalysts · doi:10.3390/catal13060939 · Cited by 2 · see citing works
Saud, A. S., Ahmad, M. S., Madduluri, V. R., Maniam, G. P., & Rahim, M. H. A. (2025) · Research on Chemical Intermediates · doi:10.1007/s11164-025-05662-w · Cited by 1 · see citing works
Yao, S., Iqbal, A., Bakar, N. H. H. A., Yusop, M. R., Pauzi, H., & Kanakaraju, D. (2022) · ChemistrySelect · doi:10.1002/slct.202201970 · Cited by 1 · see citing works
Gregory, G. L., Ulmann, M., & Buchard, A. (2015) · ChemInform · doi:10.1002/chin.201537193
Self-citationMechanisms in Heterobimetallic Reactivity
Singer, F. N., & Buchard, A. (2022) · Wiley eBooks · doi:10.1002/9781119448877.ch4
Self-citationOrganic base-mediated fixation of CO2 into value-added chemicals
Truong, C. C., & Mishra, D. K. (2022) · Elsevier eBooks · doi:10.1016/b978-0-323-85585-3.00010-9
Sustainable and Recyclable Polymers from CO2 and Lignin: Enabling Waste to Wealth TransformationPreprint
Chung, H., & Ghorai, A. (2023) · Research Square · doi:10.21203/rs.3.rs-3256421/v1
Lithium Borate Polycarbonates for High‐Capacity Solid‐State Composite Cathodes
Charlesworth, T., Yiamsawat, K., Gao, H., Rees, G. J., Williams, C. K., Bruce, P. G., Pasta, M., & Gregory, G. L. (2024) · Angewandte Chemie · doi:10.1002/ange.202408246
Self-citationBiodegradable block-copolymers from CO2-derived cyclic carbonates for cationic dye removal
Piacquadio, R., Viscusi, G., Gorrasi, G., & Mazzeo, M. (2026) · European Polymer Journal · doi:10.1016/j.eurpolymj.2026.114945
Gao, X., Zhao, F., & Du, Z. (2026) · Research Square · doi:10.21203/rs.3.rs-10698432/v1
Manganese Metal‐Organic Frameworks as Versatile Catalytic Platforms for Organic Transformations
Poonia, B., & Kumar, V. (2026) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.70311
CO2-Derived Dynamic Covalent Networks via Transesterification-mediated Backbone Functionalization
Chen, K., Zou, C., Liu, Y., Wang, M., Gu, H., Wang, H., Ju, H., Chen, J., & Cao, P. (2026) · Supramolecular Materials · doi:10.1016/j.supmat.2026.100143
- Authors
- Gregory, G. L., Ulmann, M., & Buchard, A.
- Affiliations
- University of Bath (GB)
- Corresponding author
- Buchard, Antoine
- Venue
- RSC Advances
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2015
- Volume
- 5
- Issue
- 49
- Pages
- 39404-39408
- ISSN
- 2046-2069 (ISSN-L)
- OpenAlex
- W2005523412
- Cited by
- 87
- References
- 47
- Citations by year
- 2026: 5 · 2025: 5 · 2024: 8 · 2023: 9 · 2022: 17 · 2021: 8 · 2020: 7 · 2019: 6 · 2018: 11 · 2017: 7 · 2016: 3 · 2015: 1
- FWCI
- 2.76
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- cc-by
- Locations
- RSC Advances (publishedVersion, cc-by)
- Pure (University of Bath) (submittedVersion, cc-by)
- DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion)
- The University of Bath Online Publications Store (The University of Bath) (submittedVersion, cc-by)
- Funders
- University of Bath
- Engineering and Physical Sciences Research Council (EP/J003921/1)
- Topics
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Engineering › Mechanical Engineering › Carbon Dioxide Capture Technologies
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Keywords
- cyclic carbonates, 1,3-diols, low-pressure CO2, phosgene replacement, CO2 utilization, carbonate synthesis
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