Cited by 87Carbon dioxide utilization in catalysisCarbon Dioxide Capture Technologiesbiodegradable polymer synthesis and properties

Synthesis of 6-membered cyclic carbonates from 1,3-diols and low CO 2 pressure: a novel mild strategy to replace phosgene reagents

Open access
Gregory, Georgina L., Ulmann, Marion, Buchard, Antoine·2015·RSC Advances

Abstract

Low pressure CO 2 is used for the synthesis of cyclic carbonates from 1,3-diols in a novel mild alternative to phosgene derivatives.

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Integrity signals

Registry

Crossref · 10.1039/c5ra07290e

Cites

47 of 47 references verified0 citation errors · 0 not checkable

Statistics

Claims the paper makes

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Claims other papers make about this one

Each is checked against this paper’s own text: does it say what the citing paper says it does?

  • The coupling of diols with CO2 occurred at 25 °C and ambient pressure, affording cyclic carbonates in 40-70% yields.

    “The coupling of diols with CO2 occurred at 25 °C and ambient pressure, affording cyclic carbonates in 40-70% yields.”

    From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [202]

  • Buchard reported an efficient two-step procedure using DBU as the base in the first step to activate the hydroxyl group toward carbonylation and NH3/TsCl in the second step to facilitate the cyclization.

    “Recently, Buchard reported an efficient two-step procedure using DBU as the base in the first step to activate the hydroxyl group toward carbonylation and NH3/TsCl in the second step to facilitate the cyclization.202”

    From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [202]

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

The self-check needs the paper’s full text.

Cites

Flagged first, then by citations

Research works printed but not linked: 42

  1. J. Xu, E. Feng and J. Song, J. Appl. Polym. Sci., 2014, 131, 39822-39838;
  2. J. Feng, R.-X. Zhuo and X.-Z. Zhang, Prog. Polym. Sci., 2012, 37, 211-236.
  3. K. Kobayashi, S. Kanmuri, Y. Kimura and K. Masutani, Polym. Int., 2015, 64, 641-646;
  4. C. Koning, J. Wildeson, R. Parton, B. Plum, P. Steeman and D. J. Darensbourg, Polymer, 2001, 42, 3995-4004.
  5. S.-Y. Ku, C. D. Liman, J. E. Cochran, M. F. Toney, M. L. Chabinyc and C. J. Hawker, Adv. Mater., 2011, 23, 2289-2293.
  6. Y. Tominaga, T. Shimomura and M. Nakamura, Polymer, 2010, 51, 4295-4298.
  7. N. Fritz, H. Dao, S. A. B. Allen and P. A. Kohl, Int. J. Adhes. Adhes., 2012, 38, 45-49.
  8. M. R. Kember, A. Buchard and C. K. Williams, Chem. Commun., 2011, 47, 141-163.
  9. J. H. Park, J. Y. Jeon, J. J. Lee, Y. Jang, J. K. Varghese and B. Y. Lee, Macromolecules, 2013, 46, 3301-3308;
  10. W. Zhu, X. Huang, C. Li, Y. Xiao, D. Zhang and G. Guan, Polym. Int., 2011, 60, 1060-1067;
  11. G. Rokicki, J. Pawlicki and W. Kuran, Polym. J., 1982, 14, 839-845; (
  12. Y. Ono, Catal. Today, 1997, 35, 15-25;
  13. G. Rokicki, Prog. Polym. Sci., 2000, 25, 259-342.
  14. S. M. Guillaume and J.-F. Carpentier, Catal. Sci. Technol., 2012, 2, 898-906.
  15. S. Tempelaar, L. Mespouille, O. Coulembier, P. Dubois and A. P. Dove, Chem. Soc. Rev., 2013, 42, 1312-1336;
  16. M. Azechi, K. Matsumoto and T. Endo, J. Polym. Sci., Part A: Polym. Chem., 2013, 51, 1651-1655;
  17. W. Guerin, A. K. Diallo, E. Kirilov, M. Helou, M. Slawinski, J.-M. Brusson, J.-F. Carpentier and S. M. Guillaume, Macromolecules, 2014, 47, 4230-4235;
  18. W. Guerin, M. Helou, M. Slawinski, J.-M. Brusson, J.-F. Carpentier and S. M. Guillaume, Polym. Chem., 2015, 6, 1972-1985;
  19. A. K. Diallo, E. Kirillov, M. Slawinski, J.-M. Brusson, S. M. Guillaume and J.-F. Carpentier, Polym. Chem., 2015, 6, 1961-1971.
  20. A.-A. G. Shaikh and S. Sivaram, Chem. Rev., 1996, 96, 951- 976.
  21. H. A. Staab, Angew. Chem., Int. Ed. Engl., 1962, 1, 351-367.
  22. Y. Basel and A. Hassner, J. Org. Chem., 2000, 65, 6368-6380.
  23. J. Mindemark and T. Bowden, Polymer, 2011, 52, 5716-5722.
  24. D. P. Sanders, K. Fukushima, D. J. Coady, A. Nelson, M. Fujiwara, M. Yasumoto and J. L. Hedrick, J. Am. Chem. Soc., 2010, 132, 14724-14726;
  25. D. P. Sanders, D. J. Coady, M. Yasumoto, M. Fujiwara, H. Sardon and J. L. Hedrick, Polym. Chem., 2014, 5, 327-329;
  26. K. Mikami, A. T. Lonnecker, T. P. Gustafson, N. F. Zinnel, P. J. Pai, D. H. Russell and K. L. Wooley, J. Am. Chem. Soc., 2013, 135, 6826-6829;
  27. B. Gabriele, R. Mancuso, G. Salerno, L. Veltri, M. Costa and A. Dibenedetto, ChemSusChem, 2011, 4, 1778-1786;
  28. D. M. Pearson, N. R. Conley and R. M. Waymouth, Adv. Synth. Catal., 2011, 353, 3007-3013.
  29. C. Martín, G. Fiorani and A. W. Kleij, ACS Catal., 2015, 5, 1353-1370.
  30. J. A. Burkhard, G. Wuitschik, M. Rogers-Evans, K. Müller and E. M. Carreira, Angew. Chem., Int. Ed., 2010, 49, 9052-9067.
  31. Q. Li, W. Zhang, N. Zhao, W. Wei and Y. Sun, Catal. Today, 2006, 115, 111-116;
  32. Q. Li, N. Zhao, W. Wei and Y. Sun, J. Mol. Catal. A: Chem., 2007, 270, 44-49.
  33. D. Chaturvedi, N. Mishra and V. Mishra, Tetrahedron Lett., 2007, 48, 5043-5045;
  34. M. Tamura, M. Honda, Y. Nakagawa and K. Tomishige, J. Chem. Technol. Biotechnol., 2014, 89, 19-33.
  35. M. Honda, M. Tamura, K. Nakao, K. Suzuki, Y. Nakagawa and K. Tomishige, ACS Catal., 2014, 4, 1893-1896.
  36. Y. N. Lim, C. Lee and H.-Y. Jang, Eur. J. Org. Chem., 2014, 9, 1823-1826.
  37. M. R. Reithofer, Y. N. Sum and Y. Zhang, Green Chem., 2013, 15, 2086-2090.
  38. P. G. Jessop, D. J. Heldebrant, X. Li, C. A. Eckert and C. L. Liotta, Nature, 2005, 436, 1102.
  39. P. M. Mathias, K. Afshar, F. Zheng, M. D. Bearden, C. J. Freeman, T. Andrea, P. K. Koech, I. Kutnyakov, A. Zwoster, A. R. Smith, P. G. Jessop, O. G. Nik and D. J. Heldebrant, Energy Environ. Sci., 2013, 6, 2233-2242;
  40. L. Phan, J. R. Andreatta, L. K. Horvey, C. F. Edie, A.-L. Luco, A. Mirchandani, D. J. Darensbourg and P. G. Jessop, J. Org. Chem., 2008, 73, 127-132.
  41. H. Yasuda, M.-S. Aludin, N. Kitamura, M. Tanabe and H. Sirahama, Macromolecules, 1999, 32, 6047-6057.
  42. B. J. Ludwig and E. C. Piech, J. Am. Chem. Soc., 1951, 73, 5779-5781.

Cited by

Sorted by citations

Authors
Gregory, G. L., Ulmann, M., & Buchard, A.
Affiliations
University of Bath (GB)
Corresponding author
Buchard, Antoine
Venue
RSC Advances
Published
2015
Volume
5
Issue
49
Pages
39404-39408
ISSN
2046-2069 (ISSN-L)
OpenAlex
W2005523412
Cited by
87
References
47
Citations by year
2026: 5 · 2025: 5 · 2024: 8 · 2023: 9 · 2022: 17 · 2021: 8 · 2020: 7 · 2019: 6 · 2018: 11 · 2017: 7 · 2016: 3 · 2015: 1
FWCI
2.76
Type
journal article
Language
en
Open access
Licence
cc-by
Locations
  • RSC Advances (publishedVersion, cc-by)
  • Pure (University of Bath) (submittedVersion, cc-by)
  • DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion)
  • The University of Bath Online Publications Store (The University of Bath) (submittedVersion, cc-by)
Funders
  • University of Bath
  • Engineering and Physical Sciences Research Council (EP/J003921/1)
Topics
  • Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
  • Physical Sciences › Engineering › Mechanical Engineering › Carbon Dioxide Capture Technologies
  • Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
Keywords
cyclic carbonates, 1,3-diols, low-pressure CO2, phosgene replacement, CO2 utilization, carbonate synthesis

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review