Cited by 209Advanced oxidation water treatmentMetal-Catalyzed Oxygenation MechanismsPhysical Organic Chemistry and Reaction Kinetics

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The Fenton Reaction. Dependence of the Rate on pH

Kremer, Mordechai L.·2003·The Journal of Physical Chemistry A

DOI 10.1021/jp020654p

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Abstract

The pH dependence of the evolution of O 2 in the Fenton reaction has been studied by using an indirect method for measuring [O 2 ]. The results confirmed observations of previous workers, namely, that the evolution of O 2 diminished as the pH was lowered. A quantitative analysis of the dependence of [O 2 ] and [Fe 2+ ] during the reaction as a function of time showed that the pH dependence of the course of the reaction can be accounted for by assuming an acid base reaction of the active intermediate: FeO 2+ + H + ⇌ FeOH 3+ . FeOH 3+ is the active entity in the reaction with Fe 2+ to produce Fe 3+ ions, while the other form FeO 2+ is involved in reactions leading to O 2 evolution.

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Authors: Kremer, M. L.
Affiliations: Hebrew University of Jerusalem (IL)
Corresponding author: Kremer, Mordechai L.
ORCID: Kremer, Mordechai L.
Venue: The Journal of Physical Chemistry A
Publisher: American Chemical Society (ACS)
Published: 2003-02-20
Volume: 107
Issue: 11
Pages: 1734-1741
ISSN: 1089-5639 (ISSN-L)
1520-5215
DOI: 10.1021/jp020654p
OpenAlex: W2015577313
Cited by: 197
References: 25
Citations by year: 2026: 10 · 2025: 14 · 2024: 12 · 2023: 12 · 2022: 11 · 2021: 10 · 2020: 14 · 2019: 14 · 2018: 6 · 2017: 9 · 2016: 7 · 2015: 7 · 2014: 4 · 2013: 8 · 2012: 10
FWCI: 9.64
Type: journal article
Language: en
Open access: closed
Locations: The Journal of Physical Chemistry A (publishedVersion)
Topics: Physical Sciences › Environmental Science › Water Science and Technology › Advanced oxidation water treatment
Physical Sciences › Chemistry › Inorganic Chemistry › Metal-Catalyzed Oxygenation Mechanisms
Physical Sciences › Chemistry › Organic Chemistry › Physical Organic Chemistry and Reaction Kinetics
Keywords: Fenton reaction, pH dependence, oxygen evolution reaction, acid-base balance, iron(II) oxidation, reaction kinetics

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The Fenton Reaction. Dependence of the Rate on pH

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