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The Fenton Reaction. Dependence of the Rate on pH
Abstract
The pH dependence of the evolution of O 2 in the Fenton reaction has been studied by using an indirect method for measuring [O 2 ]. The results confirmed observations of previous workers, namely, that the evolution of O 2 diminished as the pH was lowered. A quantitative analysis of the dependence of [O 2 ] and [Fe 2+ ] during the reaction as a function of time showed that the pH dependence of the course of the reaction can be accounted for by assuming an acid base reaction of the active intermediate: FeO 2+ + H + ⇌ FeOH 3+ . FeOH 3+ is the active entity in the reaction with Fe 2+ to produce Fe 3+ ions, while the other form FeO 2+ is involved in reactions leading to O 2 evolution.
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“Fenton chemistry is not straightforward, and it is performed through numerous reactions, depending upon various active intermediates, such as [Fe IV O] 2+ and hydroxyl radicals 84,85 .”
From Removal of heavy metal ions from wastewater: a comprehensive and critical review (2021) · cites this paper as [84]
Citations
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Removal of heavy metal ions from wastewater: a comprehensive and critical review
Qasem, N. A. A., Mohammed, R. H., & Lawal, D. U. (2021) · npj Clean Water · doi:10.1038/s41545-021-00127-0 · Cited by 2,225
Electrochemical synthesis of hydrogen peroxide from water and oxygen
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Kim, J., Cho, H. R., Jeon, H., Kim, D., Song, C., Lee, N., Choi, S. H., & Hyeon, T. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b05559 · Cited by 714
Tropospheric Aqueous-Phase Chemistry: Kinetics, Mechanisms, and Its Coupling to a Changing Gas Phase
Herrmann, H., Schaefer, T., Tilgner, A., Styler, S. A., Weller, C., Teich, M., & Otto, T. (2015) · Chemical Reviews · doi:10.1021/cr500447k · Cited by 695
High-valent iron in chemical and biological oxidations
Groves, J. T. (2006) · Journal of Inorganic Biochemistry · doi:10.1016/j.jinorgbio.2006.01.012 · Cited by 626
Metadata
- Authors
- Kremer, M. L.
- Affiliations
- Hebrew University of Jerusalem (IL)
- Corresponding author
- Kremer, Mordechai L.
- ORCID
- Kremer, Mordechai L.
- Venue
- The Journal of Physical Chemistry A
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-02-20
- Volume
- 107
- Issue
- 11
- Pages
- 1734-1741
- ISSN
- 1089-5639 (ISSN-L)
- 1520-5215
- OpenAlex
- W2015577313
- Cited by
- 197
- References
- 25
- Citations by year
- 2026: 10 · 2025: 14 · 2024: 12 · 2023: 12 · 2022: 11 · 2021: 10 · 2020: 14 · 2019: 14 · 2018: 6 · 2017: 9 · 2016: 7 · 2015: 7 · 2014: 4 · 2013: 8 · 2012: 10
- FWCI
- 9.64
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- The Journal of Physical Chemistry A (publishedVersion)
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Advanced oxidation water treatment
- Physical Sciences › Chemistry › Inorganic Chemistry › Metal-Catalyzed Oxygenation Mechanisms
- Physical Sciences › Chemistry › Organic Chemistry › Physical Organic Chemistry and Reaction Kinetics
- Keywords
- Fenton reaction, pH dependence, oxygen evolution reaction, acid-base balance, iron(II) oxidation, reaction kinetics
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