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Cited by 400

The DOI matches its Crossref record; 32 of the 32 references it cites were found in a registry or an index.

Full Valence Band Photoemission from Liquid Water Using EUV Synchrotron Radiation

Winter, B., Weber, R., Widdra, W., Dittmar, M., Faubel, M., Hertel, I. V.·2004·The Journal of Physical Chemistry A
DOI 10.1021/jp030263q
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Abstract

The valence band photoelectron spectra of liquid water (H 2 O and D 2 O) are studied in the photon energy range from h ν = 60 to 120 eV. The experiments use a 6 μm diameter liquid-jet free vacuum surface at the MBI undulator beamline of the synchrotron radiation facility BESSY. Photoelectron emission from all four valence molecular orbitals (MOs) is observed. In comparison to those of the gas phase, the peaks are significantly broadened and shifted to lower binding energies by about 1.5 eV. This is attributed primarily to the electronic polarization of the solvent molecules around an ionized water molecule. Energy shifts, peak broadening, and relative peak intensities for the four MOs differ because of their specific participation in the hydrogen bonding in liquid water. Relative photoionization cross sections for MOs were measured for h ν = 60, 80, and 100 eV. The main difference for liquid water, as compared to the gas phase, is the relative intensity decrease of the 1 b 2 and 3 a 1 orbitals, reflecting changes of the MOs due to H-bonding.

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Metadata

Authors
Winter, B., Weber, R., Widdra, W., Dittmar, M., Faubel, M., & Hertel, I. V.
Venue
The Journal of Physical Chemistry A
Publisher
American Chemical Society (ACS)
Published
2004-03-16
Volume
108
Issue
14
Pages
2625-2632
ISSN
  • 1089-5639 (ISSN-L)
  • 1520-5215
DOI
10.1021/jp030263q
OpenAlex
W1969607108
Cited by
400
References
32
FWCI
5.72
Type
journal article
Language
en
Open access
closed

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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.