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Cited by 3,085

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Anisotropic Metal Nanoparticles: Synthesis, Assembly, and Optical Applications

Murphy, Catherine J., Sau, Tapan K., Gole, Anand M., Orendorff, Christopher J., Gao, Jinxin, Gou, Linfeng, Hunyadi, Simona E., Li, Tan·2005·The Journal of Physical Chemistry B
DOI 10.1021/jp0516846
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Abstract

This feature article highlights work from the authors' laboratories on the synthesis, assembly, reactivity, and optical applications of metallic nanoparticles of nonspherical shape, especially nanorods. The synthesis is a seed-mediated growth procedure, in which metal salts are reduced initially with a strong reducing agent, in water, to produce approximately 4 nm seed particles. Subsequent reduction of more metal salt with a weak reducing agent, in the presence of structure-directing additives, leads to the controlled formation of nanorods of specified aspect ratio and can also yield other shapes of nanoparticles (stars, tetrapods, blocks, cubes, etc.). Variations in reaction conditions and crystallographic analysis of gold nanorods have led to insight into the growth mechanism of these materials. Assembly of nanorods can be driven by simple evaporation from solution or by rational design with molecular-scale connectors. Short nanorods appear to be more chemically reactive than long nanorods. Finally, optical applications in sensing and imaging, which take advantage of the visible light absorption and scattering properties of the nanorods, are discussed.

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Cited by

Items 101–113 of 113

Metadata

Authors
Murphy, C. J., Sau, T. K., Gole, A. M., Orendorff, C. J., Gao, J., Gou, L., Hunyadi, S. E., & Li, T.
Venue
The Journal of Physical Chemistry B
Publisher
American Chemical Society (ACS)
Published
2005-06-18
Volume
109
Issue
29
Pages
13857-13870
ISSN
  • 1520-5207 (ISSN-L)
  • 1520-6106
DOI
10.1021/jp0516846
OpenAlex
W2040958578
Cited by
3,085
References
77
FWCI
74.64
Type
journal article
Language
en
Open access
closed

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