Probing the Gold Nanorod−Ligand−Solvent Interface by Plasmonic Absorption and Thermal Decay
Abstract
Thermal transport between CTAB passivated gold nanorods and solvent is studied by an optical pump−probe technique. Increasing the free CTAB concentration from 1 mM to 10 mM causes a ∼3× increase in the CTAB layer’s effective thermal interface conductance and a corresponding shift in the longitudinal surface plasmon resonance. The transition occurs near the CTAB critical micelle concentration, revealing the importance of the role of free ligand on thermal transport.
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TDTR can also be easily adapted to transient absorption and be exploited to study thermophysical phenomena in nanoparticle solutions, such as the heat diffusion from particles to the surroundings and thermal transport across surfactants.
“TDTR can also be easily adapted to transient absorption and be exploited to study thermophysical phenomena in nanoparticle solutions, such as the heat diffusion from particles to the surroundings and thermal transport across surfactants, 240-243”
From Tutorial: Time-domain thermoreflectance (TDTR) for thermal property characterization of bulk and thin film materials (2018) · cites this paper as [240]
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- Authors
- Schmidt, A. J., Alper, J. D., Chiesa, M., Chen, G., Das, S. K., & Hamad-Schifferli, K.
- Affiliations
- Indian Institute of Technology Madras (IN)
- Department of Mechanical Engineering, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, Program of Mechanical Engineering, Masdar Institute of Science and Technology, UAE, Department of Mechanical Engineering, Indian Institute of Technology, Madras, India, and Department of Biological Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139
- Corresponding author
- Chen, Gang
- Das, Sarit K.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-08-12
- Volume
- 112
- Issue
- 35
- Pages
- 13320-13323
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2044047596
- Cited by
- 91
- References
- 35
- Citations by year
- 2025: 4 · 2024: 4 · 2023: 4 · 2022: 8 · 2021: 2 · 2020: 4 · 2019: 4 · 2018: 7 · 2017: 9 · 2016: 11 · 2015: 8 · 2014: 6 · 2013: 3 · 2012: 8
- FWCI
- 1.15
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- The Journal of Physical Chemistry C (publishedVersion)
- Funders
- Division of Materials Research
- Topics
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Gold and Silver Nanoparticles Synthesis and Applications
- Physical Sciences › Engineering › Biomedical Engineering › Plasmonic and Surface Plasmon Research
- Physical Sciences › Materials Science › Materials Chemistry › Thermal properties of materials
- Keywords
- gold nanorods, interface thermal conductance, thermal decay, surface plasmon resonance, critical micelle concentration, ligand concentration, heat transport, optical pump-probe
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