The DOI matches its Crossref record; 32 of the 32 references it cites were found in a registry or an index.
Evolution of the Adsorbed Water Layer Structure on Silicon Oxide at Room Temperature
Abstract
The molecular configuration of water adsorbed on a hydrophilic silicon oxide surface at room temperature has been determined as a function of relative humidity using attenuated total reflection (ATR)-infrared spectroscopy. A completely hydrogen-bonded icelike network of water grows up to three layers as the relative humidity increases from 0 to 30%. In the relative humidity range of 30-60%, the liquid water structure starts appearing while the icelike structure continues growing to saturation. The total thickness of the adsorbed layer increases only one molecular layer in this humidity range. Above 60% relative humidity, the liquid water configuration grows on top of the icelike layer. This structural evolution indicates that the outermost layer of the adsorbed water molecules undergoes transitions in equilibrium behavior as humidity varies. These transitions determine the shape of the adsorption isotherm curve. The structural transitions of the outermost adsorbed layer are accompanied by interfacial energy changes and explain many phenomena observed only for water adsorption.
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Cited by
Lipatov, A., Alhabeb, M., Lukatskaya, M. R., Boson, A., Gogotsi, Y., & Sinitskii, A. (2016) · Advanced Electronic Materials · doi:10.1002/aelm.201600255 · Cited by 1,751
Molecular Structure of Water at Interfaces: Wetting at the Nanometer Scale
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Glover, R. D., Miller, J. M., & Hutchison, J. E. (2011) · ACS Nano · doi:10.1021/nn2031319 · Cited by 303
Ion Diffusion Within Water Films in Unsaturated Porous Media
Tokunaga, T. K., Finsterle, S., Kim, Y., Wan, J., Lanzirotti, A., & Newville, M. (2017) · Environmental Science & Technology · doi:10.1021/acs.est.6b05891 · Cited by 46
Water Structure Controls Carbonic Acid Formation in Adsorbed Water Films
Miller, Q. R. S., Ilton, E. S., Qafoku, O., Dixon, D. A., Vasiliu, M., Thompson, C. J., Schaef, H. T., Rosso, K. M., & Loring, J. S. (2018) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.8b02162 · Cited by 19
Metadata
- Authors
- Asay, D. B., & Kim, S. H.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-08-13
- Volume
- 109
- Issue
- 35
- Pages
- 16760-16763
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W1983279622
- Cited by
- 732
- References
- 32
- FWCI
- 6.01
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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