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Cited by 317

The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.

Oxygen Reduction on Silver Low-Index Single-Crystal Surfaces in Alkaline Solution: Rotating Ring DiskAg(hkl) Studies

Blizanac, B. B., Ross, P. N., Marković, N. M.·2006·The Journal of Physical Chemistry B

Abstract

The rotating ring disk method is applied to investigate the oxygen reduction reaction on Ag single-crystal surfaces in alkaline solution over the temperature range 293-333 K. At all temperatures, the oxygen reduction reaction proceeds through the 4e- reaction pathway with a very small (approximately 0.5-2%) peroxide formation. At the same temperature and overpotentials, the kinetics of the ORR always increases in the order (100) < or = (111) < (110), indicating that the reaction is structure-sensitive. We present an interpretation of the structure sensitivity based on the supposition that it arises from (i) a potential-dependent adsorption of spectator hydroxyl ions and (ii) variations in activation energies, which are determined by the O2 adsorption on Ag single-crystal surfaces covered by adsorbed oxygenated species.

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Metadata

Authors
Blizanac, B. B., Ross, P. N., & Marković, N. M.
Venue
The Journal of Physical Chemistry B
Published
2006-02-22
Volume
110
Issue
10
Pages
4735-4741
ISSN
  • 1520-5207 (ISSN-L)
  • 1520-6106
OpenAlex
W1965636614
Cited by
317
References
1
FWCI
3.84
Type
journal article
Language
en
Open access
closed

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