The DOI matches its Crossref record; 13 of the 13 references it cites were found in a registry or an index.
Nanoparticle Silver Catalysts That Show Enhanced Activity for Carbon Dioxide Electrolysis
Abstract
Electrochemical conversion of CO 2 has been proposed both as a way to reduce CO 2 emissions and as a source of renewable fuels and chemicals, but conversion rates need improvement before the process will be practical. In this article, we show that the rate of CO 2 conversion per unit surface area is about 10 times higher on 5 nm silver nanoparticles than on bulk silver even though measurements on single crystal catalysts show much smaller variations in rate. The enhancement disappears on 1 nm particles. We attribute this effect to a volcano effect associated with changes of the binding energy of key intermediates as the particle size decreases. These results demonstrate that nanoparticle catalysts have unique properties for CO 2 conversion.
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Cites
Ionic Liquid–Mediated Selective Conversion of CO 2 to CO at Low Overpotentials
Rosen, B. A., Salehi-Khojin, A., Thorson, M. R., Zhu, W., Whipple, D. T., Kenis, P. J. A., & Masel, R. I. (2011) · Science · doi:10.1126/science.1209786 · Cited by 1,558
Self-citationPrinciples of Adsorption and Reaction on Solid Surfaces
Masel, R. I. (1996) · Cited by 1,531
Self-citationProspects of CO2 Utilization via Direct Heterogeneous Electrochemical Reduction
Whipple, D. T., & Kenis, P. J. A. (2010) · The Journal of Physical Chemistry Letters · doi:10.1021/jz1012627 · Cited by 1,417
Self-citationStructure sensitivity and nanoscale effects in electrocatalysis
Koper, M. T. M. (2011) · Nanoscale · doi:10.1039/c0nr00857e · Cited by 468
Microfluidic Reactor for the Electrochemical Reduction of Carbon Dioxide: The Effect of pH
Whipple, D. T., Finke, E. C., & Kenis, P. J. A. (2010) · Electrochemical and Solid-State Letters · doi:10.1149/1.3456590 · Cited by 375
Self-citationBlizanac, B. B., Ross, P. N., & Marković, N. M. (2006) · The Journal of Physical Chemistry B · doi:10.1021/jp056050d · Cited by 317
Work function measurements on (100) and (110) surfaces of silver
Dweydari, A. W., & Mee, C. H. B. (1975) · Physica Status Solidi (a) · doi:10.1002/pssa.2210270126 · Cited by 310
Electrochemical reduction of CO2 on single crystal electrodes of silver Ag(111), Ag(100) and Ag(110)
Hoshi, N., Kato, M., & Hori, Y. (1997) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(97)00447-6 · Cited by 304
Rosen, B. A., Haan, J. L., Mukherjee, P., Braunschweig, B., Zhu, W., Salehi-Khojin, A., Dlott, D. D., & Masel, R. I. (2012) · The Journal of Physical Chemistry C · doi:10.1021/jp210542v · Cited by 270
Self-citationBasic Research Needs: Catalysis for Energy
Bell, A. T., Gates, B. C., Ray, D., & Thompson, M. R. (2008) · OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) · doi:10.2172/927492 · Cited by 125
Cited by
Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces
Kuhl, K. P., Hatsukade, T., Cave, E. R., Abram, D. N., Kibsgaard, J., & Jaramillo, T. F. (2014) · Journal of the American Chemical Society · doi:10.1021/ja505791r · Cited by 1,649
Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide
Zhu, D. D., Liu, J. L., & Qiao, S. Z. (2016) · Advanced Materials · doi:10.1002/adma.201504766 · Cited by 1,594
Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
Zhang, L., Zhao, Z., & Gong, J. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201612214 · Cited by 1,048
A Gross‐Margin Model for Defining Technoeconomic Benchmarks in the Electroreduction of CO2
Verma, S., Kim, B., Jhong, H. “., Ma, S., & Kenis, P. J. A. (2016) · ChemSusChem · doi:10.1002/cssc.201600394 · Cited by 655
Self-citation
Metadata
- Authors
- Salehi-Khojin, A., Jhong, H.-R. M., Rosen, B. A., Zhu, W., Ma, S., Kenis, P. J. A., & Masel, R. I.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-01-17
- Volume
- 117
- Issue
- 4
- Pages
- 1627-1632
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2110045599
- Cited by
- 435
- References
- 13
- FWCI
- 6.68
- Type
- journal article
- Language
- en
- Open access
- closed
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