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Cited by 56Material Dynamics and PropertiesThermodynamic properties of mixturesnanoparticles nucleation surface interactions

The DOI matches its Crossref record; 41 of the 41 references it cites were found in a registry or an index.

Thermal Properties and Mixing State of Ethylene Glycol−Water Binary Solutions by Calorimetry, Large-Angle X-ray Scattering, and Small-Angle Neutron Scattering

Matsugami, Masaru, Takamuku, Toshiyuki, Otomo, Toshiya, Yamaguchi, Toshio·2006·The Journal of Physical Chemistry B
DOI 10.1021/jp061456r
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Abstract

Thermal properties and mixing states of ethylene glycol (EG)-water binary solutions in the entire mole fraction range of EG, 0 < or = x(EG) < or = 1, have been clarified by using differential scanning calorimetry (DSC), large-angle X-ray scattering (LAXS), and small-angle neutron scattering (SANS) techniques. The DSC curves obtained have shown that the EG-water solutions over the range of EG mole fraction 0.3 < or = x(EG) < or = 0.5 are kept in the supercooling state until approximately 100 K, and those in the range of 0.6 < or = x(EG) < or = 0.8 are vitrified, and those in the ranges of 0 < x(EG) < or = 0.2 and 0.9 < or = x(EG) < 1 are crystallized. The radial distribution function (RDF) for pure EG obtained from the LAXS measurements has suggested that a gauche conformation of an EG molecule is favorable in the liquid. The RDFs for the EG-water solutions have shown that the structure of the binary solutions moderately changes from the inherent structure of EG to the tetrahedral-like structure of water when the water content increases. The SANS intensities for deuterated ethylene glycol (HOCD2CD2OH) (EGd4)-water solutions at x(EG) = 0.4 and 0.6 have not been significantly observed in the temperature range from 298 to 173 K, showing that EG and water molecules are homogeneously mixed. On the other hand, the SANS intensities at x(EG) = 0.2 and 0.9 have been strengthened when the temperature decreases due to crystallization of the solutions. On the basis of all the present results, a relation between thermal properties of EG-water binary solutions and their mixing states clarified by the LAXS and SANS measurements has been discussed at the molecular level.

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Crossref · 10.1021/jp061456r

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41 of 41 references verified0 citation errors · 0 not checkable

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  • Organohydrogel method can effectively improve mechanical stretchability and multi-stimuli sensitivity of hydrogels.

    “this method can effectively improve the mechanical stretchability and multi-stimuli sensitivity of hydrogels”

    From Functionalized Hydrogel-Based Wearable Gas and Humidity Sensors. (2023) · cites this paper as [162]

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Research works printed but not linked: 6

  1. Ihara M., 1994, Adv. X-ray Anal. Jpn., 25, 49
  2. Johanson G., 1973, Chem. Scr., 4, 195
  3. Riddick J. A., 1986, Techniques of Chemistry
  4. (a) Nishi, N.; Matsumoto, M.; Takahashi, S.; Takamuku, T.; Yamagami, M.; Yamaguchi, T.Structures and Dynamics of Clusters; Kondow, T., Kaya, K., Terasaki, A., Eds.; Universal Academic Press, Inc., and Yamada Science Foundation: 1996; pp 113−120.
  5. Matsumoto M., 1996, Kyushu University
  6. Powder Diffraction File Sets, 1974, Inorganic

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Metadata

Authors
Matsugami, M., Takamuku, T., Otomo, T., & Yamaguchi, T.
Affiliations
High Energy Accelerator Research Organization (JP)
ORCID
Venue
The Journal of Physical Chemistry B
Publisher
American Chemical Society (ACS)
Published
2006-06-01
Volume
110
Issue
25
Pages
12372-12379
ISSN
  • 1520-5207 (ISSN-L)
  • 1520-6106
DOI
10.1021/jp061456r
OpenAlex
W2023444704
Cited by
56
References
41
Citations by year
2026: 1 · 2025: 2 · 2023: 6 · 2022: 5 · 2021: 6 · 2020: 1 · 2019: 2 · 2018: 3 · 2017: 4 · 2016: 4 · 2015: 2 · 2014: 2 · 2013: 6 · 2012: 2
FWCI
0.87
Type
journal article
Language
en
Open access
closed
Locations
  • The Journal of Physical Chemistry B (publishedVersion)
  • PubMed (publishedVersion)
  • Institutional Repositories DataBase (IRDB) (submittedVersion)
Funders
Fukuoka University
Topics
  • Physical Sciences › Materials Science › Materials Chemistry › Material Dynamics and Properties
  • Physical Sciences › Chemical Engineering › Fluid Flow and Transfer Processes › Thermodynamic properties of mixtures
  • Physical Sciences › Chemistry › Physical and Theoretical Chemistry › nanoparticles nucleation surface interactions
Keywords
mixing state, supercooling, vitrification, crystallization, radial distribution function, gauche conformation, tetrahedral water structure, homogeneous mixing, molecular structure, thermal properties

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