The DOI matches its Crossref record; 27 of the 27 references it cites were found in a registry or an index.
Catalytic Activity−d-Band Center Correlation for the O2Reduction Reaction on Platinum in Alkaline Solutions
Abstract
We determined, by the rotating disk electrode technique, the kinetics of the oxygen-reduction reaction (ORR) on the surfaces of single crystals of Au(111), Ag(111), Pd(111), Rh(111), Ir(111), and Ru(0001), on Pt monolayers deposited on their surfaces, and also on nanoparticles of these metals dispersed on high-surface-area carbon. Plotting the correlation between the experimentally determined activities of these three types of electrocatalysts with the calculated metal d -band center energies, ε d, revealed a volcano-type dependence. In all cases, the electronic properties of the metal electrocatalysts, represented by the ε d value, were used for elucidating the metal-dependent catalytic activities, and establishing their electronic properties the ORR kinetics relationship. Pt(111), Pt/C, and Pt/Pd(111) were found to top their corresponding volcano plots. Pd in alkaline solutions showed particularly high activity, suggesting it may offer potential replacement for Pt in fuel cells.
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Cites
Soft self-consistent pseudopotentials in a generalized eigenvalue formalism
Vanderbilt, D. (1990) · Physical Review B · doi:10.1103/physrevb.41.7892 · Cited by 23,185
Hammer, B., Hansen, L. B., & Nørskov, J. K. (1999) · Physical Review B · doi:10.1103/physrevb.59.7413 · Cited by 8,270
Theoretical surface science and catalysis—calculations and concepts
Hammer, B., & Nørskov, J. K. (2000) · Advances in Catalysis · doi:10.1016/s0360-0564(02)45013-4 · Cited by 3,972
Electronic factors determining the reactivity of metal surfaces
Hammer, B., & Nørskov, J. K. (1995) · Surface Science · doi:10.1016/0039-6028(96)80007-0 · Cited by 2,871
Stamenkovic, V., Mun, B. S., Mayrhofer, K. J. J., Ross, P. N., Markovic, N. M., Rossmeisl, J., Greeley, J., & Nørskov, J. K. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200504386 · Cited by 2,109
Kitchin, J. R., Nørskov, J. K., Barteau, M. A., & Chen, J. G. (2004) · The Journal of Chemical Physics · doi:10.1063/1.1737365 · Cited by 1,358
Enhancement of the Electroreduction of Oxygen on Pt Alloys with Fe, Ni, and Co
Toda, T., Igarashi, H., Uchida, H., & Watanabe, M. (1999) · Journal of The Electrochemical Society · doi:10.1149/1.1392544 · Cited by 1,336
Alloy catalysts designed from first principles
Greeley, J., & Mavrikakis, M. (2004) · Nature Materials · doi:10.1038/nmat1223 · Cited by 1,156
Mukerjee, S., Srinivasan, S., Soriaga, M. P., & McBreen, J. (1995) · Journal of The Electrochemical Society · doi:10.1149/1.2048590 · Cited by 1,155
Zhang, J., Vukmirovic, M. B., Xu, Y., Mavrikakis, M., & Adzic, R. R. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200462335 · Cited by 1,106
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Cited by
Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions
Jiao, Y., Zheng, Y., Jaroniec, M., & Qiao, S. Z. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00470a · Cited by 5,388
Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis
Hong, W. T., Risch, M., Stoerzinger, K. A., Grimaud, A., Suntivich, J., & Shao-Horn, Y. (2015) · Energy & Environmental Science · doi:10.1039/c4ee03869j · Cited by 2,089
Hydrogen Oxidation and Evolution Reaction Kinetics on Platinum: Acid vs Alkaline Electrolytes
Sheng, W., Gasteiger, H. A., & Shao-Horn, Y. (2010) · Journal of The Electrochemical Society · doi:10.1149/1.3483106 · Cited by 1,829
Oxygen Reduction in Alkaline Media: From Mechanisms to Recent Advances of Catalysts
Ge, X., Sumboja, A., Wuu, D., An, T., Li, B., Goh, F. W. T., Hor, T. S. A., Zong, Y., & Liu, Z. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00524 · Cited by 1,341
Theory-guided design of catalytic materials using scaling relationships and reactivity descriptors
Zhao, Z.-J., Liu, S., Zha, S., Cheng, D., Studt, F., Henkelman, G., & Gong, J. (2019) · Nature Reviews Materials · doi:10.1038/s41578-019-0152-x · Cited by 657
Metadata
- Authors
- Lima, F. H. B., Zhang, J., Shao, M. H., Sasaki, K., Vukmirovic, M. B., Ticianelli, E. A., & Adzic, R. R.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-12-01
- Volume
- 111
- Issue
- 1
- Pages
- 404-410
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2012922112
- Cited by
- 678
- References
- 27
- FWCI
- 6.39
- Type
- journal article
- Language
- en
- Open access
- closed
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- Lima, F. H. B., Zhang, J., Shao, M. H., Sasaki, K., Vukmirovic, M. B., Ticianelli, E. A., & Adzic, R. R. (2007). Catalytic Activity−d-Band Center Correlation for the O2Reduction Reaction on Platinum in Alkaline Solutions. The Journal of Physical Chemistry C. https://doi.org/10.1021/jp065181r
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