The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Electrode/Electrolyte Interface Reactivity in High-Voltage Spinel LiMn1.6Ni0.4O4/Li4Ti5O12 Lithium-Ion Battery
Abstract
High-voltage spinel oxides combined with Li 4 Ti 5 O 12 result in 3 V lithium-ion batteries with a high power capability; however, the electrochemical performances are limited by electrode/electrolyte interfacial reactivity at high potential. We have investigated electrode/electrolyte interfaces in LiMn 1.6 Ni 0.4 O 4 /Li 4 Ti 5 O 12 cells by X-ray photoelectron spectroscopy (XPS) and electrochemical impedance spectrocopy (EIS). EIS has shown that both electroadsorption and film-formation mechanisms occur at the positive electrode. XPS has revealed that very low amounts of lithiated species are deposited at the surface of the positive electrode, despite the high potential, but that great amounts of organic species are deposited. Interesting results were obtained for the Li 4 Ti 5 O 12 electrode. Whereas Li 4 Ti 5 O 12 is usually considered as a passivation-free electrode material, large amounts of organic and inorganic species were deposited at the surface of this electrode. The question of a possible interaction between both electrodes in the formation mechanisms of surface films is discussed.
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Hüfner, S. (1995) · Springer Series in Solid-State Sciences · doi:10.1007/978-3-662-03150-6 · Cited by 854
Cited by
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Xu, K. (2014) · Chemical Reviews · doi:10.1021/cr500003w · Cited by 5,566
Review on recent progress of nanostructured anode materials for Li-ion batteries
Goriparti, S., Miele, E., De Angelis, F., Di Fabrizio, E., Proietti Zaccaria, R., & Capiglia, C. (2014) · Journal of Power Sources · doi:10.1016/j.jpowsour.2013.11.103 · Cited by 2,092
Reversible anionic redox chemistry in high-capacity layered-oxide electrodes
Sathiya, M., Rousse, G., Ramesha, K., Laisa, C. P., Vezin, H., Sougrati, M. T., Doublet, M.-L., Foix, D., Gonbeau, D., Walker, W., et al. (2013) · Nature Materials · doi:10.1038/nmat3699 · Cited by 1,539
Self-citationLi, W., Dolocan, A., Oh, P., Celio, H., Park, S., Cho, J., & Manthiram, A. (2017) · Nature Communications · doi:10.1038/ncomms14589 · Cited by 466
Research Progress on Negative Electrodes for Practical Li‐Ion Batteries: Beyond Carbonaceous Anodes
Aravindan, V., Lee, Y., & Madhavi, S. (2015) · Advanced Energy Materials · doi:10.1002/aenm.201402225 · Cited by 462
Metadata
- Authors
- Dedryvère, R., Foix, D., Franger, S., Patoux, S., Daniel, L., & Gonbeau, D.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-05-28
- Volume
- 114
- Issue
- 24
- Pages
- 10999-11008
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2332915332
- Cited by
- 301
- References
- 1
- FWCI
- 10.96
- Type
- journal article
- Language
- en
- Open access
- closed
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