The DOI matches its Crossref record; 40 of the 40 references it cites were found in a registry or an index.
Dynamic behaviour of interphases and its implication on high-energy-density cathode materials in lithium-ion batteries
Open accessAbstract
Undesired electrode–electrolyte interactions prevent the use of many high-energy-density cathode materials in practical lithium-ion batteries. Efforts to address their limited service life have predominantly focused on the active electrode materials and electrolytes. Here an advanced three-dimensional chemical and imaging analysis on a model material, the nickel-rich layered lithium transition-metal oxide, reveals the dynamic behaviour of cathode interphases driven by conductive carbon additives (carbon black) in a common nonaqueous electrolyte. Region-of-interest sensitive secondary-ion mass spectrometry shows that a cathode-electrolyte interphase, initially formed on carbon black with no electrochemical bias applied, readily passivates the cathode particles through mutual exchange of surface species. By tuning the interphase thickness, we demonstrate its robustness in suppressing the deterioration of the electrode/electrolyte interface during high-voltage cell operation. Our results provide insights on the formation and evolution of cathode interphases, facilitating development of in situ surface protection on high-energy-density cathode materials in lithium-based batteries.
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Cites
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Cited by
An Outlook on Lithium Ion Battery Technology
Manthiram, A. (2017) · ACS Central Science · doi:10.1021/acscentsci.7b00288 · Cited by 1,771
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A new cyclic carbonate enables high power/ low temperature lithium-ion batteries
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Metadata
- Authors
- Li, W., Dolocan, A., Oh, P., Celio, H., Park, S., Cho, J., & Manthiram, A.
- Venue
- Nature Communications
- Published
- 2017-04-26
- Volume
- 8
- Issue
- 1
- Pages
- 14589-14589
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2608000686
- Cited by
- 466
- References
- 40
- FWCI
- 16.78
- Type
- journal article
- Language
- en
- Open access
- gold
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- Li, W., Dolocan, A., Oh, P., Celio, H., Park, S., Cho, J., & Manthiram, A. (2017). Dynamic behaviour of interphases and its implication on high-energy-density cathode materials in lithium-ion batteries. Nature Communications. https://doi.org/10.1038/ncomms14589
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
