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Star-Shaped Donor-π-Acceptor Conjugated Oligomers with 1,3,5-Triazine Cores: Convergent Synthesis and Multifunctional Properties
Abstract
Monodispersed oligomers have been widely developed and used in different optoelectronic areas due to their well-defined molecular structures, high purity, and solution processability. Star-shaped oligomers are especially interesting for OLED application because of their antiaggregation abilities and stable electroluminescence. In addition, star-shaped donor-pi-acceptor conjugated molecules are known to afford good nonlinear optical and two-photon absorption properties due to the intramolecular charge transfer and cooperative enhancement effects. In this context, three generations of highly soluble 1,3,5-triazine based donor-pi-acceptor compounds, TFT1, TFT2, and TFT3, were prepared through a convergent synthetic strategy and their optoelectronic properties were fully studied, which showed distinct correlations with the structures. Closed-aperture and open-aperture Z-scan methods were employed to measure the nonlinear refractive index and two-photon absorption properties of the oligomers, respectively. TFT1 showed a high nonlinear refractive index of 4.14 x 10(-12) esu in THF solution with an excitation wavelength of 800 nm. Also, TFT1 exhibited a large two-photon absorption cross section of 234 GM and a frequency up-converted two-photon excited fluorescence with a lambda(TPEF)(max) value of 527 nm under 800 nm laser irradiation with a pulse duration of 140 fs. OLED devices using the spin-coated films of these oligomers as an active layer showed intensive blue electroluminesce…
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The chemical, structural and electronic properties of triazine allow design of multichromophore complexes with improved light-harvesting ability and high electron injection and transportation rates.
“The chemical, structural and electronic properties of this moiety allow us to design multichromophore complexes with improved light-harvesting ability, and high electron injection and transportation rates.”
From Recent progress in porphyrin-based materials for organic solar cells (2018) · cites this paper as [76]
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Metadata
- Authors
- Ren, S., Zeng, D., Zhong, H., Wang, Y., Qian, S., & Fang, Q.
- Affiliations
- Chinese Academy of Sciences (CN)
- Corresponding author
- Qian, Shixiong
- Fang, Qiang
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-07-22
- Volume
- 114
- Issue
- 32
- Pages
- 10374-10383
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2028720266
- Cited by
- 97
- References
- 78
- Citations by year
- 2026: 2 · 2025: 2 · 2024: 3 · 2023: 3 · 2022: 4 · 2021: 5 · 2020: 7 · 2019: 4 · 2018: 10 · 2017: 8 · 2016: 6 · 2015: 14 · 2014: 11 · 2013: 2 · 2012: 9
- FWCI
- 4.54
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- The Journal of Physical Chemistry B (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Light-Emitting Diodes Research
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Nonlinear Optical Materials Studies
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Electronics and Photovoltaics
- Keywords
- star-shaped oligomers, convergent synthesis, nonlinear optical properties, two-photon absorption, nonlinear refractive index, two-photon fluorescence, frequency up-conversion, blue electroluminescence, anti-aggregation, intramolecular charge transfer
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