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Preparation of Highly Conductive Graphene Hydrogels for Fabricating Supercapacitors with High Rate Capability

Zhang, Li, Shi, Gaoquan·2011·The Journal of Physical Chemistry C

Abstract

Graphene hydrogels prepared via hydrothermal reduction of graphene oxide dispersions (GH-Hs) were further reduced with hydrazine (Hz) or hydroiodic acid (HI) to improve their conductivities. The chemically reduced graphene hydrogels possess high conductivities of 1.3–3.2 S m –1, which are 1 order of magnitude higher than that of a GH-H (0.3 S m –1 ). The supercapacitor based on the Hz-reduced GH-H exhibited a high specific capacitance of 220 F g –1 at 1 A g –1, and this capacitance can be maintained for 74% as the discharging current density was increased up to 100 A g –1 . Furthermore, it showed high power density and long cycle life. The high-performances of this supercapacitor make it promising for high rate charge/discharge applications.

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Crossref · 10.1021/jp204036a

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Metadata

Authors
Zhang, L., & Shi, G.
Venue
The Journal of Physical Chemistry C
Published
2011-08-08
Volume
115
Issue
34
Pages
17206-17212
ISSN
  • 1932-7447 (ISSN-L)
  • 1932-7455
OpenAlex
W1990327922
Cited by
762
References
1
FWCI
24.23
Type
journal article
Language
en
Open access
closed

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