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Cited by 271

The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.

Graphene-Based Flexible Supercapacitors: Pulse-Electropolymerization of Polypyrrole on Free-Standing Graphene Films

Davies, Aaron, Audette, Philippe, Farrow, Blake, Hassan, Fathy, Chen, Zhongwei, Choi, Ja-Yeon, Yu, Aiping·2011·The Journal of Physical Chemistry C

Abstract

A simple method has been implemented to create flexible, uniform graphene–polypyrrole composite films using a pulsed electropolymerization technique for supercapacitor electrodes. Applying the pseudocapacitive contribution of conformal redox-active polypyrrole to graphene supercapacitor electrodes results in high performance while still maintaining the inherent flexibility of graphene films. Specific capacitances as high as 237 F/g were obtained for a moderate total deposition time of only 120 s, which is approximately four times higher than the blank scaffold, graphene films. This flexible supercapacitor film exhibited very high energy and power densities with values of ∼33 Wh/kg and ∼1184 W/kg, respectively, at a scan rate of 0.01 V/s. This increase was attributed to the favorable nucleation of new polymer chains at defects on the graphene surface, which become less favorable as defect sites are occupied by existing polymer nanoparticles.

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Metadata

Authors
Davies, A., Audette, P., Farrow, B., Hassan, F., Chen, Z., Choi, J.-Y., & Yu, A.
Venue
The Journal of Physical Chemistry C
Published
2011-08-17
Volume
115
Issue
35
Pages
17612-17620
ISSN
  • 1932-7447 (ISSN-L)
  • 1932-7455
OpenAlex
W1992779654
Cited by
271
References
1
FWCI
11.36
Type
journal article
Language
en
Open access
closed

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