The DOI matches its Crossref record; 37 of the 37 references it cites were found in a registry or an index.
Nature and Light Dependence of Bulk Recombination in Co-Pi-Catalyzed BiVO4 Photoanodes
Open accessAbstract
BiVO 4 is considered to be a promising photoanode material for solar water splitting applications. Its performance is limited by two main factors: slow water oxidation kinetics and poor charge separation. We confirm recent reports that cobalt phosphate (Co-Pi) is an efficient water oxidation catalyst for BiVO 4 and report an AM1.5 photocurrent of 1.7 mA/cm 2 at 1.23 V vs RHE for 100 nm spray-deposited, compact, and undoped BiVO 4 films with an optimized Co-Pi film thickness of 30 nm. The charge separation of these films depends strongly on light intensity, ranging from 90% at low light intensities to less than 20% at intensities corresponding to 1 sun. These observations indicate that the charge separation efficiency in BiVO 4 is limited by poor electron transport and not by the presence of bulk defect states, interface traps, or the presence of a Schottky junction at the back-contact.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Plasmonic-metal nanostructures for efficient conversion of solar to chemical energy
Linic, S., Christopher, P., & Ingram, D. B. (2011) · Nature Materials · doi:10.1038/nmat3151 · Cited by 4,852
In Situ Formation of an Oxygen-Evolving Catalyst in Neutral Water Containing Phosphate and Co 2+
Kanan, M. W., & Nocera, D. G. (2008) · Science · doi:10.1126/science.1162018 · Cited by 4,122
Highly active oxide photocathode for photoelectrochemical water reduction
Paracchino, A., Laporte, V., Sivula, K., Grätzel, M., & Thimsen, E. (2011) · Nature Materials · doi:10.1038/nmat3017 · Cited by 2,128
New Benchmark for Water Photooxidation by Nanostructured α-Fe2O3 Films
Kay, A., Cesar, I., & Grätzel, M. (2006) · Journal of the American Chemical Society · doi:10.1021/ja064380l · Cited by 1,562
A Fast Soluble Carbon-Free Molecular Water Oxidation Catalyst Based on Abundant Metals
Yin, Q., Tan, J. M., Besson, C., Geletii, Y. V., Musaev, D. G., Kuznetsov, A. E., Luo, Z., Hardcastle, K. I., & Hill, C. L. (2010) · Science · doi:10.1126/science.1185372 · Cited by 1,438
Mechanistic Studies of the Oxygen Evolution Reaction by a Cobalt-Phosphate Catalyst at Neutral pH
Surendranath, Y., Kanan, M. W., & Nocera, D. G. (2010) · Journal of the American Chemical Society · doi:10.1021/ja106102b · Cited by 1,232
Chen, Z., Jaramillo, T. F., Deutsch, T. G., Kleiman-Shwarsctein, A., Forman, A. J., Gaillard, N., Garland, R., Takanabe, K., Heske, C., Sunkara, M., et al. (2010) · Journal of Materials Research · doi:10.1557/jmr.2010.0020 · Cited by 1,203
Heterojunction BiVO4/WO3 electrodes for enhanced photoactivity of water oxidation
Hong, S. J., Lee, S., Jang, J. S., & Lee, J. S. (2011) · Energy & Environmental Science · doi:10.1039/c0ee00743a · Cited by 1,168
Tokunaga, S., Kato, H., & Kudo, A. (2001) · Chemistry of Materials · doi:10.1021/cm0103390 · Cited by 1,112
Zhong, D. K., Choi, S., & Gamelin, D. R. (2011) · Journal of the American Chemical Society · doi:10.1021/ja207348x · Cited by 1,040
Cited by
Earth-abundant catalysts for electrochemical and photoelectrochemical water splitting
Roger, I., Shipman, M. A., & Symes, M. D. (2017) · Nature Reviews Chemistry · doi:10.1038/s41570-016-0003 · Cited by 3,503
Semiconducting materials for photoelectrochemical energy conversion
Sivula, K., & van de Krol, R. (2016) · Nature Reviews Materials · doi:10.1038/natrevmats.2015.10 · Cited by 1,645
Self-citationTan, H. L., Amal, R., & Ng, Y. H. (2017) · Journal of Materials Chemistry A · doi:10.1039/c7ta04441k · Cited by 459
A Front‐Illuminated Nanostructured Transparent BiVO4 Photoanode for >2% Efficient Water Splitting
Kuang, Y., Jia, Q., Nishiyama, H., Yamada, T., Kudo, A., & Domen, K. (2016) · Advanced Energy Materials · doi:10.1002/aenm.201501645 · Cited by 359
Kim, J. H., Jo, Y., Kim, J. H., Jang, J. W., Kang, H. J., Lee, Y. H., Kim, D. S., Jun, Y., & Lee, J. S. (2015) · ACS Nano · doi:10.1021/acsnano.5b03859 · Cited by 266
Metadata
- Authors
- Abdi, F. F., & van de Krol, R.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-04-20
- Volume
- 116
- Issue
- 17
- Pages
- 9398-9404
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W1983713181
- Cited by
- 573
- References
- 37
- FWCI
- 14.94
- Type
- journal article
- Language
- en
- Open access
- green
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Nature and Light Dependence of Bulk Recombination in Co-Pi-Catalyzed BiVO4 Photoanodes. https://app.cochat.ai/papers/10.1021/jp3007552
- The paper
- Abdi, F. F., & van de Krol, R. (2012). Nature and Light Dependence of Bulk Recombination in Co-Pi-Catalyzed BiVO4 Photoanodes. The Journal of Physical Chemistry C. https://doi.org/10.1021/jp3007552
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
