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Computational and Photoelectrochemical Study of Hydrogenated Bismuth Vanadate
Abstract
We demonstrate hydrogenation as a facile method to significantly enhance the performance of BiVO 4 films for photoelectrochemical water oxidation. Hydrogenation was performed for BiVO 4 films by annealing them in hydrogen atmosphere at elevated temperatures between 200 and 400 °C. Hydrogen gas can reduce BiVO 4 to form oxygen vacancies as well as hydrogen impurities. DFT calculation predicted that both oxygen vacancies and hydrogen impurities are shallow donors for BiVO 4 with low formation energies. These defects could increase the donor densities of BiVO 4 without introducing deep trap states. Electrochemical impedance measurements showed that the donor densities of BiVO 4 films were significantly enhanced upon hydrogenation. Hydrogen-treated BiVO 4 (H-BiVO 4 ) photoanodes achieved a maximum photocurrent density of 3.5 mA/cm 2 at 1.0 V vs Ag/AgCl, which is 1 order of magnitude higher than that of air-annealed BiVO 4 obtained at the same potential. The enhanced photoactivities were attributed to increased donor densities of H-BiVO 4, which facilitates the charge transport and collection.
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Cited by
Tan, H. L., Amal, R., & Ng, Y. H. (2017) · Journal of Materials Chemistry A · doi:10.1039/c7ta04441k · Cited by 459
Hetero-type dual photoanodes for unbiased solar water splitting with extended light harvesting
Kim, J. H., Jang, J.-W., Jo, Y. H., Abdi, F. F., Lee, Y. H., van de Krol, R., & Lee, J. S. (2016) · Nature Communications · doi:10.1038/ncomms13380 · Cited by 344
Kim, J. H., Jo, Y., Kim, J. H., Jang, J. W., Kang, H. J., Lee, Y. H., Kim, D. S., Jun, Y., & Lee, J. S. (2015) · ACS Nano · doi:10.1021/acsnano.5b03859 · Cited by 266
Metadata
- Authors
- Wang, G., Ling, Y., Lu, X., Qian, F., Tong, Y., Zhang, J. Z., Lordi, V., Rocha Leao, C., & Li, Y.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-05-21
- Volume
- 117
- Issue
- 21
- Pages
- 10957-10964
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2123270410
- Cited by
- 254
- References
- 0
- FWCI
- 7.09
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Computational and Photoelectrochemical Study of Hydrogenated Bismuth Vanadate. https://app.cochat.ai/papers/10.1021/jp401972h
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- Wang, G., Ling, Y., Lu, X., Qian, F., Tong, Y., Zhang, J. Z., Lordi, V., Rocha Leao, C., & Li, Y. (2013). Computational and Photoelectrochemical Study of Hydrogenated Bismuth Vanadate. The Journal of Physical Chemistry C. https://doi.org/10.1021/jp401972h
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