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Computational and Photoelectrochemical Study of Hydrogenated Bismuth Vanadate

Wang, Gongming, Ling, Yichuan, Lu, Xihong, Qian, Fang, Tong, Yexiang, Zhang, Jin Z., Lordi, Vincenzo, Rocha Leao, Cedric, Li, Yat·2013·The Journal of Physical Chemistry C

Abstract

We demonstrate hydrogenation as a facile method to significantly enhance the performance of BiVO 4 films for photoelectrochemical water oxidation. Hydrogenation was performed for BiVO 4 films by annealing them in hydrogen atmosphere at elevated temperatures between 200 and 400 °C. Hydrogen gas can reduce BiVO 4 to form oxygen vacancies as well as hydrogen impurities. DFT calculation predicted that both oxygen vacancies and hydrogen impurities are shallow donors for BiVO 4 with low formation energies. These defects could increase the donor densities of BiVO 4 without introducing deep trap states. Electrochemical impedance measurements showed that the donor densities of BiVO 4 films were significantly enhanced upon hydrogenation. Hydrogen-treated BiVO 4 (H-BiVO 4 ) photoanodes achieved a maximum photocurrent density of 3.5 mA/cm 2 at 1.0 V vs Ag/AgCl, which is 1 order of magnitude higher than that of air-annealed BiVO 4 obtained at the same potential. The enhanced photoactivities were attributed to increased donor densities of H-BiVO 4, which facilitates the charge transport and collection.

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Metadata

Authors
Wang, G., Ling, Y., Lu, X., Qian, F., Tong, Y., Zhang, J. Z., Lordi, V., Rocha Leao, C., & Li, Y.
Venue
The Journal of Physical Chemistry C
Published
2013-05-21
Volume
117
Issue
21
Pages
10957-10964
ISSN
  • 1932-7447 (ISSN-L)
  • 1932-7455
OpenAlex
W2123270410
Cited by
254
References
0
FWCI
7.09
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Computational and Photoelectrochemical Study of Hydrogenated Bismuth Vanadate. https://app.cochat.ai/papers/10.1021/jp401972h
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Wang, G., Ling, Y., Lu, X., Qian, F., Tong, Y., Zhang, J. Z., Lordi, V., Rocha Leao, C., & Li, Y. (2013). Computational and Photoelectrochemical Study of Hydrogenated Bismuth Vanadate. The Journal of Physical Chemistry C. https://doi.org/10.1021/jp401972h

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