The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Theory of Surface-Enhanced Raman Scattering in Semiconductors
Abstract
We develop an analytical expression for the lowest order nonzero contribution to the surface-enhanced Raman spectrum from a system composed of a molecule adsorbed on a semiconductor nanoparticle. We consider a combined molecule-semiconductor system and include Herzberg–Teller vibronic coupling of the zero-order Born–Oppenheimer states. This follows a previous derivation for metallic SERS, but instead of a Fermi level, the semiconductor system involves a band gap and we find that the SERS enhancement is maximized at either the conduction or valence band edge. The resulting expression may be regarded as an extension of the Albrecht A-, B-, and C-terms and show that the SERS enhancement is caused by several resonances in the combined system, namely, surface plasmon, exciton, charge-transfer, and molecular resonances. These resonances are coupled by terms in the numerator, which provide strict selection rules that enable us to test the theory and predict the relative intensities of the Raman lines. Furthermore, by considering interactions of the various contributions to the SERS enhancement, we are able to develop ways to optimize the enhancement factor by tailoring the semiconductor nanostructure thereby adjusting the location of the various contributing resonances.
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Citations
Cites
Beiträge zur Optik trüber Medien, speziell kolloidaler Metallösungen
Mie, G. (1908) · Annalen der Physik · doi:10.1002/andp.19083300302 · Cited by 11,537
Raman spectra of pyridine adsorbed at a silver electrode
Fleischmann, M., Hendra, P. J., & McQuillan, A. J. (1974) · Chemical Physics Letters · doi:10.1016/0009-2614(74)85388-1 · Cited by 7,172
Surface raman spectroelectrochemistry
Jeanmaire, D. L., & Van Duyne, R. P. (1977) · Journal of Electroanalytical Chemistry and Interfacial Electrochemistry · doi:10.1016/s0022-0728(77)80224-6 · Cited by 4,738
Cited by
A Review on Surface-Enhanced Raman Scattering
Pilot, R., Signorini, R., Durante, C., Orian, L., Bhamidipati, M., & Fabris, L. (2019) · Biosensors · doi:10.3390/bios9020057 · Cited by 1,010
Surface-enhanced Raman spectroscopy
Han, X. X., Rodriguez, R. S., Haynes, C. L., Ozaki, Y., & Zhao, B. (2022) · Nature Reviews Methods Primers · doi:10.1038/s43586-021-00083-6 · Cited by 907
Enhanced Raman Scattering with Dielectrics
Alessandri, I., & Lombardi, J. R. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00365 · Cited by 655
Self-citationSemiconductor SERS enhancement enabled by oxygen incorporation
Zheng, Z., Cong, S., Gong, W., Xuan, J., Li, G., Lu, W., Geng, F., & Zhao, Z. (2017) · Nature Communications · doi:10.1038/s41467-017-02166-z · Cited by 452
Recent Progress of Amorphous Nanomaterials
Kang, J., Yang, X., Hu, Q., Cai, Z., Liu, L.-M., & Guo, L. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00229 · Cited by 398
Surface-enhanced Raman spectroscopy: a half-century historical perspective
Yi, J., You, E.-M., Hu, R., Wu, D.-Y., Liu, G.-K., Yang, Z.-L., Zhang, H., Gu, Y., Wang, Y.-H., Wang, X., et al. (2025) · Chemical Society Reviews · doi:10.1039/d4cs00883a · Cited by 382
Surface-Enhanced Raman Spectroscopy: Current Understanding, Challenges, and Opportunities
Ma, H., Pan, S.-Q., Wang, W.-L., Yue, X., Xi, X.-H., Yan, S., Wu, D.-Y., Wang, X., Liu, G., & Ren, B. (2024) · ACS Nano · doi:10.1021/acsnano.4c02670 · Cited by 346
Review of Surface Enhanced Raman Scattering Applications in Forensic Science
Muehlethaler, C., Leona, M., & Lombardi, J. R. (2016) · Analytical Chemistry · doi:10.1021/acs.analchem.5b04131 · Cited by 313
Self-citationA Novel Ultra‐Sensitive Semiconductor SERS Substrate Boosted by the Coupled Resonance Effect
Yang, L., Peng, Y., Yang, Y., Liu, J., Huang, H., Yu, B., Zhao, J., Lu, Y., Huang, Z., Li, Z., et al. (2019) · Advanced Science · doi:10.1002/advs.201900310 · Cited by 298
Self-citationSurface-enhanced Raman scattering using bismuth nanoparticles: A study with amino acids
Bezerra, A. G., Cavassin, P., Machado, T. N., Woiski, T. D., Caetano, R., & Schreiner, W. H. (2017) · Journal of Nanoparticle Research · doi:10.1007/s11051-017-4057-6 · Cited by 32
Metadata
- Authors
- Lombardi, J. R., & Birke, R. L.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-05-13
- Volume
- 118
- Issue
- 20
- Pages
- 11120-11130
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2320608472
- Cited by
- 545
- References
- 3
- FWCI
- 7.07
- Type
- journal article
- Language
- en
- Open access
- closed
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