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Tunable Photodeposition of MoS2 onto a Composite of Reduced Graphene Oxide and CdS for Synergic Photocatalytic Hydrogen Generation

Li, Yuexiang, Wang, Hao, Peng, Shaoqin·2014·The Journal of Physical Chemistry C

Abstract

Recently, MoS 2 as an excellent cocatalyst for hydrogen evolution reaction (HER) has attracted extensive attention. In this work, MoS 2 was controllably loaded on the composite of reduced graphene oxide (rGO) and CdS (rGO/CdS) by a facile photoreduction method at different pHs. At low pH 7, MoS 2 deposits on the surface of the CdS particles of the composite. However, at high pH 11, it loads on the exposed rGO. When MoS 2 is on the rGO, the transfer of the photoexcited electron from CdS to rGO is compatible with the HER at MoS 2 (synergic effect), whereas the transfer is incompatible with the HER when it is on the CdS (antisynergic effect). Moreover, the MoS 2 deposited on the CdS decreases the photoabsorption and photoactivity of CdS, and the effect is avoided when MoS 2 is on the rGO. The photocatalytic HER rate under the synergic condition is 4.3 times as high as that under antisynergic condition. This work would open a promising way to design and fabricate the efficient composite photocatalysts.

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Metadata

Authors
Li, Y., Wang, H., & Peng, S.
Venue
The Journal of Physical Chemistry C
Published
2014-08-13
Volume
118
Issue
34
Pages
19842-19848
ISSN
  • 1932-7447 (ISSN-L)
  • 1932-7455
OpenAlex
W2322738052
Cited by
218
References
7
FWCI
8.95
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Tunable Photodeposition of MoS2 onto a Composite of Reduced Graphene Oxide and CdS for Synergic Photocatalytic Hydrogen Generation. https://app.cochat.ai/papers/10.1021/jp5054474
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Li, Y., Wang, H., & Peng, S. (2014). Tunable Photodeposition of MoS2 onto a Composite of Reduced Graphene Oxide and CdS for Synergic Photocatalytic Hydrogen Generation. The Journal of Physical Chemistry C. https://doi.org/10.1021/jp5054474

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