The DOI matches its Crossref record; 32 of the 32 references it cites were found in a registry or an index.
Surface Phases of TiO2 Nanoparticles Studied by UV Raman Spectroscopy and FT-IR Spectroscopy
Abstract
Surface phases of TiO 2 nanoparticles (30 ∼ 200 nm) were studied by UV Raman spectroscopy and FT-IR spectroscopy with CO and CO 2 as probe molecules. UV Raman spectroscopy can differentiate the surface phase structure of TiO 2 calcined at different temperatures. IR spectra of adsorbed CO and CO 2 on TiO 2 calcined at different temperatures are in good agreement with the results from UV Raman spectra. IR results evidently confirm that UV Raman spectroscopy is a surface-sensitive technique for TiO 2 . Both UV Raman and IR spectra indicate that the crystalline phase of TiO 2 in the surface region is usually different from that in the bulk which is characterized by XRD. CO is weakly adsorbed on Ti 4+ ions of anatase phase but is hardly adsorbed on those of rutile phase at room temperature. Adsorbed CO 2 on anatase phase produces mainly bidentate carbonate, while on rutile phase produces mainly bicarbonate species. These results suggest that the surface Lewis acidity of anatase phase is stronger than that of rutile phase, and the concentration of cus Ti 4+ -O 2- pairs on the surface of anatase phase is much higher than that on rutile phase; however, the basicity of surface OH groups of rutile phase is stronger than that of anatase phase.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Electrochemical Photolysis of Water at a Semiconductor Electrode
FUJISHIMA, A., & HONDA, K. (1972) · Nature · doi:10.1038/238037a0 · Cited by 34,169
Environmental applications of semiconductor photocatalysis
Hoffmann, M. R., Martin, S. T., Choi, W., & Bahnemann, D. W. (1995) · Chemical Reviews · doi:10.1021/cr00033a004 · Cited by 18,495
Photocatalysis on TiO2 Surfaces: Principles, Mechanisms, and Selected Results
Linsebigler, A. L., Lu, G., & Yates, J. T. (1995) · Chemical Reviews · doi:10.1021/cr00035a013 · Cited by 11,575
Light-induced amphiphilic surfaces
Wang, R., Hashimoto, K., Fujishima, A., Chikuni, M., Kojima, E., Kitamura, A., Shimohigoshi, M., & Watanabe, T. (1997) · Nature · doi:10.1038/41233 · Cited by 3,384
HARUTA, M. (1989) · Journal of Catalysis · doi:10.1016/0021-9517(89)90034-1 · Cited by 3,185
Raman spectrum of anatase, TiO 2
Ohsaka, T., Izumi, F., & Fujiki, Y. (1978) · Journal of Raman Spectroscopy · doi:10.1002/jrs.1250070606 · Cited by 2,327
UV Raman Spectroscopic Study on TiO2. I. Phase Transformation at the Surface and in the Bulk
Zhang, J., Li, M., Feng, Z., Chen, J., & Li, C. (2006) · The Journal of Physical Chemistry B · doi:10.1021/jp0552473 · Cited by 969
Self-citationBusca, G., & Lorenzelli, V. (1982) · Materials Chemistry · doi:10.1016/0390-6035(82)90059-1 · Cited by 942
Particle size effects on transformation kinetics and phase stability in nanocrystalline TiO2
Gribb, A. A., & Banfield, J. F. (1997) · American Mineralogist · doi:10.2138/am-1997-7-809 · Cited by 722
Surface chemistry of titania (anatase) and titania-supported catalysts
Hadjiivanov, K. I., & Klissurski, D. G. (1996) · Chemical Society Reviews · doi:10.1039/cs9962500061 · Cited by 591
Infrared study of the surface of titanium dioxides. I. Hydroxyl groups
Primet, M., Pichat, P., & Mathieu, M. V. (1971) · The Journal of Physical Chemistry · doi:10.1021/j100679a007 · Cited by 591
Investigation of CO and CO2 Adsorption on Tetragonal and Monoclinic Zirconia
Pokrovski, K., Jung, K. T., & Bell, A. T. (2001) · Langmuir · doi:10.1021/la001723z · Cited by 547
Martra, G. (2000) · Applied Catalysis A: General · doi:10.1016/s0926-860x(00)00641-4 · Cited by 430
FTIR Study of the Low-Temperature Water–Gas Shift Reaction on Au/Fe2O3 and Au/TiO2 Catalysts
Boccuzzi, F., Chiorino, A., Manzoli, M., Andreeva, D., & Tabakova, T. (1999) · Journal of Catalysis · doi:10.1006/jcat.1999.2636 · Cited by 425
Zhang, H., & Banfield, J. F. (2000) · Journal of materials research/Pratt's guide to venture capital sources · doi:10.1557/jmr.2000.0067 · Cited by 350
Interaction of Carbon Dioxide with the Surface of Zirconia Polymorphs
Bachiller‐Baeza, B., Rodríguez-Ramos, I., & Guerrero-Ruiz, A. R. (1998) · Langmuir · doi:10.1021/la970856q · Cited by 336
Li, G., & Gray, K. A. (2007) · Chemical Physics · doi:10.1016/j.chemphys.2007.05.023 · Cited by 306
Anpo, M. (2004) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.77.1427 · Cited by 283
Yates, D. J. C. (1961) · The Journal of Physical Chemistry · doi:10.1021/j100823a011 · Cited by 279
Morterra, C. (1988) · Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases · doi:10.1039/f19888401617 · Cited by 272
Liao, L.-F., Lien, C.-F., Shieh, D.-L., Chen, M.-T., & Lin, J.-L. (2002) · The Journal of Physical Chemistry B · doi:10.1021/jp0211988 · Cited by 249
Park, D.-R., Zhang, J., Ikeue, K., Yamashita, H., & Anpo, M. (1999) · Journal of Catalysis · doi:10.1006/jcat.1999.2472 · Cited by 227
Self-citationRamis, G., Busca, G., & Lorenzelli, V. (1991) · Materials Chemistry and Physics · doi:10.1016/0254-0584(91)90037-u · Cited by 218
Infrared study of the surface of titanium dioxides. II. Acidic and basic properties
Mathieu, M. V., Primet, M., & Pichat, P. (1971) · The Journal of Physical Chemistry · doi:10.1021/j100679a008 · Cited by 210
Sreethawong, T., Suzuki, Y., & Yoshikawa, S. (2005) · Journal of Solid State Chemistry · doi:10.1016/j.jssc.2004.11.014 · Cited by 201
Gibson, D. H. (1999) · Coordination Chemistry Reviews · doi:10.1016/s0010-8545(99)00021-1 · Cited by 200
Infrared Spectroscopic Study of the Carbon Dioxide Adsorption on the Surface of Ga2O3 Polymorphs
Collins, S. E., Baltanás, M. A., & Bonivardi, A. L. (2006) · The Journal of Physical Chemistry B · doi:10.1021/jp055594c · Cited by 191
FTIR Study of Low-Temperature CO Adsorption on Pure and Ammonia-Precovered TiO2 (Anatase)
Hadjiivanov, K., Lamotte, J., & Lavalley, J.-C. (1997) · Langmuir · doi:10.1021/la962104m · Cited by 169
Pyridine-TiO2 surface interaction as a probe for surface active centers analysis
Bezrodna, T., Puchkovska, G. O., Shimanovska, V. V., et al. (2003) · Applied Surface Science · doi:10.1016/s0169-4332(03)00346-5 · Cited by 141
Titania-supported metals as CO hydrogenation catalysts
Vannice, M. A. (1982) · Journal of Catalysis · doi:10.1016/0021-9517(82)90025-2 · Cited by 133
Surface Acidity and Basicity of a Rutile Powder
Ferretto, L., & Glisenti, A. (2003) · Chemistry of Materials · doi:10.1021/cm021269f · Cited by 90
Adsorption and Photooxidation of CH3CN on TiO2
Zhuang, J., Rusu, C. N., & Yates, J. T. (1999) · The Journal of Physical Chemistry B · doi:10.1021/jp991040w · Cited by 89
Cited by
Fundamentals of TiO2 Photocatalysis: Concepts, Mechanisms, and Challenges
Guo, Q., Zhou, C., Ma, Z., & Yang, X. (2019) · Advanced Materials · doi:10.1002/adma.201901997 · Cited by 1,909
Nanomaterials for renewable energy production and storage
Chen, X., Li, C., Grätzel, M., Kostecki, R., & Mao, S. S. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35230c · Cited by 1,015
Self-citationLiu, L., Zhao, H., Andino, J. M., & Li, Y. (2012) · ACS Catalysis · doi:10.1021/cs300273q · Cited by 870
Long, R., Li, Y., Liu, Y., Chen, S., Zheng, X., Gao, C., He, C., Chen, N., Qi, Z., Song, L., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b00452 · Cited by 571
Artificial Photosynthesis over Crystalline TiO2-Based Catalysts: Fact or Fiction?
Yang, C.-C., Yu, Y.-H., van der Linden, B., Wu, J. C. S., & Mul, G. (2010) · Journal of the American Chemical Society · doi:10.1021/ja101318k · Cited by 375
Metadata
- Authors
- Su, W., Zhang, J., Feng, Z., Chen, T., Ying, P., & Li, C.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-04-30
- Volume
- 112
- Issue
- 20
- Pages
- 7710-7716
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W1974904479
- Cited by
- 379
- References
- 32
- FWCI
- 5.66
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
