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Role and Function of Noble-Metal/Cr-Layer Core/Shell Structure Cocatalysts for Photocatalytic Overall Water Splitting Studied by Model Electrodes
Abstract
The mechanism of hydrogen evolution by a core/shell noble-metal/Cr 2 O 3 particulate as a highly efficient cocatalyst for overall water splitting under visible light using the photocatalyst (Ga 1− x Zn x )(N 1− x O x ) is investigated by electrochemical and in situ spectroscopic measurements of model electrodes. The electrodes are prepared by electrochemical deposition of 1.8−3.5 nm thick Cr 2 O 3 films on Rh and Pt plates and are evaluated as model systems of Rh/Cr 2 O 3 and Pt/Cr 2 O 3 core/shell particulates, which have previously been applied effectively as cocatalysts for hydrogen evolution in this system. Proton adsorption/desorption and H 2 evolution currents are observed for both the Cr 2 O 3 -coated and the bare electrodes, and the infrared absorption band due to Pt−H stretching (2039 cm −1 ) is apparent for both the coated and the bare electrodes. These observations indicate that the Cr 2 O 3 layer does not interfere with proton reduction or hydrogen evolution and that proton reduction takes place at the Cr 2 O 3 /Pt interface. However, the reduction of oxygen to water is suppressed only in the Cr 2 O 3 -coated samples. The Cr 2 O 3 layer is thus permeable to protons and the evolved hydrogen molecules, but not to oxygen. Cocatalyst modification by thin films with this type of functionality thus appears to be a useful strategy for improving the efficiency of photocatalytic overall water splitting.
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Citations
Cites
Heterogeneous photocatalyst materials for water splitting
Kudo, A., & Miseki, Y. (2009) · Chem. Soc. Rev. · doi:10.1039/b800489g · Cited by 10,585
High-Resolution X-Ray Photoemission Spectrum of the Valence Bands of Gold
Shirley, D. A. (1972) · Physical Review B · doi:10.1103/physrevb.5.4709 · Cited by 6,231
Photocatalyst releasing hydrogen from water
Maeda, K., Teramura, K., Lu, D., Takata, T., Saito, N., Inoue, Y., & Domen, K. (2006) · Nature · doi:10.1038/440295a · Cited by 2,812
Self-citationInorganic Materials as Catalysts for Photochemical Splitting of Water
Osterloh, F. E. (2008) · Chemistry of Materials · doi:10.1021/cm7024203 · Cited by 2,161
Kato, H., Asakura, K., & Kudo, A. (2003) · Journal of the American Chemical Society · doi:10.1021/ja027751g · Cited by 1,705
New Non-Oxide Photocatalysts Designed for Overall Water Splitting under Visible Light
Maeda, K., & Domen, K. (2007) · The Journal of Physical Chemistry C · doi:10.1021/jp070911w · Cited by 1,514
Self-citationGaN:ZnO Solid Solution as a Photocatalyst for Visible-Light-Driven Overall Water Splitting
Maeda, K., Takata, T., Hara, M., Saito, N., Inoue, Y., Kobayashi, H., & Domen, K. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0518777 · Cited by 1,397
Self-citationTanuma, S., Powell, C. J., & Penn, D. R. (1991) · Surface and Interface Analysis · doi:10.1002/sia.740171304 · Cited by 1,205
Calculations of electron inelastic mean free paths for 31 materials
Tanuma, S., Powell, C. J., & Penn, D. R. (1988) · Surface and Interface Analysis · doi:10.1002/sia.740111107 · Cited by 959
Subramanian, V., Wolf, E., & Kamat, P. V. (2001) · The Journal of Physical Chemistry B · doi:10.1021/jp011118k · Cited by 916
Marković, N. M., Grgur, B. N., & Ross, P. N. (1997) · The Journal of Physical Chemistry B · doi:10.1021/jp970930d · Cited by 913
Stamenković, V., Schmidt, T. J., Ross, P. N., & Marković, N. M. (2002) · The Journal of Physical Chemistry B · doi:10.1021/jp021182h · Cited by 829
Tsuji, I., Kato, H., Kobayashi, H., & Kudo, A. (2004) · Journal of the American Chemical Society · doi:10.1021/ja048296m · Cited by 824
Kraeutler, B., & Bard, A. J. (1978) · Journal of the American Chemical Society · doi:10.1021/ja00481a059 · Cited by 699
Maeda, K., Teramura, K., Lu, D., Saito, N., Inoue, Y., & Domen, K. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200602473 · Cited by 641
Self-citationPhotocatalytic decomposition of water vapour on an NiO–SrTiO3catalyst
Domen, K., Naito, S., Soma, M., Onishi, T., & Tamaru, K. (1980) · J. Chem. Soc., Chem. Commun. · doi:10.1039/c39800000543 · Cited by 437
Self-citationMechanism of photocatalytic decomposition of water into H2 and O2 over NiO$z.sbnd;SrTiO3
DOMEN, K. (1986) · Journal of Catalysis · doi:10.1016/0021-9517(86)90143-0 · Cited by 395
Self-citationMaeda, K., Teramura, K., Takata, T., Hara, M., Saito, N., Toda, K., Inoue, Y., Kobayashi, H., & Domen, K. (2005) · The Journal of Physical Chemistry B · doi:10.1021/jp053499y · Cited by 389
Self-citationPhotocatalytic decomposition of water over NiO$z.sbnd;K4Nb6O17 catalyst
KUDO, A. (1988) · Journal of Catalysis · doi:10.1016/0021-9517(88)90066-8 · Cited by 371
Vibrational Stark effect of adsorbates at electrochemical interfaces
Lambert, D. K. (1996) · Electrochimica Acta · doi:10.1016/0013-4686(95)00349-5 · Cited by 371
Domen, K., Kudo, A., Onishi, T., Kosugi, N., & Kuroda, H. (1986) · The Journal of Physical Chemistry · doi:10.1021/j100274a018 · Cited by 371
Self-citationPhotocatalyst Materials for Water Splitting
Kudo, A. (2003) · Catalysis Surveys from Asia · doi:10.1023/a:1023480507710 · Cited by 369
Photocatalytic water splitting into H2 and O2 over various tantalate photocatalysts
Kato, H., & Kudo, A. (2003) · Catalysis Today · doi:10.1016/s0920-5861(02)00355-3 · Cited by 308
Maeda, K., Teramura, K., & Domen, K. (2008) · Journal of Catalysis · doi:10.1016/j.jcat.2007.12.009 · Cited by 295
Self-citationZinc Germanium Oxynitride as a Photocatalyst for Overall Water Splitting under Visible Light
Lee, Y., Terashima, H., Shimodaira, Y., Teramura, K., Hara, M., Kobayashi, H., Domen, K., & Yashima, M. (2007) · The Journal of Physical Chemistry C · doi:10.1021/jp0656532 · Cited by 282
Self-citationMaeda, K., Teramura, K., Lu, D., Saito, N., Inoue, Y., & Domen, K. (2007) · The Journal of Physical Chemistry C · doi:10.1021/jp071056j · Cited by 264
Self-citationAn x‐ray photoelectron spectroscopic study of some chromium–oxygen systems
Desimoni, E., Malitesta, C., Zambonin, P. G., & Rivière, J. C. (1988) · Surface and Interface Analysis · doi:10.1002/sia.740130210 · Cited by 264
Sayama, K., & Arakawa, H. (1997) · Journal of the Chemical Society, Faraday Transactions · doi:10.1039/a607662i · Cited by 261
Tsuji, I., Kato, H., Kobayashi, H., & Kudo, A. (2005) · The Journal of Physical Chemistry B · doi:10.1021/jp044722e · Cited by 259
Photolysis of water over metallized powdered titanium dioxide
Yamaguti, K., & Sato, S. (1985) · Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases · doi:10.1039/f19858101237 · Cited by 239
Kita, H. (1966) · Journal of The Electrochemical Society · doi:10.1149/1.2423772 · Cited by 236
Maeda, K., Teramura, K., Masuda, H., Takata, T., Saito, N., Inoue, Y., & Domen, K. (2006) · The Journal of Physical Chemistry B · doi:10.1021/jp0616563 · Cited by 231
Self-citationSato, J., Saito, N., Nishiyama, H., & Inoue, Y. (2001) · The Journal of Physical Chemistry B · doi:10.1021/jp010794j · Cited by 213
Maeda, K., Teramura, K., Saito, N., Inoue, Y., & Domen, K. (2006) · Journal of Catalysis · doi:10.1016/j.jcat.2006.07.023 · Cited by 209
Self-citationPhotocatalytic Water Splitting Under Visible Light with Particulate Semiconductor Catalysts
Lee, J. S. (2005) · Catalysis Surveys from Asia · doi:10.1007/s10563-005-9157-0 · Cited by 200
Spectroscopic identification of the adsorbed intermediate in hydrogen evolution on platinum
Nichols, R. J., & Bewick, A. (1988) · Journal of Electroanalytical Chemistry and Interfacial Electrochemistry · doi:10.1016/0022-0728(88)80047-0 · Cited by 198
Abe, R., Sayama, K., & Arakawa, H. (2003) · Chemical Physics Letters · doi:10.1016/s0009-2614(03)00252-5 · Cited by 185
Maeda, K., Teramura, K., Lu, D., Takata, T., Saito, N., Inoue, Y., & Domen, K. (2006) · The Journal of Physical Chemistry B · doi:10.1021/jp061829o · Cited by 183
Self-citationOxygen Reduction Reaction on Ruthenium and Rhodium Nanoparticles Modified with Selenium and Sulfur
Cao, D., Wieckowski, A., Inukai, J., & Alonso-Vante, N. (2006) · Journal of The Electrochemical Society · doi:10.1149/1.2180709 · Cited by 172
Domen, K., Naito, S., Onishi, T., Tamaru, K., & Soma, M. (1982) · The Journal of Physical Chemistry · doi:10.1021/j100215a032 · Cited by 172
Self-citationInoue, Y., Kubokawa, T., & Sato, K. (1991) · The Journal of Physical Chemistry · doi:10.1021/j100163a032 · Cited by 171
Drastic Enhancement of TiO2-Photocatalyzed Reduction of Nitrobenzene by Loading Ag Clusters
Tada, H., Ishida, T., Takao, A., & Ito, S. (2004) · Langmuir · doi:10.1021/la049167m · Cited by 169
An Electrochemical and X‐Ray Photoelectron Spectroscopy Study of the Passive State of Chromium
Moffat, T. P., & Latanision, R. M. (1992) · Journal of The Electrochemical Society · doi:10.1149/1.2069514 · Cited by 168
Kunimatsu, K., Senzaki, T., Samjeské, G., Tsushima, M., & Osawa, M. (2007) · Electrochimica Acta · doi:10.1016/j.electacta.2006.12.007 · Cited by 166
Sato, J., Saito, N., Nishiyama, H., & Inoue, Y. (2002) · Journal of Photochemistry and Photobiology A Chemistry · doi:10.1016/s1010-6030(02)00076-x · Cited by 129
Lee, Y., Teramura, K., Hara, M., & Domen, K. (2007) · Chemistry of Materials · doi:10.1021/cm062980d · Cited by 124
Self-citationTeramura, K., Maeda, K., Saito, T., Takata, T., Saito, N., Inoue, Y., & Domen, K. (2005) · The Journal of Physical Chemistry B · doi:10.1021/jp054313y · Cited by 118
Self-citationKunimatsu, K., Senzaki, T., Tsushima, M., & Osawa, M. (2004) · Chemical Physics Letters · doi:10.1016/j.cplett.2004.11.100 · Cited by 113
Maeda, K., Hashiguchi, H., Masuda, H., Abe, R., & Domen, K. (2008) · The Journal of Physical Chemistry C · doi:10.1021/jp710758q · Cited by 112
Self-citationSato, J., Kobayashi, H., Saito, N., Nishiyama, H., & Inoue, Y. (2003) · Journal of Photochemistry and Photobiology A Chemistry · doi:10.1016/s1010-6030(03)00028-5 · Cited by 96
Origin of Visible Light Absorption in GaN-Rich (Ga 1 - x Zn x )(N 1 - x O x ) Photocatalysts
Hirai, T., Maeda, K., Yoshida, M., Kubota, J., Ikeda, S., Matsumura, M., & Domen, K. (2007) · The Journal of Physical Chemistry C · doi:10.1021/jp709811k · Cited by 88
Self-citationSun, X., Maeda, K., Faucheur, M. L., Teramura, K., & Domen, K. (2007) · Applied Catalysis A General · doi:10.1016/j.apcata.2007.05.005 · Cited by 73
Self-citationWang, X., Maeda, K., Lee, Y., & Domen, K. (2008) · Chemical Physics Letters · doi:10.1016/j.cplett.2008.03.065 · Cited by 72
Self-citationMatsumoto, Y., Ünal, U., Тanaka, N., Kudo, A., & Kato, H. (2004) · Journal of Solid State Chemistry · doi:10.1016/j.jssc.2004.08.001 · Cited by 69
Kudo, A., Nakagawa, S., & Kato, H. (1999) · Chemistry Letters · doi:10.1246/cl.1999.1197 · Cited by 53
Cornell, A., Lindbergh, G., & Simonsson, D. (1992) · Electrochimica Acta · doi:10.1016/0013-4686(92)85093-z · Cited by 39
An Ellipsometric Study of Chromium Passivation
Genshaw, M. A., & Sirohi, R. S. (1971) · Journal of The Electrochemical Society · doi:10.1149/1.2408402 · Cited by 28
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Maeda, K., & Domen, K. (2010) · The Journal of Physical Chemistry Letters · doi:10.1021/jz1007966 · Cited by 2,739
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Li, X., Yu, J., Jaroniec, M., & Chen, X. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00400 · Cited by 2,304
Engineering heterogeneous semiconductors for solar water splitting
Li, X., Yu, J., Low, J., Fang, Y., Xiao, J., & Chen, X. (2015) · Journal of Materials Chemistry A · doi:10.1039/c4ta04461d · Cited by 1,888
Wang, Q., Hisatomi, T., Jia, Q., Tokudome, H., Zhong, M., Wang, C., Pan, Z., Takata, T., Nakabayashi, M., Shibata, N., et al. (2016) · Nature Materials · doi:10.1038/nmat4589 · Cited by 1,684
Self-citationHisatomi, T., & Domen, K. (2019) · Nature Catalysis · doi:10.1038/s41929-019-0242-6 · Cited by 1,586
Self-citation
Metadata
- Authors
- Yoshida, M., Takanabe, K., Maeda, K., Ishikawa, A., Kubota, J., Sakata, Y., Ikezawa, Y., & Domen, K.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-05-13
- Volume
- 113
- Issue
- 23
- Pages
- 10151-10157
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2012881910
- Cited by
- 282
- References
- 57
- FWCI
- 5.30
- Type
- journal article
- Language
- en
- Open access
- closed
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