The DOI matches its Crossref record; 36 of the 36 references it cites were found in a registry or an index.
Studies of Surface Wettability Conversion on TiO2 Single-Crystal Surfaces
Abstract
Reversible surface wettability conversion on titanium dioxide (TiO 2 ) single crystals has been achieved, and its mechanism has been examined by means of contact angle measurement and X-ray photoelectron spectroscopy (XPS). A UV light illuminated TiO 2 single-crystal surface exhibited a 0° contact angle for both water and oil, indicative of a highly amphiphilic surface against its native hydrophobic surface. This was ascribed to photoreduction of surface Ti 4+ to Ti 3+ at definite sites, leading to preferential adsorption of dissociative water on top. A long-term storage of the highly amphiphilic surface resulted in reconversion of the surface wettability. It was found that the amphiphilic-to-hydrophobic reconversion is due to the replacement of the adsorbed hydroxyl groups by oxygen, which returns the surface geometric and electronic structures similar to the native TiO 2 surface. The result of angle-resolved XPS measurement revealed that the surface reactions occurred at the uppermost layers of the single crystals. By comparing the reactivities of (110), (100), and (001) single-crystal surfaces, it was concluded that oxygen bridging sites played an important role in the surface wettability conversions.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Electrochemical Photolysis of Water at a Semiconductor Electrode
FUJISHIMA, A., & HONDA, K. (1972) · Nature · doi:10.1038/238037a0 · Cited by 34,169
Self-citationA low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films
O'Regan, B., & Grätzel, M. (1991) · Nature · doi:10.1038/353737a0 · Cited by 28,599
Environmental applications of semiconductor photocatalysis
Hoffmann, M. R., Martin, S. T., Choi, W., & Bahnemann, D. W. (1995) · Chemical Reviews · doi:10.1021/cr00033a004 · Cited by 18,495
Photocatalysis on TiO2 Surfaces: Principles, Mechanisms, and Selected Results
Linsebigler, A. L., Lu, G., & Yates, J. T. (1995) · Chemical Reviews · doi:10.1021/cr00035a013 · Cited by 11,575
Fox, M. A., & Dulay, M. T. (1993) · Chemical Reviews · doi:10.1021/cr00017a016 · Cited by 4,163
Light-induced amphiphilic surfaces
Wang, R., Hashimoto, K., Fujishima, A., Chikuni, M., Kojima, E., Kitamura, A., Shimohigoshi, M., & Watanabe, T. (1997) · Nature · doi:10.1038/41233 · Cited by 3,384
Self-citationThe interaction of water with solid surfaces: Fundamental aspects
Thiel, P. A., & Madey, T. E. (1987) · Surface Science Reports · doi:10.1016/0167-5729(87)90001-x · Cited by 2,411
Ceramic sensors for humidity detection: the state-of-the-art and future developments
Traversa, E. (1995) · Sensors and Actuators B: Chemical · doi:10.1016/0925-4005(94)01268-m · Cited by 848
Photogeneration of Highly Amphiphilic TiO2 Surfaces
Wang, R., Hashimoto, K., Fujishima, A., Chikuni, M., Kojima, E., Kitamura, A., Shimohigoshi, M., & Watanabe, T. (1998) · Advanced Materials · doi:10.1002/(sici)1521-4095(199801)10:2<135::aid-adma135>3.0.co;2-m · Cited by 834
Self-citationBactericidal and Detoxification Effects of TiO2 Thin Film Photocatalysts
Sunada, K., Kikuchi, Y., Hashimoto, K., & Fujishima, A. (1998) · Environmental Science & Technology · doi:10.1021/es970860o · Cited by 806
Self-citation
Cited by
The surface science of titanium dioxide
Diebold, U. (2003) · Surface Science Reports · doi:10.1016/s0167-5729(02)00100-0 · Cited by 7,944
TiO2 photocatalysis and related surface phenomena
FUJISHIMA, A., ZHANG, X., & TRYK, D. (2008) · Surface Science Reports · doi:10.1016/j.surfrep.2008.10.001 · Cited by 6,737
Self-citationPhotoinduced reactivity of titanium dioxide
CARP, O. (2004) · Progress in Solid State Chemistry · doi:10.1016/j.progsolidstchem.2004.08.001 · Cited by 4,566
TiO2 Photocatalysis: A Historical Overview and Future Prospects
Hashimoto, K., Irie, H., & Fujishima, A. (2005) · Japanese Journal of Applied Physics · doi:10.1143/jjap.44.8269 · Cited by 3,367
Self-citationThe interaction of water with solid surfaces: fundamental aspects revisited
Henderson, M. (2002) · Surface Science Reports · doi:10.1016/s0167-5729(01)00020-6 · Cited by 2,299
Surface Science Studies of the Photoactivation of TiO 2 New Photochemical Processes
Thompson, T. L., & Yates, J. T. (2006) · Chemical Reviews · doi:10.1021/cr050172k · Cited by 2,064
A surface science perspective on TiO2 photocatalysis
Henderson, M. A. (2011) · Surface Science Reports · doi:10.1016/j.surfrep.2011.01.001 · Cited by 2,038
Bioinspired Surfaces with Superwettability: New Insight on Theory, Design, and Applications
Wang, S., Liu, K., Yao, X., & Jiang, L. (2015) · Chemical Reviews · doi:10.1021/cr400083y · Cited by 1,646
Effect of aspect ratio and surface defects on the photocatalytic activity of ZnO nanorods
Zhang, X., Qin, J., Xue, Y., Yu, P., Zhang, B., Wang, L., & Liu, R. (2014) · Scientific Reports · doi:10.1038/srep04596 · Cited by 1,018
Wang, S., Pan, L., Song, J.-J., Mi, W., Zou, J.-J., Wang, L., & Zhang, X. (2015) · Journal of the American Chemical Society · doi:10.1021/ja512047k · Cited by 718
Yan, J., Wu, G., Guan, N., Li, L., Li, Z., & Cao, X. (2013) · Physical Chemistry Chemical Physics · doi:10.1039/c3cp50927c · Cited by 684
Photocatalysis and Photoinduced Hydrophilicity of Various Metal Oxide Thin Films
Miyauchi, M., Nakajima, A., Watanabe, T., & Hashimoto, K. (2002) · Chemistry of Materials · doi:10.1021/cm020076p · Cited by 649
Self-citationThe Fabrication and Switchable Superhydrophobicity of TiO2 Nanorod Films
Feng, X., Zhai, J., & Jiang, L. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200501337 · Cited by 629
Photocatalytic activity and photoinduced hydrophilicity of titanium dioxide coated glass
Watanabe, T., Nakajima, A., Wang, R., Minabe, M., Koizumi, S., Fujishima, A., & Hashimoto, K. (1999) · Thin Solid Films · doi:10.1016/s0040-6090(99)00205-9 · Cited by 585
Self-citationBio-Inspired Titanium Dioxide Materials with Special Wettability and Their Applications
Liu, K., Cao, M., Fujishima, A., & Jiang, L. (2014) · Chemical Reviews · doi:10.1021/cr4006796 · Cited by 571
Self-citationHeterogeneous photocatalysis: From water photolysis to applications in environmental cleanup
FUJISHIMA, A., ZHANG, X., & TRYK, D. (2007) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2006.09.009 · Cited by 552
Self-citationZhu, K., Vinzant, T. B., Neale, N. R., & Frank, A. J. (2007) · Nano Letters · doi:10.1021/nl072145a · Cited by 461
Mini review on photocatalysis of titanium dioxide nanoparticles and their solar applications
Lan, Y., Lu, Y., & Ren, Z. (2013) · Nano Energy · doi:10.1016/j.nanoen.2013.04.002 · Cited by 419
Mor, G. K., Prakasam, H. E., Varghese, O. K., Shankar, K., & Grimes, C. A. (2007) · Nano Letters · doi:10.1021/nl0710046 · Cited by 385
Recent development and future prospects of TiO2photocatalysis
Peiris, S., de Silva, H. B., Ranasinghe, K. N., Bandara, S. V., & Perera, I. R. (2021) · Journal of the Chinese Chemical Society · doi:10.1002/jccs.202000465 · Cited by 346
Infrared Spectra of Photoinduced Species on Hydroxylated Titania Surfaces
Szczepankiewicz, S. H., Colussi, A. J., & Hoffmann, M. R. (2000) · The Journal of Physical Chemistry B · doi:10.1021/jp0007890 · Cited by 326
Reversible Hydrogen Storage via Titanium-Catalyzed LiAlH4 and Li3AlH6
Chen, J., Kuriyama, N., Xu, Q., Takeshita, H. T., & Sakai, T. (2001) · The Journal of Physical Chemistry B · doi:10.1021/jp012127w · Cited by 299
Zheng, J., Bao, S., & Jin, P. (2015) · Nano Energy · doi:10.1016/j.nanoen.2014.09.023 · Cited by 297
Biomimetic polymeric superhydrophobic surfaces and nanostructures: from fabrication to applications
Wen, G., Guo, Z., & Liu, W. (2017) · Nanoscale · doi:10.1039/c7nr00096k · Cited by 287
Photoresponsive surfaces with controllable wettability
Wang, S., Song, Y., & Jiang, L. (2007) · Journal of Photochemistry and Photobiology C: Photochemistry Reviews · doi:10.1016/j.jphotochemrev.2007.03.001 · Cited by 279
Metadata
- Authors
- Wang, R., Sakai, N., Fujishima, A., Watanabe, T., & Hashimoto, K.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 1999-03-01
- Volume
- 103
- Issue
- 12
- Pages
- 2188-2194
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2031409217
- Cited by
- 664
- References
- 36
- FWCI
- 18.79
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
