The DOI matches its Crossref record; 35 of the 35 references it cites were found in a registry or an index.
Slow Dynamic Processes in Lead Halide Perovskite Solar Cells. Characteristic Times and Hysteresis
Abstract
Characteristic times of perovskite solar cells (PSCs) have been measured by different techniques: transient photovoltage decay, transient photoluminescence, and impedance spectroscopy. A slow dynamic process is detected that shows characteristic times in the seconds to milliseconds scale, with good quantitative agreement between transient photovoltage decay and impedance spectroscopy. Here, we show that this characteristic time is related with a novel slow dynamic process caused by the peculiar structural properties of lead halide perovskites and depending on perovskite crystal size and organic cation nature. This new process may lie at the basis of the current-voltage hysteresis reported for PSCs and could have important implications in PSC performance because it may give rise to distinct dynamical behavior with respect to other classes of photovoltaic devices. Furthermore, we show that low-frequency characteristic time, commonly associated with electronic carrier lifetime in other photovoltaic devices, cannot be attributed to a recombination process in the case of PSCs.
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Cites
Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
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Self-citationPerovskites: The Emergence of a New Era for Low-Cost, High-Efficiency Solar Cells
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Cited by
High-efficiency solution-processed perovskite solar cells with millimeter-scale grains
Nie, W., Tsai, H., Asadpour, R., Blancon, J.-C., Neukirch, A. J., Gupta, G., Crochet, J. J., Chhowalla, M., Tretiak, S., Alam, M. A., et al. (2015) · Science · doi:10.1126/science.aaa0472 · Cited by 3,295
Growth of CH3NH3PbI3 cuboids with controlled size for high-efficiency perovskite solar cells
Im, J.-H., Jang, I.-H., Pellet, N., Grätzel, M., & Park, N.-G. (2014) · Nature Nanotechnology · doi:10.1038/nnano.2014.181 · Cited by 1,759
Self-citationHalide perovskite materials for solar cells: a theoretical review
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Stability of Metal Halide Perovskite Solar Cells
Leijtens, T., Eperon, G. E., Noel, N. K., Habisreutinger, S. N., Petrozza, A., & Snaith, H. J. (2015) · Advanced Energy Materials · doi:10.1002/aenm.201500963 · Cited by 1,308
Metadata
- Authors
- Sanchez, R. S., Gonzalez-Pedro, V., Lee, J.-W., Park, N.-G., Kang, Y. S., Mora-Sero, I., & Bisquert, J.
- Venue
- The Journal of Physical Chemistry Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-06-23
- Volume
- 5
- Issue
- 13
- Pages
- 2357-2363
- ISSN
- 1948-7185 (ISSN-L)
- OpenAlex
- W2328295620
- Cited by
- 665
- References
- 35
- FWCI
- 57.13
- Type
- journal article
- Language
- en
- Open access
- closed
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